Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions

  1. Robert J. Angelici
  1. Michael I. Bruce1,
  2. Brian K. Nicholson2,
  3. Michael L. Williams1,
  4. Thérèse Arliguie3 and
  5. Guy Lavigne3

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132593.ch56

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

How to Cite

Bruce, M. I., Nicholson, B. K., Williams, M. L., Arliguie, T. and Lavigne, G. (1990) Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions, in Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28 (ed R. J. Angelici), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132593.ch56

Editor Information

  1. Department of Chemistry, Iowa State University

Author Information

  1. 1

    Department of Physical and Inorganic Chemistry, University of Adelaide, South Australia, 5001.

  2. 2

    Department of Chemistry, University of Waikato, Hamilton, New Zealand.

  3. 3

    Laboratoire de Chimie de Coordination, CNRS, 31077 Toulouse, France.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1990

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471526193

Online ISBN: 9780470132593

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Keywords:

  • tetranuclear ruthenium carbonyl hydride;
  • hydrogen;
  • carbon monoxide;
  • reduction;
  • cyclohexane

Summary

This chapter contains sections titled:

  • Sodium Benzophenone Ketyl Solution

  • Undecacarbonyl(dimethylphenylphosphine)triruthenium, Ru3(CO)11(PMe2Ph)

  • Decacarbonyl(dimethylphenylphosphine)(2-isocyano-2-methylpropane)triruthenium,Ru3(CO)10(CNBut)(PMe2Ph)

  • Decacarbonyl[methylenebis(diphenylphosphine)]triruthenium, Ru3(CO)10[Ph2P)2CH2]

  • [μ-Ethynediyl-bis(diphenylphosphine)]bis[undecacarbonyltriruthenium],Ru3(CO)11]2[μ-C2(PPh2P)2]

  • Undecacarbonyltetrahydrido[tris(4-methylphenyl)phosphite]tetrarutenium,Ru4H4(CO)11[P(OC6H4Me-p)3]

  • Decacarbonyl(dimethylphenylphosphine)tetrahydrido[tris(4-methylphenyl)phosphite]tetraruthenium, Ru4H4(CO)10(PMe2Ph)[P(OC6H4Me-p)3]