Standard Article

Cyclopropyl Homoconjugation—Experimental Facts and Interpretations

Cyclopropyl Group (1995)

  1. Ronald F. Childs1,
  2. Dieter Cremer2,
  3. George Elia3

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0034

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Childs, R. F., Cremer, D. and Elia, G. 2009. Cyclopropyl Homoconjugation—Experimental Facts and Interpretations. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    McMaster University, Department of Chemistry, Hamilton, Ontario, Canada

  2. 2

    University of Göteborg, Department of Theoretical Chemistry, Göteborg, Sweden

  3. 3

    McMaster University, Department of Chemistry, Hamilton, Ontario, Canada

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Homoconjugation in Acyclic Systems
  • 3
    Monohomoaromatic and Homoantiaromatic Cations
  • 4
    Higher Homoaromatic Cations
  • 5
    Neutral Homoaromatic Systems
  • 6
    Homoaromatic Anions
  • 7
    Concluding Remarks
  • 8
    Acknowledgements

Keywords:

  • homoconjugation in acyclic systems;
  • homotropenylium ions;
  • boron analogues of homocyclopropenium ions;
  • higher homo aromatic cations;
  • neutral homoaromatic systems;
  • homo aromatic anions

Featured Compounds

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  1. 1 - 54
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:85.1238
Molecular Formula:C5H9O
InChIKey:GCKAOOUVLWHVCN-UHFFFAOYSA-N
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Compound 9
Molecular Weight:99.1504
Molecular Formula:C6H11O
InChIKey:UNZKLOKNOWXRGC-UHFFFAOYSA-N
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Compound 10
Molecular Weight:71.0972
Molecular Formula:C4H8O
InChIKey:JOVLBDRGXMOJJE-UHFFFAOYSA-N
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Compound 21
Molecular Weight:679.92
Molecular Formula:C24H21Cl6O2Sb
InChIKey:Not Available
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Compound 26
Molecular Weight:112.1696
Molecular Formula:C7H12O
InChIKey:CGZZMOTZOONQIA-UHFFFAOYSA-N
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Compound 27
Molecular Weight:110.1537
Molecular Formula:C7H10O
InChIKey:Not Available
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Compound 28
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:APDZRJZYGWLSEF-UHFFFAOYSA-N
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Compound 29
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:QVWDCTQRORVHHT-UHFFFAOYSA-N
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Compound 30
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:UNELZWLTCBQRGC-UHFFFAOYSA-N
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Compound 31
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:BMYAHGFOXUAXIW-UHFFFAOYSA-N
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53
Molecular Weight:360.34
Molecular Formula:C20H42B2Si2
InChIKey:FSEXPKKUHXFTOR-UHFFFAOYSA-N
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Compound 55
Molecular Weight:320.446
Molecular Formula:C18H24O3S
InChIKey:POPVTRJHRSZQEI-UHFFFAOYSA-N
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Compound 56
Molecular Weight:148.2447
Molecular Formula:C11H16
InChIKey:RPNFTZLYTXXLRA-UHFFFAOYSA-N
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Compound 57
Molecular Weight:208.2967
Molecular Formula:C13H20O2
InChIKey:WBRQBDOQMZDWII-UHFFFAOYSA-N
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Compound 60
Molecular Weight:114.573
Molecular Formula:C6H7Cl
InChIKey:NXQUBTIYCIJYFP-UHFFFAOYSA-N
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Compound 116
Molecular Weight:66.1011
Molecular Formula:C5H6
InChIKey:CGKPQMCLTLUAOW-UHFFFAOYSA-N
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Compound 71-C
Molecular Weight:117.1672
Molecular Formula:C9H10
InChIKey:ZUKQQCSJFOOHJA-UHFFFAOYSA-N
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Compound 74
Molecular Weight:118.1757
Molecular Formula:C9H10
InChIKey:ZMCCSKLGOXNRGF-XCADPSHZSA-N
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Compound 78
Molecular Weight:185.2412
Molecular Formula:C13H13O
InChIKey:NAEHXZRPJLEMDO-UHFFFAOYSA-N
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Compound 79
Molecular Weight:185.2412
Molecular Formula:C13H13O
InChIKey:NAEHXZRPJLEMDO-UHFFFAOYSA-N
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Compound 82
Molecular Weight:65.909
Molecular Formula:C4H7B
InChIKey:JEBJTIXUEPOTAO-UHFFFAOYSA-N
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Compound 91
Molecular Weight:82.1436
Molecular Formula:C6H10
InChIKey:JAPMJSVZDUYFKL-UHFFFAOYSA-N
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 96
Molecular Weight:95.1617
Molecular Formula:C7H12
InChIKey:DIGMLAHFKSCKCI-UHFFFAOYSA-N
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Compound 98
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 101
Molecular Weight:170.1991
Molecular Formula:C10H12F2
InChIKey:MPSSULHDFMPHGB-UHFFFAOYSA-N
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Compound 105
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:CHVJITGCYZJHLR-UHFFFAOYSA-N
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Compound 120
Molecular Weight:104.1491
Molecular Formula:C8H8
InChIKey:VEAPRCKNPMGWCP-UHFFFAOYSA-N
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Compound 106
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:JCIHTLANYGNMGL-UHFFFAOYSA-N
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Compound 107
Molecular Weight:148.2447
Molecular Formula:C11H16
InChIKey:QEGYVNCZOFKWNM-UHFFFAOYSA-N
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Compound 108
Molecular Weight:132.2023
Molecular Formula:C10H12
InChIKey:NBQVIMNMHQYULH-UHFFFAOYSA-N
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Compound 109
Molecular Weight:130.1864
Molecular Formula:C10H10
InChIKey:HLZPNEAXFWPJJG-UHFFFAOYSA-N
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Compound 110
Molecular Weight:267.345
Molecular Formula:C9H10BCl3O2
InChIKey:UOQGVEANVWEGGC-UHFFFAOYSA-N
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Compound 111
Molecular Weight:217.286
Molecular Formula:C5H8BCl3O2
InChIKey:BMYUEWPIDSCXFE-UHFFFAOYSA-N
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Compound 112
Molecular Weight:293.382
Molecular Formula:C11H12BCl3O2
InChIKey:RPHXGBXMENENND-YOKUOFPWSA-N
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Compound 113
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:SAALDVJAFXJQTM-UHFFFAOYSA-N
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Compound 114
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:SAALDVJAFXJQTM-UHFFFAOYSA-N
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Compound 115
Molecular Weight:170.2503
Molecular Formula:C13H14
InChIKey:YRZSUWVUOIYFEH-UHFFFAOYSA-N
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Compound 117
Molecular Weight:216.2772
Molecular Formula:C17H12
InChIKey:FNQKRQMQQQHBTE-PORYWJCVSA-N
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Compound 118
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 119
Molecular Weight:106.165
Molecular Formula:C8H10
InChIKey:JDQMYZVQKVSYEV-UHFFFAOYSA-N
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Compound 121
Molecular Weight:118.1757
Molecular Formula:C9H10
InChIKey:RHNDWILNXCGXLR-UHFFFAOYSA-N
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Compound 122
Molecular Weight:130.1864
Molecular Formula:C10H10
InChIKey:UKFBVTJTKMSPMI-UHFFFAOYSA-N
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Compound 128
Molecular Weight:120.1916
Molecular Formula:C9H12
InChIKey:CDCDYENGTKUCSR-UAOXYDSYSA-N
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Compound 129
Molecular Weight:130.1864
Molecular Formula:C10H10
InChIKey:HKRMLKXSBBQRIM-UHFFFAOYSA-N
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Compound 130
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 134
Molecular Weight:106.165
Molecular Formula:C8H10
InChIKey:VTYQQMGYHHVPMX-UHFFFAOYSA-N
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Compound 135
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:YEHSTKKZWWSIMD-UHFFFAOYSA-N
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  1. 1 - 54