Chapter 2. Gas Permeation Parameters and Other Physicochemical Properties of a Polymer of Intrinsic Microporosity (PIM-1)

  1. Yuri Yampolskii5 and
  2. Benny Freeman6
  1. Peter M. Budd1,
  2. Neil B. McKeown2,
  3. Detlev Fritsch3,
  4. Yuri Yampolskii5 and
  5. Victor Shantarovich4

Published Online: 30 JUN 2010

DOI: 10.1002/9780470665626.ch2

Membrane Gas Separation

Membrane Gas Separation

How to Cite

Budd, P. M., McKeown, N. B., Fritsch, D., Yampolskii, Y. and Shantarovich, V. (2010) Gas Permeation Parameters and Other Physicochemical Properties of a Polymer of Intrinsic Microporosity (PIM-1), in Membrane Gas Separation (eds Y. Yampolskii and B. Freeman), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470665626.ch2

Editor Information

  1. 5

    A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Pr., 119991, Moscow, Russia

  2. 6

    University of Texas at Austin, Austin, TX, USA

Author Information

  1. 1

    Organic Materials Innovation Centre, School of Chemistry, University of Manchester, Manchester, M13 9PL, UK

  2. 2

    School of Chemistry, Cardiff University, Cardiff, CF10 3AT, UK

  3. 3

    Institute of Polymer Research, GKSS Research Centre Geesthacht GmbH, Max-Planck-Strasse 1, D-21502 Geesthacht, Germany

  4. 4

    N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 Kosygin Street, 119991 Moscow, Russia

  5. 5

    A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Pr., 119991, Moscow, Russia

Publication History

  1. Published Online: 30 JUN 2010
  2. Published Print: 13 AUG 2010

ISBN Information

Print ISBN: 9780470746219

Online ISBN: 9780470665626

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Keywords:

  • gas permeation parameters and physicochemical properties of polymer of intrinsic microporosity (PIM-1);
  • permeable glassy polymers - with very high free volume;
  • chain mobility constraint - polymer backbone, that cannot easily change conformation;
  • polymer of intrinsic microporosity (PIM);
  • gas adsorption;
  • Brunauer, Emmet, Teller (BET) analysis of adsorption isotherms - surface area calculation;
  • Horvath–Kawazoe method;
  • gas permeation - gas permeation properties of glassy polymers and ‘trade-off’ behaviour;
  • inverse gas chromatography (IGC), polymer of interest acting as stationary phase;
  • positron annihilation lifetime spectroscopy

Summary

This chapter contains sections titled:

  • Introduction

  • The PIM concept

  • Gas Adsorption

  • Gas Permeation

  • Inverse Gas Chromatography

  • Positron Annihilation Lifetime Spectroscopy

  • Conclusions

  • Acknowledgements

  • References