The Synthesis of Molybdenum and Tungsten Dinitrogen Complexes

  1. Daryle H. Busch
  1. Jonathan R. Dilworth1,
  2. Raymond L. Richards1,
  3. Grace J.-J. Chen2 and
  4. John W. Mcdonald2

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132517.ch31

Inorganic Syntheses, Volume 20

Inorganic Syntheses, Volume 20

How to Cite

Dilworth, J. R., Richards, R. L., Chen, G. J.-J. and Mcdonald, J. W. (1980) The Synthesis of Molybdenum and Tungsten Dinitrogen Complexes, in Inorganic Syntheses, Volume 20 (ed D. H. Busch), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132517.ch31

Editor Information

  1. Department of Chemistry, The Ohio State University

Author Information

  1. 1

    A.R.C. Unit of Nitrogen Fixation, University of Sussex, Brighton, Sussex, England BN1 9QJ.

  2. 2

    Charles F. Kettering Research Laboratory, Yellow Springs, OH 45387.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1980

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471077152

Online ISBN: 9780470132517

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Keywords:

  • dinitrogen complexes;
  • tungsten;
  • molybdenum;
  • synthesis;
  • methanol

Summary

This chapter contains sections titled:

  • Bis (acetonitrile)tetrachloromolubdenum(IV)[MoCl4(CH3CN)2]

  • Tetrachlorobis(tetrahydrofuran)molybdenum(IV),[MoCl4(thf)2]

  • Trichlorotris(tetrahydrofuran)molybdenum(III),[MoCl3(thf)3]

  • trans-Bis(dinitrogen)bis[ethylenebis](diphenyphosphine)]molybdenum(O),trans[MO(N2)2(Ph2PCH2CH2PPh2)2]

  • Tetrachlorobis(triphenylphosphine)tungsten(IV),[WCl4(PPh3)2]

  • Tetrachloro[ethylenebis(diphenylphosphine)]-tungsten(IV)WCl4(Ph2PCH2CH2PPh2)]

  • trans-Bis(dinitrogen)bis[ethylenebis(diphenyphosphine)]-tungesten(o),trans-[W(N2)2(Ph2PCH2CH2PPh2)2]