Chapter 10. Polyynes

  1. Prof. Michael M. Haley2 and
  2. Prof. Rik R. Tykwinski3
  1. Vivian W. W. Yam and
  2. C. H. Tao

Published Online: 13 JUN 2006

DOI: 10.1002/3527607994.ch10

Carbon-Rich Compounds: From Molecules to Materials

Carbon-Rich Compounds: From Molecules to Materials

How to Cite

Yam, V. W. W. and Tao, C. H. (2006) Polyynes, in Carbon-Rich Compounds: From Molecules to Materials (eds M. M. Haley and R. R. Tykwinski), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527607994.ch10

Editor Information

  1. 2

    Department of Chemistry, University of Oregon, Eugene, Oregon 97403-1253, USA

  2. 3

    Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada

Author Information

  1. Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

Publication History

  1. Published Online: 13 JUN 2006
  2. Published Print: 6 FEB 2006

ISBN Information

Print ISBN: 9783527312245

Online ISBN: 9783527607990

SEARCH

Keywords:

  • carbon-rich compounds;
  • polyynes;
  • organic polyynes;
  • synthetic routes towards transition metal alkynyl complexes;
  • rhenium(I) alkynyls;
  • platinum(II) alkynyls;
  • copper(I) and silver(I) alkynyls;
  • mixed-metal alkynyls

Summary

This chapter contains sections titled:

  • Introduction

    • Organic Polyynes

    • Organometallic Polyynyl Complexes

    • Synthetic Routes Towards Transition Metal Alkynyl Complexes

      • Copper-catalyzed Dehydrohalogenation

      • Metal Halides with Alkynylating Agents

      • Metal-free Methods with Terminal Alkynes

    • Rhenium(I) Alkynyls

    • Platinum(II) Alkynyls

      • Platinum(II) Phosphine Systems

      • Platinum(II) Polypyridine Systems

    • Copper(I) and Silver(I) Alkynyls

    • Gold(I) Alkynyls

    • Mixed-metal Alkynyls

    • Conclusions

    • Experimental: Selected Procedures

      • Synthesis of [tBu2bpy)(CO)3ReC≡C[BOND]C≡C[BOND]C≡CPh]

      • Synthesis of [1,3,5-{PhC≡CPt(PEt3)2C≡CC6H4C≡C}3C6H3]

      • Synthesis of [Pt(trpy)C≡C[BOND]Ph]PF6

      • Synthesis of [Cu3(µ-dppm)331-C≡C[BOND]tBu)2]PF6

      • Synthesis of [{η2-Re(CO)3(bpy)(C≡CPh)}2Ag]PF6

      • Synthesis of [Ag6(µ-dppm)4{µ3-C≡C[BOND]C≡C[BOND]Re(Me2bpy)(CO)3}4](PF6)2

      • Synthesis of [1,3-{Cl(PEt3)2PdC≡C}2-5-(bpy)(CO)3ReC≡C}C6H3]