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The Synthesis of Functionalized Phosphinic and Phosphonic Acids and their Derivatives. Part A: Halo, Hydroxy, Epoxy, Mercapto, Carboxy and Oxo Functionalized Acids

Organophosphorus Compounds (1996)

  1. R. S. Edmundson

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0063

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Edmundson, R. S. 2009. The Synthesis of Functionalized Phosphinic and Phosphonic Acids and their Derivatives. Part A: Halo, Hydroxy, Epoxy, Mercapto, Carboxy and Oxo Functionalized Acids. Patai's Chemistry of Functional Groups. .

Author Information

  1. Leeds, UK

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Halo-Phosphonic and -Phosphinic Acids
  • 3
    Hydroxy-Phosphonic and -Phosphinic Acids
  • 4
    Epoxy-Phosphonic and -Phosphinic Acids
  • 5
    Mercapto-Phosphonic and -Phosphinic Acids
  • 6
    Phosphonoyl- and Phosphinoyl-Alkanoic Acids and their Derivatives
  • 7
    Oxoalkyl-Phosphonic and -Phosphinic Acids

Keywords:

  • halophosphinic and phosphinic acids;
  • synthesis through modifications to carbon ligands;
  • synthesis through phosphorus–carbon bond formation;
  • by replacement of hydroxy groups;
  • by direct halogenation at carbon;
  • by modification through addition reactions;
  • by oxidative haloalkane phosphonation;
  • by chlorophosphonation of alkenes and alkynes;
  • through use of organometallic reagent use