Iridium(III) Complexes with the Weakly Bonded Anions [BF4]- and [Oso2CF3]-

  1. Robert J. Angelici
  1. Wolfgang Beck1,
  2. Herbert Bauer1,
  3. Bernhard Olgemöller1,
  4. Devereaux A. Clifford2 and
  5. Robert H. Crabtree2

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132593.ch4

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

How to Cite

Beck, W., Bauer, H., Olgemöller, B., Clifford, D. A. and Crabtree, R. H. (1990) Iridium(III) Complexes with the Weakly Bonded Anions [BF4]- and [Oso2CF3]-, in Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28 (ed R. J. Angelici), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132593.ch4

Editor Information

  1. Department of Chemistry, Iowa State University

Author Information

  1. 1

    Institut für Anorganische Chemie, Universität München, Meiserstr. 1,8000 München 2, Federal Republic of Germany.

  2. 2

    Department of Chemistry, Yale University, New Haven CT 06511.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1990

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471526193

Online ISBN: 9780470132593

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Keywords:

  • trans-Carbonylchlorobis(triphenylphosphine)iridium;
  • carbonylchlorohydrido(tetrafluoroborato)-bis(triphenylphosphine)iridium(III);
  • carbonylchloromethyl(tetrafluoroborato)bis((triphenylphosphine) iridium(III);
  • dichloromethane;
  • plastic micropipette

Summary

This chapter contains sections titled:

  • Carbonylchlorohydrido(tetrafluoroborato)bis(triphenylphosphine)iridium(III):Ir(Cl)(CO)(PPh3)2(H)(BF4)

  • Carbonylchloromethyl(tetrafluoroborato)bis(triphenylphosphine)iridium(III):Ir(Cl)(CO)(PPh3)2(CH3)(BF4)

  • Chloro(dinitrogen)hydrido(tetrafluoroborato)bis(triphenylphosphine)iridium(III):Ir(Cl)(N2)(PPh3)2(H)(BF4)

  • Carbonylhydridobis(trifluoromethanesulfonato)bis(triphenylphosphine)iridium(III):Ir(CO)(PPh3)2(H)(O3SCF3)2