(2,2′-Bipyridine-N,N′)(2,2′:6′,2″-Terpyridine-N,N′,N″) Complexes of Ruthenium(III)/(II) and Osmium(III)/(II)

  1. Jean'ne M. Shreeve
  1. David C. Ware1,
  2. Peter A. Lay1,
  3. Henry Taube1,
  4. Mei H. Chou2 and
  5. Carol Creutz2

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132555.ch79

Inorganic Syntheses, Volume 24

Inorganic Syntheses, Volume 24

How to Cite

Ware, D. C., Lay, P. A., Taube, H., Chou, M. H. and Creutz, C. (1986) (2,2′-Bipyridine-N,N′)(2,2′:6′,2″-Terpyridine-N,N′,N″) Complexes of Ruthenium(III)/(II) and Osmium(III)/(II), in Inorganic Syntheses, Volume 24 (ed J. M. Shreeve), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132555.ch79

Editor Information

  1. Department of Chemistry, University of Idaho

Author Information

  1. 1

    Department of Chemistry, Stanford University, Stanford, CA 94305.

  2. 2

    Department of Chemistry, Brookhaven National Laboratories, Upton, NY 11973.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1986

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471834410

Online ISBN: 9780470132555

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Keywords:

  • ruthenium complexes;
  • osmium complexes;
  • hydrochloric acid;
  • exothermic addition;
  • hydrogen peroxide

Summary

This chapter contains sections titled:

  • (2,2′-Bipyridine-N,N′)chloro(2,2′:6′,2″-terpyridine-N,N′,N″) ruthenium(II) Chloride Hydrate, [Ru(bpy)(trpy)Cl·2.5H2O

  • (2,2′-Bipyridine-N,N′)(2,2′:6′,2″-terpyridine-N,N′,N″) (trifluoromethanesulfonato-O)ruthenium(III)Trifluoromethanesulfonate,[Ru(bpy)(trpy)(OSO2CF3)](CF3SO3)2, and (trifluoromethanesulfonato-O)osmium(III) Trifluoromethanesulfonate, [Os(bpy)(trpy)(OSO2CF3)](CF3SO3)2

  • (2,2′-Bipyridine-N,N′)(2,2′:6′,2″-terpyridine-N,N′,N″)(trifluoromethanesulfonato-O)ruthenium(II)Trifluoromethanesulfonate [Ru(bpy)(trpy)(OSO2CF3)](CF3SO3)

  • (2,2′-Bipyridine-N,N′)(2,2′:6′,2″-terpyridine-N,N′,N″)(trifluoromethanesulfonato-O)osmium(II)Trifluoromethanesulfonate [Os(bpy)(trpy)(OSO2CF3)](CF3SO3)

  • Aqua(2,2′-bipyridine-N,N′)(2,2′:6′,2″-terpyridine-N,N′,N″ ruthenium(III)Trifluoromethanesulfonate Trihydrate [Ru(bpy)(trpy)(OH2)](CF3SO3)3·3H2O, and Aqua (2,2′-bipyridine-N,N′)(2,2′:6′2″-terpyridine-N,N′,N″)- osmium(III) Trifluoromethanesulfonate Dihydrate,[Ru(bpy)(trpy)(OH2)](CF3SO3)3·2H2O

  • Aqua(2,2′-bipyridine-N,N′)(2,2′:6′,2″-terpyridine-N,N′,N″ osmium(II)Trifluoromethanesulfonate Hydrate, [Os(bpy)(trpy)(OH2)](CF3SO3)2·H2O