The Synthesis of Molybdenum and Tungsten Dinitrogen Complexes

  1. Robert J. Angelici
  1. Jonathan R. Dilworth1,
  2. Raymond L. Richards1,
  3. Grace J.-J. Chen2 and
  4. John W. Mcdonald2

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132593.ch7

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

How to Cite

Dilworth, J. R., Richards, R. L., Chen, G. J.-J. and Mcdonald, J. W. (1990) The Synthesis of Molybdenum and Tungsten Dinitrogen Complexes, in Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28 (ed R. J. Angelici), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132593.ch7

Editor Information

  1. Department of Chemistry, Iowa State University

Author Information

  1. 1

    A.R.C. Unit of Nitrogen Fixation, University of Sussex, Brighton, Sussex, BN1 9QJ, United Kingdom.

  2. 2

    Charles F. Kettering Research Laboratory, Yellow Springs, OH 45387.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1990

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471526193

Online ISBN: 9780470132593

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Keywords:

  • bis(acetonitrile)tetrachloromolybdenum(IV);
  • tetrachlorobis(tetrafuran)-molybdenum(IV);
  • trichlorotris(tetrahydrofuran)-molybdenum(III);
  • trichlorotris(acetonitrile)-molybdenum(III);
  • tetrahydrofuran-diethyl ether

Summary

This chapter contains sections titled:

  • Bis(acetonitrile)tetrahydrofuran)molybdenum(IV),[MoCl4(CH3CN)2]

  • Tetrachlorobis(tetrahydrofuran)molybdenum(IV),[MoCl4(THF)2]

  • Trichlorotris(tetrahydrofuran)molybdenum(III),[MoCl3(THF)3]

  • Trichlorotris(acetonitril)molybdenum(III),[MoCl3(MeCN)3]

  • trans-Bis(dinitrogen)bis[1,2-ethanediylbis-(diphenylphosphine)]molybdenum(0),trans[Mo(N2)2(Ph2PCH2CH2PPh2)2]

  • Tetrachlorobis(triphenylphosphine)tungsten(IV),[WCl4(PPh3)2]

  • Tetrachloro[1,2-ethanediylbis(diphenylphosphine)]tungsten(IV),[WCl4PCH2CH2PPh2)]

  • trans-Bis(dinitrogen)-bis[1,2-ethanediylbis(diphenylphosphine)]tungsten(0), trans-[W(N2)(Ph2PCH2CH2PPh2)2]