Published Online: 15 SEP 2010
Copyright © 2010 John Wiley & Sons, Inc. All rights reserved.
Comprehensive Organic Name Reactions and Reagents
How to Cite
2010. Ferrier-II Rearrangement. Comprehensive Organic Name Reactions and Reagents. 229:1051–1054.
- Published Online: 15 SEP 2010
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The mercury (II) salt-induced or promoted conversion of 5-enopyranosides into cyclohexanones with stereochemical control, by which substituents at positions 3 and 5 are predominantly in a trans relationship, is known as the Ferrier-II rearrangement. This reaction has proven valuable in preparation of carbosugars, myo-inositols, and other natural products.
- palladium dichloride;