Chapter 10. Shape-Persistent Acetylenic Macrocycles for Ordered Systems

  1. Prof. Dr. François Diederich2,
  2. Prof. Dr. Peter J. Stang3 and
  3. Prof. Dr. Rik R. Tykwinski4
  1. Sigurd Höger

Published Online: 24 OCT 2005

DOI: 10.1002/3527605487.ch10

Acetylene Chemistry: Chemistry, Biology, and Material Science

Acetylene Chemistry: Chemistry, Biology, and Material Science

How to Cite

Höger, S. (2004) Shape-Persistent Acetylenic Macrocycles for Ordered Systems, in Acetylene Chemistry: Chemistry, Biology, and Material Science (eds F. Diederich, P. J. Stang and R. R. Tykwinski), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527605487.ch10

Editor Information

  1. 2

    Laboratorium für Organische Chemie, ETH Hönggerberg, HCI, CH-8093 Zürich, Switzerland

  2. 3

    Department of Chemistry, University of Utah, 315S 1400E, Rm. 2020, 84112 Salt Lake City, USA

  3. 4

    Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada

Author Information

  1. Polymer Institut, Universität Karlsruhe, Hertzstraße 16, 76187 Karlsruhe, Germany

Publication History

  1. Published Online: 24 OCT 2005
  2. Published Print: 14 DEC 2004

ISBN Information

Print ISBN: 9783527307814

Online ISBN: 9783527605484

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Keywords:

  • acetylene chemistry;
  • biology and material science;
  • shape-persistent acetylenic macrocycles;
  • ordered systems;
  • experimental procedures

Summary

This chapter contains sections titled:

  • Introduction

  • Ordered Systems

    • Host-Guest Complexes

    • Tubular Superstructures in Solution

    • Thermotropic Liquid Crystals

    • Two-Dimensional Organization

  • Conclusions

  • Experimental Procedures

    • Deprotection of a CPDMS-Protected Acetylene

    • Template-Based Oxidative Cyclodimerization of a Rigid Bisacetylene

    • Deprotection of a Macrocyclic THP-Protected Tetraphenol

    • Alkylation of a Macrocyclic Tetraphenol

    • Hydrolysis of a Macrocycle with Two Intraannular Ester Groups

    • Formation of a Macrocycle with Two Intraannular Thioether Groups

  • Acknowledgements