Mixed-Metal-Gold Phosphine Cluster Compounds

  1. Russell N. Grimes
  1. A. M. Mueting1,
  2. B. D. Alexander1,
  3. P. D. Boyle1,
  4. A. L. Casalnuovo1,
  5. L. N. Ito1,
  6. B. J. Johnson1,
  7. L. H. Pignolet1,
  8. M. Leeaphon2,
  9. K. E. Meyer2,
  10. R. A. Walton2,
  11. D. M. Heinekey3 and
  12. T. G. P. Harper3

Published Online: 5 JAN 2007

DOI: 10.1002/9780470132609.ch63

Inorganic Syntheses, Volume 29

Inorganic Syntheses, Volume 29

How to Cite

Mueting, A. M., Alexander, B. D., Boyle, P. D., Casalnuovo, A. L., Ito, L. N., Johnson, B. J., Pignolet, L. H., Leeaphon, M., Meyer, K. E., Walton, R. A., Heinekey, D. M. and Harper, T. G. P. (1992) Mixed-Metal-Gold Phosphine Cluster Compounds, in Inorganic Syntheses, Volume 29 (ed R. N. Grimes), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470132609.ch63

Author Information

  1. 1

    Department of Chemistry, University of Minnestoa, Minneapolis, MN 55455.

  2. 2

    Department of Chemistry, Purdue University, West Lafayette, IN 47907.

  3. 3

    Department of Chemistry, Yale University, New Haven, CT 06520.

Publication History

  1. Published Online: 5 JAN 2007
  2. Published Print: 1 JAN 1992

Book Series:

  1. Inorganic Syntheses

ISBN Information

Print ISBN: 9780471544708

Online ISBN: 9780470132609

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Keywords:

  • nitrato(triphenylphosphine)gold(I);
  • carbonyldi-μ-hydrido-tris(triphenylphosphine)(triphenylphosphinegold)ruthenium(1+)hexafluorophosphate(1-);
  • (nitrato-O,O′)bis(triphenylphosphine)tris(triphenylphosphinegold)iridium(l+) tetrafluoroborate(1-);
  • hexahydridotetrakis(triphenylphosphine)bis(triphenylphosphinegold)dirhenium(1+) tetraphenylborate(1-);
  • inorganic synthesis

Summary

This chapter contains sections titled:

  • Nitrato(triphenylphosphine)gold(I), Au(PPh3)NO3

  • Carbonyldi-μ-hydrido-tris(triphenylphosphine)(triphenylphosphinegold)ruthenium(1 +), Hexafluorophosphate(1 −),[AuRu(H)2(CO)(PPh3)4][PF6]

  • 4-1,5-Cyclooctadiene)bis(triphenylphosphine)iridium(1 +)Tetrafluoroborate(1 −), [Ir(η4-cod)(PPh3)2][BF4]

  • Bis(acetone)dihydridobis(triphenylphosphine)irihium(1 +)Tetrafluoroborate(1 −), [Ir(PPh3)2(H)2(acetone)2][BF4]

  • η-Hydrido(nitrato-O,O′)bis(triphenylphosphine)bis(triphenylphosphinegold)iridium(1 +) Tetrafluoroborate(1 −), [Au2Ir(H)(PPh3)4(NO3)][BF4]

  • (Nitrato-O,O′)bis(triphenylphosphine)tris(triphenylphosphinegold)iridium(1 +)Tetrafluoroborate(1 −)[Au3Ir(PPh3)5(NO3)][BF4]

  • Tri-μ-hydrido-tris(triphenylphosphine)bis(triphenylphosphinegold)osmium(1 +) Hexafluorophosphate(1 −), and Its Ruthenium Analog, [Au2Os(H)3(PPh3)5][PF6]

  • Tetrahydridobis(triphenylphosphine)pantakis(triphenylphosphanegold)rhenium(2 +) Bis[hexafluorophosphate(1 −)], [Au5Re(H)4(PPh3)7][PF6]2

  • Tris[1,2-ethanebis(diphenylpphosphine)]hexahydrido-(nitrato-O,O′-gold)triiridium(1 +) Tetrafluoroborate(1 −), [AuIr3(μ-H)3H3(dppe)3(NO3)][BF4]

  • Hexahydridotetrakis(triphenylphosphine)bis(triphenylphosphinegold)dirhenium(1 +) Tetraphenylborate(1 −), [Au2Re2(H)6(PPh3)6]X

  • Tetrahydridobis(bis[tris(4-methylphenyl)]phosphine)tetrakis(triphenylphposphinegold)rhenium(1 +)Hexafluorophosphate(1 −), [Au4Re(H)4[P(p-tolyl)3]2(PPh3)4][PF6]2

  • (Nitrato-O,O′)bis(tripphenylphosphine)bis(triphenylphosphinegold) Platinum(1 +) Hexafluorophosphate(1 −), [Au2Pt(PPh3)4(NO3)][PF6]

  • (Triphenylphosphine)hexakis(triphenylphosphinegold)Platinum(2 +) Bis[tetraphenylborate(1 −)], [Au6Pt(PPh3)7][PF6]2

  • Di-μ-hydrido-bis(triphenylphosphine)tetrkis(triphenylphosphinegold)iridium(1 +) Tetraphenylborate(1 −), [Au4Ir(H)2(PPh3)6][BF4]