Chapter 7. Properties of the Interphase Epoxy–Amine/Metal: Influences from the Nature of the Amine and the Metal

  1. Prof. Dr. Wulff Possart
  1. M. Aufray1 and
  2. A. A. Roche2

Published Online: 28 APR 2006

DOI: 10.1002/3527607307.ch7

Adhesion: Current Research and Applications

Adhesion: Current Research and Applications

How to Cite

Aufray, M. and Roche, A. A. (2005) Properties of the Interphase Epoxy–Amine/Metal: Influences from the Nature of the Amine and the Metal, in Adhesion: Current Research and Applications (ed W. Possart), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527607307.ch7

Editor Information

  1. Laboratoire Européen de Recherche Universitaire Saarland-Lorraine (LERUSL), Universität des Saarlandes, Gebäude 22-6, Postfach 151150, 66041 Saarbrücken, Germany

Author Information

  1. 1

    INSA de Lyon Laboratoire des Matériaux, Macromoléculaires (IMP/LMM), 20, av Albert Einstein, 69621 Villeurbanne Cedex, France

  2. 2

    INSA de Lyon, Laboratoire des Matériaux Macromoléculaires (IMP/LMM), 17, rue Jean Capelle, 69621 Villeurbanne Cedex, France

Publication History

  1. Published Online: 28 APR 2006
  2. Published Print: 24 AUG 2005

ISBN Information

Print ISBN: 9783527312634

Online ISBN: 9783527607303

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Keywords:

  • adhesion;
  • research;
  • application;
  • properties of interphase epoxy-amine/metal;
  • influences;
  • nature of the amine;
  • nature of metal;
  • thermal analysis;
  • interphase formation mechanisms

Summary

This chapter contains sections titled:

  • Abstract

  • Introduction

  • Materials and Methods

    • Materials

    • Thermal Analysis (DSC)

    • Micro-Infrared Spectroscopy (µ-FTIR)

    • Fourier Transform Near-Infrared Spectroscopy (FT-NIR)

    • Inductively Coupled Plasma Spectroscopy (ICP)

    • X-Ray Diffraction (XRD)

    • Polarized Optical Microscopy (POM) Coupled with a Hot Stage Apparatus

  • Results and Discussion

    • Interphase Formation Mechanisms

    • Formation of New Networks

    • Crystallization of “Modified” IPDA

    • Modification of Mechanical Properties

    • Comparison of Coatings and Metal–Bulk Interphases

    • Influence of the Stoichiometric Ratio

  • Conclusion

  • Acknowledgments

  • References