Chapter 1. Artificial Enzymes

  1. Prof. Dr. Ronald Breslow
  1. Prof. Dr. Ronald Breslow

Published Online: 24 MAR 2006

DOI: 10.1002/3527606645.ch1

Artificial Enzymes

Artificial Enzymes

How to Cite

Breslow, R. (2005) Artificial Enzymes, in Artificial Enzymes (ed R. Breslow), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527606645.ch1

Editor Information

  1. Columbia University, Department of Chemistry, 556 Chandler Laboratory, New York, NY 10027-6948, USA

Author Information

  1. Columbia University, Department of Chemistry, 556 Chandler Laboratory, New York, NY 10027-6948, USA

Publication History

  1. Published Online: 24 MAR 2006
  2. Published Print: 25 MAY 2005

ISBN Information

Print ISBN: 9783527311651

Online ISBN: 9783527606641

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Keywords:

  • artificial enzymes;
  • mimics of enzymes;
  • thiamine pyrophosphate as coenzyme;
  • pyridoxamine and pyridoxal phosphates as coenzymes;
  • artificial hydrolytic enzymes;
  • cytochrome P-450 mimics;
  • future prospects

Summary

This chapter contains sections titled:

  • Mimics of Enzymes that use Thiamine Pyrophosphate as a Coenzyme

  • Mimics of Enzymes that use Pyridoxamine and Pyridoxal Phosphates as Coenzymes

  • Artificial Hydrolytic Enzymes

    • Chymotrypsin Mimics

    • Metalloenzyme Mimics

    • Artificial Ribonucleases

    • Artificial Enolases and Aldolases

  • Cytochrome P-450 Mimics

    • Aromatic Substitution in Cyclodextrin Complexes

    • Selective Photochemical Reactions

    • Directed Halogenations

    • Nitrene Insertions

    • Binding by Cyclodextrin Dimers

    • Hydroxylations by Artificial P-450 Enzymes

  • Future Prospects