Chapter 3. Heavy Analogs of Carbanions: Si-, Ge-, Sn- and Pb-Centered Anions

  1. Vladimir Ya. Lee and
  2. Akira Sekiguchi

Published Online: 21 JUL 2010

DOI: 10.1002/9780470669266.ch3

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds

How to Cite

Lee, V. Ya. and Sekiguchi, A. (2010) Heavy Analogs of Carbanions: Si-, Ge-, Sn- and Pb-Centered Anions, in Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470669266.ch3

Author Information

  1. Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Japan

Publication History

  1. Published Online: 21 JUL 2010
  2. Published Print: 23 JUL 2010

ISBN Information

Print ISBN: 9780470725436

Online ISBN: 9780470669266

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Keywords:

  • heavy analogs of carbanions - Si-, Ge-, Sn- and Pb-centered anions;
  • alkyl-substituted silyl anions;
  • silyl anions with functional groups - (hydrido)silyllithium derivatives;
  • structure - NMR spectroscopy (condensed phase structure);
  • X-ray crystallography (crystal structure);
  • cyclic anions - silole, germole and stannole anions and dianions;
  • polylithiosilanes - tetralithiosilane;
  • germyl, stannyl and plumbyl anions;
  • reactions and synthetic applications;
  • cyclic and polycyclic anions

Summary

This chapter contains sections titled:

  • Introduction

  • Synthesis

  • Structure

  • Reactions and Synthetic Applications

  • Recent Developments

  • Summary and Outlook

  • References