8. Additional Stereochemical Effects in Carbohydrates

  1. Norman L. Allinger

Published Online: 18 AUG 2010

DOI: 10.1002/9780470608852.ch8

Molecular Structure

Molecular Structure

How to Cite

Allinger, N. L. (2010) Additional Stereochemical Effects in Carbohydrates, in Molecular Structure, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9780470608852.ch8

Publication History

  1. Published Online: 18 AUG 2010
  2. Published Print: 19 JUL 2010

ISBN Information

Print ISBN: 9780470195574

Online ISBN: 9780470608852

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Keywords:

  • carbohydrates and additional stereochemical effects - and hexopyranoses (six-carbon sugars);
  • polyoxyethylene (POE) - polyethylene, made up of series of butane segments;
  • combined anomeric and delta-two effects - using “the cellobiose analog” CBA

Summary

This chapter contains sections titled:

  • Glucose

  • Gauche Effect

  • Delta-Two Effect

  • Glucose Diastereomers

  • Cellobiose Analog

  • External Anomeric Torsional Effect

  • References