Chapter 18. Synthesis and Applications of a Vinylsilazane Preceramic Polymer
- John B. Wachtman Jr.
Published Online: 26 MAR 2008
Copyright © 1990 The American Ceramic Society, Inc.
14th Annual Conference on Composites and Advanced Ceramic Materials, Part 2 of 2: Ceramic Engineering and Science Proceedings, Volume 11, Issue 9/10
How to Cite
Toreki, W., Batich, C. D., Sacks, M. D. and Morrone, A. A. (1990) Synthesis and Applications of a Vinylsilazane Preceramic Polymer, in 14th Annual Conference on Composites and Advanced Ceramic Materials, Part 2 of 2: Ceramic Engineering and Science Proceedings, Volume 11, Issue 9/10 (ed J. B. Wachtman), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470313053.ch18
- Published Online: 26 MAR 2008
- Published Print: 1 JAN 1990
Print ISBN: 9780470374931
Online ISBN: 9780470313053
Vinyl polymerization (in bulk and in solution) of a cyclic oligomer of vinyl-methylsilazane (i.e., 1,3,5-trimelhyl-1,3,5-trivinylcyclotrisilazane) was investigated as a method for preparing polymeric precursors to silicon carbide and silicon nitride. After synthesis, the polymers were characterized by size exclusion chromatography and infrared (IR) spectroscopy. Polymers were pyrolyzed under various conditions, and the resulting ceramic products were characterized by IR spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, elemental analysis, helium pycnometry, and gas adsorption surface area analysis. Potential applications for the polymers are discussed.