The Stereochemistry of Germanium and Tin Compounds

  1. Gregory L. Geoffroy
  1. Marcel Gielen

Published Online: 26 FEB 2007

DOI: 10.1002/9780470147214.ch5

Topics in Stereochemistry: Topics in Inorganic and Organometallic Stereochemistry, Volume 12

Topics in Stereochemistry: Topics in Inorganic and Organometallic Stereochemistry, Volume 12

How to Cite

Gielen, M. (1981) The Stereochemistry of Germanium and Tin Compounds, in Topics in Stereochemistry: Topics in Inorganic and Organometallic Stereochemistry, Volume 12 (ed G. L. Geoffroy), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470147214.ch5

Editor Information

  1. Pennsylvanrb State University, University Park, Pennsylvania

Author Information

  1. Vrije Universiteit Brussel - T. W. - AOSC, and Université Libre de Bruxelles, Collectif de Chimie Organique Physique, Brussels, Belgium

Publication History

  1. Published Online: 26 FEB 2007
  2. Published Print: 1 JAN 1981

ISBN Information

Print ISBN: 9780471052920

Online ISBN: 9780470147214

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Keywords:

  • optical stability;
  • optically active organogermanium compounds;
  • stereospecific substitution reaction;
  • minimum constraints;
  • stereospecificity

Summary

This chapter contains sections titled:

  • The Optical Stability of RR′R″MX Compounds

  • The Stereochemistry of Substitution Reactions at the Metal Atom of RR′R″-MX Compounds

  • The Intramolecular Rearrangements of Trigonal Bipyramidal Group(IV) Metal Complexes and Their Importance for the Stereochemistry of Substitution Reactions at RR′R″MX Compounds

  • Dynamic Stereochemistry of cis-Octahedral Bis(b̃-diketonato)-group(IV) Metal Complexes