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Chapter 5. Processing of Nanocrystalline Hafnium Carbide Powders

  1. Waltraud M. Kriven,
  2. Hua-Tay Lin
  1. Chang-An Wang,
  2. Michael D. Sacks

Published Online: 27 MAR 2008

DOI: 10.1002/9780470294802.ch5

27th Annual Cocoa Beach Conference on Advanced Ceramics and Composites: A: Ceramic Engineering and Science Proceedings, Volume 24, Issue 3

27th Annual Cocoa Beach Conference on Advanced Ceramics and Composites: A: Ceramic Engineering and Science Proceedings, Volume 24, Issue 3

How to Cite

Wang, C.-A. and Sacks, M. D. (2008) Processing of Nanocrystalline Hafnium Carbide Powders, in 27th Annual Cocoa Beach Conference on Advanced Ceramics and Composites: A: Ceramic Engineering and Science Proceedings, Volume 24, Issue 3 (eds W. M. Kriven and H.-T. Lin), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470294802.ch5

Author Information

  1. Georgia Institute of Technology, Atlanta, GA 30332-0245

Publication History

  1. Published Online: 27 MAR 2008
  2. Published Print: 1 JAN 2003

ISBN Information

Print ISBN: 9780470375839

Online ISBN: 9780470294802

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Keywords:

  • hahiurn carbide;
  • hafnium tetrachloride;
  • carbothermal reduction reaction;
  • hafnium dioxide;
  • tetragonal hafnium oxide

Summary

Hafnium carbide (HfC) powders were produced by the carbothermal reduction reaction of hafnium dioxide and carbon. Fine-scale mixing of the reactants was achieved by using solution processing to synthesize a single-source Hf-O-C precursor. HfC powders with small average crystallite size (-50 nm) were produced at 1475°C, although higher temperature was required to complete the carbothermal reduction reaction.