Chapter 9. Sequence-Specific Hydrogen Bonded Units for Directed Association, Assembly, and Ligation

  1. Vincent M. Rotello and
  2. S. Thayumanavan
  1. Bing Gong

Published Online: 25 FEB 2008

DOI: 10.1002/9780470384053.ch9

Molecular Recognition and Polymers: Control of Polymer Structure and Self-Assembly

Molecular Recognition and Polymers: Control of Polymer Structure and Self-Assembly

How to Cite

Gong, B. (2008) Sequence-Specific Hydrogen Bonded Units for Directed Association, Assembly, and Ligation, in Molecular Recognition and Polymers: Control of Polymer Structure and Self-Assembly (eds V. M. Rotello and S. Thayumanavan), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470384053.ch9

Editor Information

  1. Department of Chemistry, Program in Molecular and Cell Biology, University of Massachusetts, Amherst, 710 North Pleasant Street, Amherst, MA 01003, USA

Author Information

  1. Department of Chemistry, State University of New York, 811 Natural Sciences Complex, Buffalo, NY 14260, USA

Publication History

  1. Published Online: 25 FEB 2008
  2. Published Print: 22 AUG 2008

ISBN Information

Print ISBN: 9780470277386

Online ISBN: 9780470384053

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Keywords:

  • sequence-specific hydrogen bonded units;
  • noncovalent and covalent interaction integration;
  • H bonding sequence programmability and binding strength tunability

Summary

This chapter contains sections titled:

  • Introduction

  • General Design: Information-Storing Molecular Duplexes Based on the Recombination of H Bond Donors and Acceptors

  • Quadruply H Bonded Duplexes with Sequence-Independent Stability

  • Tuning Binding Strength by Varying the Number of Interstrand H Bonds

  • Probing Sequence Specificity

  • Unexpected Discovery: Duplexes Containing Folded Strands

  • Directed Assembly: Formation of β-Sheets and Supramolecular Block Copolymers

  • Integrating Noncovalent and Covalent Interactions: Directed Olefin Metathesis and Disulfide Bond Formation

  • Conclusions and Future Perspectives

  • Acknowledgments

  • References