Chapter 9. From Stoichiometric Carbonyl Complexes to Stable Zeolite-Supported Subnanometer Platinum Clusters of Defined Size

  1. Dr. Franco Laeri5,
  2. Prof. Dr. Ferdi Schüth6,
  3. Prof. Dr. Ulrich Simon7 and
  4. Dr. Michael Wark8
  1. Martin Beneke1,2,
  2. Nils I. Jaeger3 and
  3. Günter Schulz-Eckloff4

Published Online: 28 JAN 2005

DOI: 10.1002/3527602674.ch9

Host-Guest-Systems Based on Nanoporous Crystals

Host-Guest-Systems Based on Nanoporous Crystals

How to Cite

Beneke, M., Jaeger, N. I. and Schulz-Eckloff, G. (2003) From Stoichiometric Carbonyl Complexes to Stable Zeolite-Supported Subnanometer Platinum Clusters of Defined Size, in Host-Guest-Systems Based on Nanoporous Crystals (eds F. Laeri, F. Schüth, U. Simon and M. Wark), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527602674.ch9

Editor Information

  1. 5

    Institute of Applied Physics, Technical University Darmstadt, Schloßgartenstr. 7, 64289 Darmstadt, Germany

  2. 6

    Max-Planck-Institute of Coal Research, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

  3. 7

    Institute of Inorganic Chemistry, RWTH Aachen, Professor-Pirlet-Str. 1, 52074 Aachen, Germany

  4. 8

    Institute of Physical Chemistry and Electrochemistry, Hannover University, Callinstr. 3-3a, 30167 Hannover, Germany

Author Information

  1. 1

    Institute of Applied and Physical Chemistry, Fachbereich 2, University of Bremen, PF 330 440, 28334 Bremen, Germany

  2. 2

    Airbus Germany, Hienefeldstraße 1-5, 28199 Bremen, Germany

  3. 3

    Institute of Applied and Physical Chemistry, Fachbereich 2, PF 330 440, 28334 Bremen, Germany

  4. 4

    Institute of Applied and Physical Chemistry, University of Bremen, PF 330 440, 28334 Bremen, Germany

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 8 AUG 2003

ISBN Information

Print ISBN: 9783527305018

Online ISBN: 9783527602674

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Keywords:

  • mesostructured aluminum phosphates;
  • nanostructure;
  • catalytic potential;
  • hexagonal mesostructured aluminum phosphates;
  • tubular mesoporous aluminum phosphates

Summary

  • Introduction

  • Chemistry Within Zeolite Cages

    • Formation of Pt Carbonyls Monitored by FTIR, EXAFS, and UV/Vis Spectroscopy

  • Reversible Decomposition of the Complex

    • Decomposition in Oxygen

    • Decomposition in Vacuum

  • Stable Subnanometer Platinum Clusters

  • Electron Donor Properties of Pt Clusters Derived from Chini Complexes

  • Conclusions

  • Acknowledgements

  • References