Standard Article

Spiroannulated Cyclopropanes

Cyclopropyl Group (1995)

  1. Kirill A Lukin1,
  2. Nikolai S Zefirov2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0041

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Lukin, K. A. and Zefirov, N. S. 2009. Spiroannulated Cyclopropanes. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    The University of Chicago, Department of Chemistry, Chicago, Illinois, USA

  2. 2

    Moscow State University, Department of Chemistry, Moscow, Russia

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Nomenclature of Spiroannulated Cyclopropanes1
  • 3
    Strain in Spiroannulated Cyclopropanes
  • 4
    Synthesis of Spiroannulated Cyclopropanes
  • 5
    Nonactivated Spiroannulated Cyclopropanes and Some of their Useful Applications
  • 6
    Conjugation between Cyclopropyl Fragments and Its Influence on Chemical Properties of Spiroannulated Cyclopropanes
  • 7
    The Rotanes
  • 8
    Oligomers of Spiroannulated Cyclopropanes: The Triangulanes
  • 9
    Concluding Remarks

Keywords:

  • spiroannulated cyclopropanes;
  • spiroannulated cyclopropane nomenclature;
  • spiroannulated cyclopropane synthesis;
  • non-activated spiroannulated cyclopropanes and useful applications;
  • triangulane chemistry;
  • triangulane geometry;
  • oligomers of spiroannulated cyclopropanes and triangulanes

Featured Compounds

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  1. 1 - 74
Compound 1
Molecular Weight:96.1271
Molecular Formula:C6H8O
InChIKey:OIRNAOWGCPSZCJ-UHFFFAOYSA-N
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Compound 2
Molecular Weight:186.2927
Molecular Formula:C14H18
InChIKey:ZLBMVWRFFRANEE-UHFFFAOYSA-N
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Compound 3
Molecular Weight:122.2075
Molecular Formula:C9H14
InChIKey:LMWNLUONWYANKL-UHFFFAOYSA-N
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Compound 4
Molecular Weight:94.1543
Molecular Formula:C7H10
InChIKey:KGSOURBADOHWIS-UHFFFAOYSA-N
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Compound 5
Molecular Weight:120.1916
Molecular Formula:C9H12
InChIKey:JCHCWAJGYWGXMQ-UHFFFAOYSA-N
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Compound 6
Molecular Weight:118.1757
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7
Molecular Weight:110.1968
Molecular Formula:C8H14
InChIKey:FOEYMRPOKBCNCR-UHFFFAOYSA-N
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Compound 25
Molecular Weight:136.234
Molecular Formula:C10H16
InChIKey:BNGAGYMTAFZQJE-UHFFFAOYSA-N
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Compound 8
Molecular Weight:387.733
Molecular Formula:C5H8Br4
InChIKey:OYSVBCSOQFXYHK-UHFFFAOYSA-N
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Compound 9
Molecular Weight:Not Available
Molecular Formula:(CH2)nC5H8Br2Zn
InChIKey:RECWTCMBWJMQNQ-UHFFFAOYSA-M
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Compound 11
Molecular Weight:106.165
Molecular Formula:C8H10
InChIKey:PQFGODFYRQJZOI-UHFFFAOYSA-N
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Compound 10
Molecular Weight:265.973
Molecular Formula:C8H10Br2
InChIKey:NCJQQVLOQUJZBM-UHFFFAOYSA-N
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Compound 30
Molecular Weight:80.1277
Molecular Formula:C6H8
InChIKey:XSERAKKLXVXZNK-UHFFFAOYSA-N
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Compound 12
Molecular Weight:Not Available
Molecular Formula:(CH2)nC5H6BrLi
InChIKey:DYSGEBGCNMMDIX-UHFFFAOYSA-N
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Compound 13
Molecular Weight:136.191
Molecular Formula:C9H12O
InChIKey:NQVWUSYSEDYIPJ-UHFFFAOYSA-N
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Compound 14
Molecular Weight:282.526
Molecular Formula:C14H26O2Si2
InChIKey:NXQBLEVGHIIRHL-UHFFFAOYSA-N
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Compound 15
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:KPDOKSJMJMDRQA-UHFFFAOYSA-N
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Compound 16
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:KHCZAHBPHDGNJP-UHFFFAOYSA-N
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Compound 17
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:CGEYHDBRZXGTLN-UHFFFAOYSA-N
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Compound 19
Molecular Weight:80.1277
Molecular Formula:C6H8
InChIKey:VIVNOHOCUKALPP-UHFFFAOYSA-N
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Compound 20
Molecular Weight:384.4208
Molecular Formula:C19H28O8
InChIKey:PIJGILVSIHZZQF-XSFCULCASA-N
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Compound 21
Molecular Weight:346.4174
Molecular Formula:C20H26O5
InChIKey:RNTOXPVPCAYUEU-PUBVCBFWSA-N
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Compound 24
Molecular Weight:82.1436
Molecular Formula:C6H10
InChIKey:PGPFRBIKUWKSTJ-UHFFFAOYSA-N
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Compound 22
Molecular Weight:160.2554
Molecular Formula:C12H16
InChIKey:WDWKDXQBNGMXEI-UHFFFAOYSA-N
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Compound 23
Molecular Weight:120.1916
Molecular Formula:C9H12
InChIKey:HAIZYAZVYQEJME-UHFFFAOYSA-N
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Compound 26
Molecular Weight:264.325
Molecular Formula:C16H16N4
InChIKey:BHOROACMNPLJEE-UHFFFAOYSA-N
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Compound 41
Molecular Weight:148.2017
Molecular Formula:C10H12O
InChIKey:NNWHZFLILCVHED-UHFFFAOYSA-N
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Compound 28
Molecular Weight:Not Available
Molecular Formula:(C3H4)nC6H8
InChIKey:HAIZYAZVYQEJME-UHFFFAOYSA-N
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32
Molecular Weight:256.2949
Molecular Formula:C13H20O5
InChIKey:CVCWXWPDDMOJKH-UHFFFAOYSA-N
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Compound 33
Molecular Weight:188.2655
Molecular Formula:C13H16O
InChIKey:FLUHWNBXUITTQS-UHFFFAOYSA-N
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Compound 31
Molecular Weight:200.3193
Molecular Formula:C15H20
InChIKey:LCFIOHZUOXHZOT-UHFFFAOYSA-N
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Compound 35
Molecular Weight:136.234
Molecular Formula:C10H16
InChIKey:DBBFMNVGJYPJQJ-UHFFFAOYSA-N
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Compound 36
Molecular Weight:164.2011
Molecular Formula:C10H12O2
InChIKey:LMKVRCXFLSORDM-UHFFFAOYSA-N
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Compound 37
Molecular Weight:188.3086
Molecular Formula:C14H20
InChIKey:YXLKXDIYZHJACL-UHFFFAOYSA-N
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Compound 34
Molecular Weight:240.3832
Molecular Formula:C18H24
InChIKey:ARNDEESLUSAMAV-UHFFFAOYSA-N
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Compound 38
Molecular Weight:132.2023
Molecular Formula:C10H12
InChIKey:ZWSMNIKJTRMBEM-UHFFFAOYSA-N
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Compound 39
Molecular Weight:296.3238
Molecular Formula:C16H16N4O2
InChIKey:NGSGGILDIWPOHA-UHFFFAOYSA-N
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Compound 40
Molecular Weight:268.3104
Molecular Formula:C16H16N2O2
InChIKey:KAYJFKRLPDLUQG-UHFFFAOYSA-N
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Compound 42
Molecular Weight:172.2661
Molecular Formula:C13H16
InChIKey:ZWLDVWCSALKQCW-UHFFFAOYSA-N
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Compound 43
Molecular Weight:67.1091
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 44
Molecular Weight:144.213
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:66.1011
Molecular Formula:C5H6
InChIKey:GHDAYTRZNHKEBO-UHFFFAOYSA-N
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Compound 46
Molecular Weight:94.1543
Molecular Formula:C7H10
InChIKey:JEATYLXCUMDKCF-UHFFFAOYSA-N
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Compound 47
Molecular Weight:146.2289
Molecular Formula:C11H14
InChIKey:JISOCMQWQHEYKJ-UHFFFAOYSA-N
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Compound 48
Molecular Weight:146.2289
Molecular Formula:C11H14
InChIKey:JISOCMQWQHEYKJ-UHFFFAOYSA-N
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Compound 68
Molecular Weight:251.946
Molecular Formula:C7H8Br2
InChIKey:ZPVWBNKTZAZWFU-UHFFFAOYSA-N
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Compound 69
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:ROYALHAUWKQSRJ-UHFFFAOYSA-N
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Compound 49
Molecular Weight:172.2661
Molecular Formula:C13H16
InChIKey:XXKLNXAAHUXJCP-UHFFFAOYSA-N
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Compound 50
Molecular Weight:146.2289
Molecular Formula:C11H14
InChIKey:NPEJUAGBMRBZMX-UHFFFAOYSA-N
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Compound 51
Molecular Weight:172.2661
Molecular Formula:C13H16
InChIKey:AFIGFBVWRIAFSN-UHFFFAOYSA-N
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 54
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:172.2661
Molecular Formula:C13H16
InChIKey:JAIDMWSIDWSHKI-UHFFFAOYSA-N
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Compound 56
Molecular Weight:118.1757
Molecular Formula:C9H10
InChIKey:HBJCXCICCHOUJO-UHFFFAOYSA-N
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Compound 57
Molecular Weight:276.4153
Molecular Formula:C21H24
InChIKey:HIUHDACVQKGKAJ-UHFFFAOYSA-N
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Compound 58
Molecular Weight:176.2548
Molecular Formula:C12H16O
InChIKey:WGGABDYSOAOBFX-UHFFFAOYSA-N
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Compound 59
Molecular Weight:215.119
Molecular Formula:C11H12Cl2
InChIKey:JBLAKYKDEBEDHM-UHFFFAOYSA-N
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Compound 60
Molecular Weight:330.058
Molecular Formula:C13H14Br2
InChIKey:ZOCRFLORVIJXKD-UHFFFAOYSA-N
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Compound 61
Molecular Weight:224.3407
Molecular Formula:C17H20
InChIKey:CULVVFWBZNSWNL-UHFFFAOYSA-N
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Compound 63
Molecular Weight:202.3352
Molecular Formula:C15H22
InChIKey:MYPLXQOKAVQVOZ-KVVVAFMNSA-N
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Compound 64
Molecular Weight:202.3352
Molecular Formula:C15H22
InChIKey:MYPLXQOKAVQVOZ-PSSVGPPCSA-N
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Compound 65
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 66
Molecular Weight:163.044
Molecular Formula:C7H8Cl2
InChIKey:VOOXWJWCYYVIBZ-UHFFFAOYSA-N
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Compound 67
Molecular Weight:163.044
Molecular Formula:C7H8Cl2
InChIKey:JSAIWPIHQJTWGX-UHFFFAOYSA-N
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Compound 71
Molecular Weight:304.021
Molecular Formula:C11H12Br2
InChIKey:SVBAUKQKZNPADF-UHFFFAOYSA-N
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Compound 72
Molecular Weight:144.213
Molecular Formula:C11H12
InChIKey:YBJGMMCEGRQQGZ-UHFFFAOYSA-N
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Compound 70
Molecular Weight:225.909
Molecular Formula:C5H6Br2
InChIKey:QWEXDICDXAQFPI-UHFFFAOYSA-N
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Compound 73
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 74
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 76
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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  1. 1 - 74