Solid-State NMR Studies on Supramolecular Chemistry
Published Online: 15 MAR 2012
Copyright © 2012 John Wiley & Sons, Ltd. All rights reserved.
Supramolecular Chemistry: From Molecules to Nanomaterials
How to Cite
Chierotti, M. R. and Gobetto, R. 2012. Solid-State NMR Studies on Supramolecular Chemistry. Supramolecular Chemistry: From Molecules to Nanomaterials. .
- Published Online: 15 MAR 2012
Solid-state NMR (SSNMR) methods provide new insights in the investigation of the structure and dynamics of condensed phases. Advances in commercial solid-state hardware and the developments of new pulse sequences have been of paramount importance for overcoming the earlier resolution problems and yield spectra sensitive to intra- and intermolecular hydrogen-bonding and π–π interactions. This chapter aims to provide an overview of the recent development of the technique for the study of the structure and dynamics of supramolecular systems paying particular attention to the role of the weak interactions such as hydrogen bonds through NMR chemical shift as well as the through-space dipolar coupling SSNMR investigations.
- hydrogen bond;
- distance measurements;
- structure determination;
- weak intercations;
- constrain determination;
- chemical shift tensor;
- dipolar interaction;