Standard Article

Stereochemistry and Conformation of Organogermanium, Organotin and Organolead Compounds

Organic Germanium, Tin and Lead Compounds (1995)

  1. James A. Marshall,
  2. Jill A. Jablonowski

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0044

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Marshall, J. A. and Jablonowski, J. A. 2009. Stereochemistry and Conformation of Organogermanium, Organotin and Organolead Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of South Carolina, Department of Chemistry and Biochemistry, Columbia, USA

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Chiral Organometallics of Type R1R2R3R4M
  • 3
    Germacyclopentanes and Cyclohexanes
  • 4
    Organometallics of Type R*MR3
  • 5
    Propargyl/Allenyl Systems

Keywords:

  • chiral organometallics of Type R1R2R3R4M;
  • tin and configurational stability;
  • pentacoordinated triorgano halostannanes;
  • germacyclopentanes and cyclohexanes;
  • organometallics of type R*MR3;
  • chiral acyclic systems;
  • propargyl/allenyl systems;
  • germacyclopentanes and cyclohexanes

Featured Compounds

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  1. 1 - 97
Compound 1
Molecular Weight:447.2
Molecular Formula:C27H34GeO
InChIKey:GDTCNPJLRJBFDB-NTDMEQEKSA-N
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Compound 2
Molecular Weight:447.2
Molecular Formula:C27H34GeO
InChIKey:GDTCNPJLRJBFDB-NTDMEQEKSA-N
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Compound R-3
Molecular Weight:292.95
Molecular Formula:C17H16Ge
InChIKey:ANFBSUVYEWPEMX-GOSISDBHSA-N
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Compound S-3
Molecular Weight:292.95
Molecular Formula:C17H16Ge
InChIKey:ANFBSUVYEWPEMX-SFHVURJKSA-N
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Compound 4
Molecular Weight:461.22
Molecular Formula:C28H36GeO
InChIKey:DFGGQGXWHPKFLN-OWVGNBGXSA-N
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Compound R-5
Molecular Weight:306.98
Molecular Formula:C18H18Ge
InChIKey:QLDDRNDIQZOAFE-LJQANCHMSA-N
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Compound R-6
Molecular Weight:321
Molecular Formula:C19H20Ge
InChIKey:VJTLFLBSCLQYEL-HXUWFJFHSA-N
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Compound S-8
Molecular Weight:335.03
Molecular Formula:C20H22Ge
InChIKey:XFRVKBKKWZSMOM-NRFANRHFSA-N
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Compound S-7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound R-8
Molecular Weight:335.03
Molecular Formula:C20H22Ge
InChIKey:XFRVKBKKWZSMOM-OAQYLSRUSA-N
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Compound S-9
Molecular Weight:327.39
Molecular Formula:C17H15ClGe
InChIKey:ZKOHQICBRLTARZ-IBGZPJMESA-N
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Compound 24
Molecular Weight:285.96
Molecular Formula:C15H19GeN
InChIKey:DSCBDORQYURKBO-UHFFFAOYSA-N
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Compound 26
Molecular Weight:305.39
Molecular Formula:C15H17ClGe
InChIKey:JQKZQSMSWHYDMF-UHFFFAOYSA-N
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Compound 10
Molecular Weight:226.85
Molecular Formula:C9H14GeO2
InChIKey:GZJBOOLDZNXDSE-UHFFFAOYSA-N
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Compound 11
Molecular Weight:268.88
Molecular Formula:C11H16GeO3
InChIKey:RHYYRGLMJCNDQJ-UHFFFAOYSA-N
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Compound R-12
Molecular Weight:336.96
Molecular Formula:C18H16GeO2
InChIKey:YVDXTDCBGBHJOZ-LJQANCHMSA-N
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Compound R-15
Molecular Weight:322.97
Molecular Formula:C18H18GeO
InChIKey:UOXJNWIHMUUDMH-LJQANCHMSA-N
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Compound R-13
Molecular Weight:327.39
Molecular Formula:C17H15ClGe
InChIKey:ZKOHQICBRLTARZ-LJQANCHMSA-N
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Compound R-14
Molecular Weight:350.99
Molecular Formula:C19H18GeO2
InChIKey:UCPLQWSPGNCWJO-HXUWFJFHSA-N
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Compound S-13
Molecular Weight:327.39
Molecular Formula:C17H15ClGe
InChIKey:ZKOHQICBRLTARZ-IBGZPJMESA-N
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Compound R-7
Molecular Weight:327.39
Molecular Formula:C17H15ClGe
InChIKey:ZKOHQICBRLTARZ-LJQANCHMSA-N
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Compound R-19
Molecular Weight:475.25
Molecular Formula:C29H38GeO
InChIKey:MYSSRIPPWKPCEK-UOSAEKHLSA-N
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Compound R-17
Molecular Weight:361.07
Molecular Formula:C22H24Ge
InChIKey:OHSZJEGFZFGMAH-HSZRJFAPSA-N
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Compound R-18
Molecular Weight:363.08
Molecular Formula:C22H26Ge
InChIKey:USGFDBBDCPAOKS-HSZRJFAPSA-N
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Compound S-18
Molecular Weight:363.08
Molecular Formula:C22H26Ge
InChIKey:USGFDBBDCPAOKS-QHCPKHFHSA-N
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Compound R-16
Molecular Weight:351.03
Molecular Formula:C20H22GeO
InChIKey:MAMUNCHVZYRZAX-OAQYLSRUSA-N
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Compound S-6
Molecular Weight:321
Molecular Formula:C19H20Ge
InChIKey:VJTLFLBSCLQYEL-FQEVSTJZSA-N
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Compound S-19
Molecular Weight:475.25
Molecular Formula:C29H38GeO
InChIKey:MYSSRIPPWKPCEK-MYZUJYNPSA-N
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Compound R-20
Molecular Weight:623.95
Molecular Formula:C37H34Ge2
InChIKey:QZLMLGNNZHCZSI-KXQOOQHDSA-N
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Compound S-20
Molecular Weight:623.95
Molecular Formula:C37H34Ge2
InChIKey:QZLMLGNNZHCZSI-LHEWISCISA-N
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Compound R-21
Molecular Weight:326.94
Molecular Formula:C19H19GeLi
InChIKey:DSNGLWZNMKKSDN-UHFFFAOYSA-N
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Compound S,S-22
Molecular Weight:639.99
Molecular Formula:C38H38Ge2
InChIKey:NILTYVUHALOOET-ZAQUEYBZSA-N
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Compound S-21
Molecular Weight:326.94
Molecular Formula:C19H19GeLi
InChIKey:DSNGLWZNMKKSDN-UHFFFAOYSA-N
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Compound R,R-22
Molecular Weight:639.99
Molecular Formula:C38H38Ge2
InChIKey:NILTYVUHALOOET-XRSDMRJBSA-N
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Compound 22
Molecular Weight:639.99
Molecular Formula:C38H38Ge2
InChIKey:NILTYVUHALOOET-LQDDJWCHSA-N
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Compound S-23
Molecular Weight:395.08
Molecular Formula:C25H22Ge
InChIKey:AZZICPMUNKSKCN-XAOABQRYSA-N
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Compound R-23
Molecular Weight:395.08
Molecular Formula:C25H22Ge
InChIKey:AZZICPMUNKSKCN-MYXIRXPSSA-N
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Compound 25
Molecular Weight:376.08
Molecular Formula:C22H25GeN
InChIKey:FTQSTHMNILLIFW-UHFFFAOYSA-N
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Compound 28
Molecular Weight:256.92
Molecular Formula:C14H16Ge
InChIKey:SNEFLANTWCBCBH-UHFFFAOYSA-N
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Compound 27
Molecular Weight:339.83
Molecular Formula:C15H16Cl2Ge
InChIKey:NBWJGIRRIBBFEC-UHFFFAOYSA-N
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Compound R-29
Molecular Weight:379.51
Molecular Formula:C17H21ClSn
InChIKey:SRKTYSGNPAERHV-UHFFFAOYSA-M
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Compound R-30
Molecular Weight:345.07
Molecular Formula:C17H22Sn
InChIKey:AJLOASYLSMRYQR-UHFFFAOYSA-N
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Compound S-29
Molecular Weight:379.51
Molecular Formula:C17H21ClSn
InChIKey:SRKTYSGNPAERHV-UHFFFAOYSA-M
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Compound S-30
Molecular Weight:345.07
Molecular Formula:C17H22Sn
InChIKey:AJLOASYLSMRYQR-UHFFFAOYSA-N
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Compound 32
Molecular Weight:455.18
Molecular Formula:C23H28O2Sn
InChIKey:AAEHLPNXWHERBC-UHFFFAOYSA-N
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Compound R-31
Molecular Weight:579.36
Molecular Formula:C31H40O3Sn
InChIKey:XZHKNWGOMZRHKC-KJGOVIRHSA-N
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Compound S-31
Molecular Weight:579.36
Molecular Formula:C31H40O3Sn
InChIKey:XZHKNWGOMZRHKC-KJGOVIRHSA-N
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Compound 33
Molecular Weight:409.19
Molecular Formula:C20H34OSn
InChIKey:PVELWRUBJMFNMK-YVGNHFBQSA-N
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Compound 34
Molecular Weight:345.07
Molecular Formula:C17H22Sn
InChIKey:PNNMOZWRSHQDDP-UHFFFAOYSA-N
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Compound 35
Molecular Weight:375.05
Molecular Formula:C17H20O2Sn
InChIKey:KJAJPHPDUQTHBK-UHFFFAOYSA-N
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Compound 36
Molecular Weight:389.08
Molecular Formula:C18H22O2Sn
InChIKey:BCFCMHQFZZFBMY-UHFFFAOYSA-N
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Compound 37
Molecular Weight:345.07
Molecular Formula:C17H22Sn
InChIKey:AJLOASYLSMRYQR-UHFFFAOYSA-N
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Compound 38
Molecular Weight:387.15
Molecular Formula:C20H28Sn
InChIKey:KEXWIKLVFFLALA-UHFFFAOYSA-N
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Compound 39
Molecular Weight:339.02
Molecular Formula:C17H16Sn
InChIKey:OSQSTSHTIWQVHJ-UHFFFAOYSA-N
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Compound 40
Molecular Weight:401.17
Molecular Formula:C21H30Sn
InChIKey:ZTYWRLFGASFWNG-UHFFFAOYSA-N
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Compound 41
Molecular Weight:379.51
Molecular Formula:C17H21ClSn
InChIKey:SRKTYSGNPAERHV-UHFFFAOYSA-M
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Compound 37D
Molecular Weight:346.07
Molecular Formula:C17H22Sn
InChIKey:Not Available
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Compound 42
Molecular Weight:244.95
Molecular Formula:C9H18Sn
InChIKey:WRZYUASWPWGHHO-UHFFFAOYSA-N
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Compound 43
Molecular Weight:247.97
Molecular Formula:C9H18Sn
InChIKey:Not Available
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Compound R-44
Molecular Weight:365.14
Molecular Formula:C18H30Sn
InChIKey:DUZJLZGZGHLPQD-UHFFFAOYSA-N
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Compound R-45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound S-44
Molecular Weight:365.14
Molecular Formula:C18H30Sn
InChIKey:DUZJLZGZGHLPQD-UHFFFAOYSA-N
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Compound S-45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46
Molecular Weight:688.12
Molecular Formula:C34H42Sn2
InChIKey:JUNQEPBOEFIGAZ-UHFFFAOYSA-N
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Compound 47
Molecular Weight:424.95
Molecular Formula:C16H20BrNSn
InChIKey:CSJTZQGZIJKONC-UHFFFAOYSA-M
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Compound S-48
Molecular Weight:424.95
Molecular Formula:C16H20BrNSn
InChIKey:CSJTZQGZIJKONC-UHFFFAOYSA-M
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Compound R-48
Molecular Weight:424.95
Molecular Formula:C16H20BrNSn
InChIKey:CSJTZQGZIJKONC-UHFFFAOYSA-M
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Compound ent-47
Molecular Weight:424.95
Molecular Formula:C16H20BrNSn
InChIKey:CSJTZQGZIJKONC-UHFFFAOYSA-M
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Compound 49
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 50
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51
Molecular Weight:565.17
Molecular Formula:C25H36BrNOSn
InChIKey:ZBRSGNMDEDFUPQ-YVGNHFBQSA-M
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Compound 53
Molecular Weight:539.14
Molecular Formula:C23H34BrNOSn
InChIKey:NQDXPPWAJRIRIZ-IQRLWNQNSA-M
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Compound 52
Molecular Weight:565.17
Molecular Formula:C25H36BrNOSn
InChIKey:ZBRSGNMDEDFUPQ-YVGNHFBQSA-M
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Compound 54
Molecular Weight:539.14
Molecular Formula:C23H34BrNOSn
InChIKey:NQDXPPWAJRIRIZ-IQRLWNQNSA-M
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Compound 55
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 56
Molecular Weight:303.07
Molecular Formula:C13H28Sn
InChIKey:NJQJEGWULABQKZ-UHFFFAOYSA-N
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Compound 57
Molecular Weight:303.07
Molecular Formula:C13H28Sn
InChIKey:NJQJEGWULABQKZ-UHFFFAOYSA-N
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Compound 58
Molecular Weight:212.91
Molecular Formula:C10H20Ge
InChIKey:QLPYQXBYZADNFU-SECBINFHSA-N
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Compound 59
Molecular Weight:315.61
Molecular Formula:C12H26Ge2
InChIKey:HJVADDACLJMDIC-JHJMLUEUSA-N
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Compound 60
Molecular Weight:395.74
Molecular Formula:C18H34Ge2
InChIKey:KTYJQOYORSEQFH-OQSMONGASA-N
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Compound 61
Molecular Weight:367.07
Molecular Formula:C16H24O2Sn
InChIKey:JFCRBZPITGSTAG-KCOFNFEMSA-N
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Compound 62
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 63
Molecular Weight:367.07
Molecular Formula:C16H24O2Sn
InChIKey:JFCRBZPITGSTAG-KCOFNFEMSA-N
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Compound 64
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 65
Molecular Weight:302.99
Molecular Formula:C11H20O2Sn
InChIKey:WEKVTWHJUUMINU-UHFFFAOYSA-N
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Compound 66
Molecular Weight:292.95
Molecular Formula:C9H18O3Sn
InChIKey:IEWXQTOPZASFPJ-GLTOOAGNSA-N
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Compound 67
Molecular Weight:292.95
Molecular Formula:C9H18O3Sn
InChIKey:IEWXQTOPZASFPJ-VDFGVKJJSA-N
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Compound 68
Molecular Weight:208.2536
Molecular Formula:C12H16O3
InChIKey:ZWUBFGGKRPVPQW-UHFFFAOYSA-N
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Compound 70
Molecular Weight:469.29
Molecular Formula:C23H42O2Sn
InChIKey:ZXVKFBJRDYFGGC-UHFFFAOYSA-N
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Compound 69
Molecular Weight:565.3
Molecular Formula:C25H41F3O3Sn
InChIKey:WZRMSSVVDPZZTH-KCOFNFEMSA-N
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Compound 71
Molecular Weight:529.43
Molecular Formula:C27H54O2Sn
InChIKey:SXWKOUVRXBQNQK-WVLXNHMISA-N
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Compound 72
Molecular Weight:529.43
Molecular Formula:C27H54O2Sn
InChIKey:SXWKOUVRXBQNQK-WVLXNHMISA-N
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Compound 73
Molecular Weight:405.2
Molecular Formula:C18H38O2Sn
InChIKey:XFVNMFHGBUJMIP-NDSUJOINSA-N
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Compound 74
Molecular Weight:210.25
Molecular Formula:C10H10O3S
InChIKey:RMRHABDTSBBNLM-SNVBAGLBSA-N
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Compound 75
Molecular Weight:388.52
Molecular Formula:C22H28O4S
InChIKey:LZXDXUGFPWBXHT-AANPDWTMSA-N
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Compound 76
Molecular Weight:388.52
Molecular Formula:C22H28O4S
InChIKey:LZXDXUGFPWBXHT-LXHROKJGSA-N
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Compound 77
Molecular Weight:705.49
Molecular Formula:C41H44GeO4S
InChIKey:PCSMLUYTRKUMBH-LJEISPKASA-N
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  1. 1 - 97