3. Optically active phosphines: preparation, uses and chiroptical properties

  1. Frank R. Hartley
  1. H. B. Kagan and
  2. M. Sasaki

Published Online: 22 JAN 2010

DOI: 10.1002/9780470034439.ch3

Organophosphorus Compounds (1990)

Organophosphorus Compounds (1990)

How to Cite

Kagan, H. B. and Sasaki, M. (1990) Optically active phosphines: preparation, uses and chiroptical properties, in Organophosphorus Compounds (1990) (ed F. R. Hartley), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470034439.ch3

Editor Information

  1. Cranfield Institute of Technology, Cranfield, UK

Author Information

  1. Laboratoire de Synthèse Asymétrique, UA CNRS 255, Université Paris-Sud, 91405 Orsay, France

Publication History

  1. Published Online: 22 JAN 2010
  2. Published Print: 25 JUL 1990

ISBN Information

Print ISBN: 9780471926078

Online ISBN: 9780470034439

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Keywords:

  • monophosphines;
  • hydrosilylation;
  • cyclic structure;
  • diphosphines;
  • diastereomer

Summary

This chapter contains sections titled:

  • Introduction

  • Various Classes of Chiral Phosphines

  • Preparation of Stereochemically Pure Phosphines

  • Chiroptical Properties, Absolute Configuration

  • Methods of Measurement of Enantiomeric Excesses

  • Stereochemistry of Chemical Reactions on Phosphorus or in Vicinal Positions

  • Uses in Organometallic Chemistry and Asymmetric Catalysis

  • Conclusion

  • References