Chapter 5. Heavy Analogs of Alkenes, 1,3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb

  1. Vladimir Ya. Lee and
  2. Akira Sekiguchi

Published Online: 21 JUL 2010

DOI: 10.1002/9780470669266.ch5

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds

How to Cite

Lee, V. Ya. and Sekiguchi, A. (2010) Heavy Analogs of Alkenes, 1,3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb, in Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470669266.ch5

Author Information

  1. Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Japan

Publication History

  1. Published Online: 21 JUL 2010
  2. Published Print: 23 JUL 2010

ISBN Information

Print ISBN: 9780470725436

Online ISBN: 9780470669266

SEARCH

Keywords:

  • heavy analogs of alkenes, 1,3-dienes, allenes and alkynes - multiply bonded derivatives of Si, Ge, Sn and Pb;
  • stable derivatives - synthesis and structure;
  • alkene heavy analogs - homonuclear compounds;
  • unsaturated hydrocarbons, alkenes, alkynes and dienes - classes of organic compounds;
  • solution structure, NMR spectroscopy - tools elucidating structures in solution;
  • crystallographic parameters of structurally characterized digermenes;
  • four-membered ring compounds - heavy cyclobutenes;
  • germastannene crystal structure;
  • heavy analogs of 1,3-dienes and allenes;
  • new field of stable multiply bonded derivatives - and heavy group 14 elements

Summary

This chapter contains sections titled:

  • Introduction

  • Early Studies: Generation and Identification

  • Stable Derivatives (Synthesis and Structure)

  • Summary and Outlook

  • References