Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions

  1. Herbert D. Kaesz
  1. Michael I. Bruce1,
  2. Brian K. Nicholson2,
  3. Michael L. Williams1,
  4. Thérèse Arliguie3 and
  5. Guy Lavigne3

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132579.ch48

Inorganic Syntheses, Volume 26

Inorganic Syntheses, Volume 26

How to Cite

Bruce, M. I., Nicholson, B. K., Williams, M. L., Arliguie, T. and Lavigne, G. (1989) Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions, in Inorganic Syntheses, Volume 26 (ed H. D. Kaesz), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132579.ch48

Editor Information

  1. Department of Chemistry and Biochemistry University of California, Los Angeles

Author Information

  1. 1

    Department of Physical and Inorganic Chemistry, University of Adelaide, South Australia, 5001.

  2. 2

    Department of Chemistry, University of Waikato, Hamilton, New Zealand.

  3. 3

    Laboratoire de Chimie de Coordination, CNRS, 31077 Toulouse, France.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1989

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471504856

Online ISBN: 9780470132579

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Keywords:

  • trinuclear-carbonyl-ruthenium cluster;
  • tetranuclear carbonyl-ruthenium cluster;
  • isocyanide;
  • tertiary phosphine;
  • phosphite ligands

Summary

This chapter contains sections titled:

  • Sodium Benzophenone Ketyl Solution

  • Undecacarbonyl(dimethylphenylphosphine)triruthenium,Ru3(CO)11(PMe2Ph)

  • Decacarbonyl(dimethylphenylphosphine)(2-isocyano-2-methylpropane)trieuthenium,Ru3(CO)10(CN-t-Bu)-(PMe2Ph)

  • Decacarbonyl[methylenebis(diphenylphosphine)]-triruthenium,Ru3(CO)10[(Ph2P)2CH2]

  • [μ-Ethynediylbis(diphenylphosphine)]bis[undecacarnonyltriruthenium],{(Ru3(CO)11)2[μ-C2(PPh2)2]}

  • Undecacarbonyltetrahydrido[tris(4-methylphenyl)phosphite]tetraruthenium,Ru4H4(CO)11[P(OC6H4Me-p)3]

  • Decacarbonyl(dimethylphenylphosphine)tetrahydrido[tris(4-methylphenyl)phosphite]tetraruthenium,Ru4H4(CO)10(PMe2Ph)[P(OC6H4Me-p)3]