14. Free-radical reactions of organophosphorus(III)

  1. Frank R. Hartley
  1. Wesley G. Bentrude

Published Online: 22 JAN 2010

DOI: 10.1002/9780470034439.ch14

Organophosphorus Compounds (1990)

Organophosphorus Compounds (1990)

How to Cite

Bentrude, W. G. (1990) Free-radical reactions of organophosphorus(III), in Organophosphorus Compounds (1990) (ed F. R. Hartley), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470034439.ch14

Editor Information

  1. Cranfield Institute of Technology, Cranfield, UK

Author Information

  1. Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, USA

Publication History

  1. Published Online: 22 JAN 2010
  2. Published Print: 25 JUL 1990

ISBN Information

Print ISBN: 9780471926078

Online ISBN: 9780470034439

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Keywords:

  • scission;
  • stereochemistries;
  • thioketones;
  • tricovalent;
  • photochemical

Summary

This chapter contains sections titled:

  • Background

  • Energetics, Rates and Overall Reactivity

  • Some Selected Rate Constants

  • Other Reactions of Phosphoranyl Radicals

  • Phosphoranyl Radical Structure and Stereochemistry

  • Photochemical Analogues of Radical Reactions

  • Practical and Synthetic Applications

  • References