14. Substitution Reactions: Free Radicals

  1. Michael B. Smith and
  2. Jerry March

Published Online: 18 MAY 2006

DOI: 10.1002/9780470084960.ch14

March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, Sixth Edition

March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, Sixth Edition

How to Cite

Smith, M. B. and March, J. (2006) Substitution Reactions: Free Radicals, in March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, Sixth Edition, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470084960.ch14

Author Information

  1. Professor of Chemistry, USA

Publication History

  1. Published Online: 18 MAY 2006
  2. Published Print: 27 DEC 2006

ISBN Information

Print ISBN: 9780471720911

Online ISBN: 9780470084960

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Keywords:

  • substitution reactions - free radicals;
  • hydrogen as leaving group;
  • allylic and benzylic halogenation

Summary

This chapter contains sections titled:

  • Mechanisms

  • Reactivity

  • Reactions

  • Hydrogen as Leaving Group

  • N2 as Leaving Group349

  • Metals as Leaving Groups

  • Halogen as Leaving Group

  • Sulfur as Leaving Group

  • Carbon as Leaving Group