Standard Article

General and Theoretical Aspects of the C[BOND]X bonds (X = F, Cl, Br, I): Integration of Theory and Experiment

Halides, Pseudo-Halides and Azides (1995)

  1. Peter Politzer,
  2. Jane S. Murray

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0001

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Politzer, P. and Murray, J. S. 2009. General and Theoretical Aspects of the C[BOND]X bonds (X = F, Cl, Br, I): Integration of Theory and Experiment. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of New Orleans, Department of Chemistry, New Orleans, Louisiana, USA

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Some Fundamental Properties of the Halogens; the Anomalous Nature of Fluorine
  • 3
    Electronegativity Equalization: Electronegativity and Charge Capacity in Relation to Molecular Properties
  • 4
    Electrostatic Potentials of Organic Molecules Containing Carbon–Halogen Bonds
  • 5
    A General Interaction Properties Function (GIPF): An Approach to Understanding and Predicting Molecular Properties
  • 6
    Strengths of Carbon–Halogen Bonds
  • 7
    Perspectives on Particular Classes of Organic Molecules Containing Carbon–Halogen Bonds
  • 8
    Acknowledgements

Keywords:

  • halogens and flourine anomalous nature;
  • electronegativity equalization;
  • halomethane and halobenzene dipole moments;
  • electrostatic potentials of organic molecules and carbon–halogen bounds;
  • general interaction properties function (GIPF);
  • halogen effects in aromatic systems upon reactivity;
  • carbon–halogen bond strengths;
  • electron-attracting tendency of atom

Featured Compounds

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  1. 1 - 10
Compound 6
Molecular Weight:79.0999
Molecular Formula:C5H5N
InChIKey:Not Available
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Compound 7
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound 8
Molecular Weight:111.1848
Molecular Formula:C7H13N
InChIKey:SBYHFKPVCBCYGV-UHFFFAOYSA-N
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Compound 9
Molecular Weight:112.1729
Molecular Formula:C6H12N2
InChIKey:IMNIMPAHZVJRPE-UHFFFAOYSA-N
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Compound 10
Molecular Weight:62.498
Molecular Formula:C2H3Cl
InChIKey:BZHJMEDXRYGGRV-UHFFFAOYSA-N
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Compound 11
Molecular Weight:78.498
Molecular Formula:C2H3ClO
InChIKey:WBNCHVFLFSFIGK-UHFFFAOYSA-N
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Compound 12
Molecular Weight:321.971
Molecular Formula:C12H4Cl4O2
InChIKey:HGUFODBRKLSHSI-UHFFFAOYSA-N
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Compound 13
Molecular Weight:289.972
Molecular Formula:C12H4Cl4
InChIKey:WOCSOSVVVSBRCE-UHFFFAOYSA-N
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Compound 14
Molecular Weight:256.1526
Molecular Formula:C12H4F4O2
InChIKey:NOZDVIWMUAUYAV-UHFFFAOYSA-N
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Compound 15
Molecular Weight:410.873
Molecular Formula:C12H4Br2Cl2O2
InChIKey:SBSJXPIUKNBZND-UHFFFAOYSA-N
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  1. 1 - 10