Resolution of the Tris(Oxalato)Chromate(III) Ion by a Second-Order Asymmetric Synthesis

  1. Harry R. Allcock
  1. George B. Kauffman1,
  2. Nobuyuki Sugisaka2,
  3. Ian K. Reid3 and
  4. R. Kent Murmann4

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132562.ch33

Inorganic Syntheses, Volume 25

Inorganic Syntheses, Volume 25

How to Cite

Kauffman, G. B., Sugisaka, N., Reid, I. K. and Murmann, R. K. (1989) Resolution of the Tris(Oxalato)Chromate(III) Ion by a Second-Order Asymmetric Synthesis, in Inorganic Syntheses, Volume 25 (ed H. R. Allcock), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132562.ch33

Editor Information

  1. Department of Chemistry, Pennsylvania State University

Author Information

  1. 1

    Department of Chemistry, California State University, Fresno, CA 93740.

  2. 2

    Riker Laboratories, Inc., 270-4S-02 3M Center, St. Paul, MN 55144.

  3. 3

    Research School of Chemistry, The Australian National University, Canberra 2600, Australia.

  4. 4

    Department of Chemistry, University of Missouri, Columbia, MO 65211.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1989

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471618744

Online ISBN: 9780470132562



  • tris(oxalato)chromate(III) ion;
  • asymmetric synthesis;
  • potassium(+)-tris(oxalato)chromate(III) dihydrate;
  • potassium(-)-tris(oxalato)chromate(III) monohydrate;
  • inorganic synthesis


This chapter contains sections titled:

  • Precipitation of (+)-Bis(1,2-ethanediamine)(oxalato)-cobalt(III)(+)-Tris(oxalato)chromate(III) Hexahydrate-(+),(+)-Diastereomer

  • Isolation of Potassium (+)-Tris(oxalato)chromate(III)Dihydrate

  • Isolation of Potassium(-)-Tris(oxalato)chromate(III)Monohydrate