Dicarbonylbis(Di-tert-Butylphosphine)-(μ-Di-tert-Butylphosphido)-μ-Hydrido-Dirhodium(1+)(Rh2(μ-T-Bu2P)(μ-H)(Co)2(T-Bu2Ph)2 and μ-Chloro-Bis(η4-1,5-Cyclooctadiene)(μ-Di-tert-Butylphosphido)Dirhodium(1+) (Rh2(μ-T-Bu2P)-μ-Cl(Cod)2),(Cod = 1,5-Cyclooctadiene)

  1. Harry R. Allcock
  1. R. A. Jones1,
  2. D. E. Heaton1,
  3. T. C. Wright1,
  4. D. W. Meek2 and
  5. C. Supplee2

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132562.ch41

Inorganic Syntheses, Volume 25

Inorganic Syntheses, Volume 25

How to Cite

Jones, R. A., Heaton, D. E., Wright, T. C., Meek, D. W. and Supplee, C. (1989) Dicarbonylbis(Di-tert-Butylphosphine)-(μ-Di-tert-Butylphosphido)-μ-Hydrido-Dirhodium(1+)(Rh2(μ-T-Bu2P)(μ-H)(Co)2(T-Bu2Ph)2 and μ-Chloro-Bis(η4-1,5-Cyclooctadiene)(μ-Di-tert-Butylphosphido)Dirhodium(1+) (Rh2(μ-T-Bu2P)-μ-Cl(Cod)2),(Cod = 1,5-Cyclooctadiene), in Inorganic Syntheses, Volume 25 (ed H. R. Allcock), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132562.ch41

Editor Information

  1. Department of Chemistry, Pennsylvania State University

Author Information

  1. 1

    Department of Chemistry, The University of Texas at Austin, Austin, TX 78712.

  2. 2

    Department of Chemistry, The Ohio State University, Columbus, OH 43210-1173.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1989

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471618744

Online ISBN: 9780470132562

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Keywords:

  • di-tert-butylphosphido (t-Bu2P) complexes;
  • dodecacarbonyltetrarhodium;
  • direct bonding;
  • carbon monoxide;
  • inorganic synthesis

Summary

This chapter contains sections titled:

  • Dicarbonylbis(di-tert-butylphosphine)(μ-di-tert-butylphosphido)-μ-hydrido-dirhodium(1+)[Rh2(μ-t-Bu2P)-(μ-H)(CO)2(t-Bu2PH)2]

  • μ-Chloro-bis(η4-1,5-cyclooctadiene)(μ-di-tert-butylphosphido)-dirhodium(1+)[Rh2(μ-t-Bu2P)μ-Cl(Cod)2]