Chapter 7. New Reductive Carbocyclisations of Carbohydrate Derivatives Promoted by Samarium Diiodide

  1. Yves Chapleur
  1. J. L. Chiara

Published Online: 28 JAN 2005

DOI: 10.1002/3527603239.ch7

Book Title

Carbohydrate Mimics: Concepts and Methods

Carbohydrate Mimics: Concepts and Methods

Additional Information

How to Cite

Chiara, J. L. (2005) New Reductive Carbocyclisations of Carbohydrate Derivatives Promoted by Samarium Diiodide, in Carbohydrate Mimics: Concepts and Methods (ed Y. Chapleur), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527603239.ch7

Editor Information

  1. UMR CNRS 7565, Université Henri Poincaré-Nancy I, BP239, F-54506 Vandceuvre, France

Author Information

  1. Grupo de Carbohydrates, Instituto de Quimica Organica, C.S.I.C., Juan de la Cervia 3, E-28006, Madrid, Spain

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 12 NOV 1997

ISBN Information

Print ISBN: 9783527295265

Online ISBN: 9783527603237

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Keywords:

  • carbocyclisations;
  • samarium diiodide;
  • 6-deoxy-6-iodo-hexopyranosides

Summary

  • Introduction

  • Results and Discussion

    • Intramolecular C[DOUBLE BOND]O/C[DOUBLE BOND]O Reductive Coupling

    • Intramolecular C[DOUBLE BOND]O/C[DOUBLE BOND]N[BOND]OR Reductive Cross-Coupling

    • Ring Contraction of 6-Deoxy-6-Iodo-Hexopyranosides

  • Conclusions

  • References

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