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Solid-State NMR Studies on Supramolecular Chemistry

Techniques

  1. Michele R. Chierotti,
  2. Roberto Gobetto

Published Online: 15 MAR 2012

DOI: 10.1002/9780470661345.smc026

Supramolecular Chemistry: From Molecules to Nanomaterials

Supramolecular Chemistry: From Molecules to Nanomaterials

How to Cite

Chierotti, M. R. and Gobetto, R. 2012. Solid-State NMR Studies on Supramolecular Chemistry. Supramolecular Chemistry: From Molecules to Nanomaterials. .

Author Information

  1. Universitá degli Studi di Torino, Torino, Italy

Publication History

  1. Published Online: 15 MAR 2012

Abstract

Solid-state NMR (SSNMR) methods provide new insights in the investigation of the structure and dynamics of condensed phases. Advances in commercial solid-state hardware and the developments of new pulse sequences have been of paramount importance for overcoming the earlier resolution problems and yield spectra sensitive to intra- and intermolecular hydrogen-bonding and π–π interactions. This chapter aims to provide an overview of the recent development of the technique for the study of the structure and dynamics of supramolecular systems paying particular attention to the role of the weak interactions such as hydrogen bonds through NMR chemical shift as well as the through-space dipolar coupling SSNMR investigations.

Keywords:

  • hydrogen bond;
  • distance measurements;
  • dynamic;
  • structure determination;
  • weak intercations;
  • constrain determination;
  • chemical shift tensor;
  • dipolar interaction;
  • REDOR