Chapter 2. Liquid-Gas Phase Transitions

  1. Vladimir P. Skripov and
  2. Mars Z. Faizullin

Published Online: 22 MAY 2006

DOI: 10.1002/3527608052.ch2

Crystal-Liquid-Gas Phase Transitions and Thermodynamic Similarity

Crystal-Liquid-Gas Phase Transitions and Thermodynamic Similarity

How to Cite

Skripov, V. P. and Faizullin, M. Z. (2006) Liquid-Gas Phase Transitions, in Crystal-Liquid-Gas Phase Transitions and Thermodynamic Similarity, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, FRG. doi: 10.1002/3527608052.ch2

Author Information

  1. Institute of Thermal Physics of the Ural Branch of the Russian Academy of Sciences, Russia

Publication History

  1. Published Online: 22 MAY 2006
  2. Published Print: 20 JAN 2006

ISBN Information

Print ISBN: 9783527405763

Online ISBN: 9783527608058

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Keywords:

  • crystal;
  • liquid;
  • gas;
  • phase transitions;
  • critical point;
  • thermodynamic similarity;
  • similarity near the critical point;
  • liquid-vapor phase coexistence

Summary

This chapter contains sections titled:

  • Basic Fact: Existence of a Critical Point

  • Method of Thermodynamic Similarity

  • Similarity Near the Critical Point: The Change of Critical Indices

  • New Universal Relationships for Liquid–Vapor Phase Coexistence in One-Component Systems

    • Correlation Between Pressure and Densities of Liquid and Vapor Along the Saturation Curve

    • Correlation Between Caloric Properties and Densities of Liquid and Vapor Along the Saturation Curve

    • Correlation Between Surface Tension and Heat of Evaporation of Nonassociated Liquids

    • One-Parameter Correlation for the Heat of Evaporation of Nonassociated Liquids