Standard Article

The Chemistry of Organophosphorus Chemical Warfare Agents

Organophosphorus Compounds (1996)

  1. R. M. Black,
  2. J. M. Harrison

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0070

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Black, R. M. and Harrison, J. M. 2009. The Chemistry of Organophosphorus Chemical Warfare Agents. Patai's Chemistry of Functional Groups. .

Author Information

  1. Porton Down, Chemical and Biological Defence Establishment, Wiltshire, Salisbury, UK

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Historical Development
  • 3
    Synthesis
  • 4
    Chemical and Physical Properties
  • 5
    Decontamination
  • 6
    Spectroscopic Analysis
  • 7
    Chromatographic Analysis
  • 8
    Trace Analysis of Nerve Agents and their Degradation Products in Verification
  • 9
    Generic Detection of Nerve Agents
  • 10
    Mechanism of Action
  • 11
    Toxicodynamics
  • 12
    Therapy and Pretreatment
  • 13
    Structure—Toxicity Relationships
  • 14
    Control Under the Chemical Weapons Convention

Keywords:

  • chemistry of organophosphorus chemical warfare agents;
  • methylphosphonofluoridates;
  • classical methods of synthesis;
  • V-agents;
  • enzyme methods;
  • chemical and physical properties;
  • DFP and Tabun synthesis;
  • Resolution—V-agents, G-agents

Featured Compounds

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  1. 1 - 54
Compound 1
Molecular Weight:162.1268
Molecular Formula:C5H11N2O2P
InChIKey:Not Available
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Compound 2
Molecular Weight:126.0666
Molecular Formula:C3H8FO2P
InChIKey:RIYPSXBGLXRZNJ-UHFFFAOYSA-N
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Compound 3
Molecular Weight:140.0932
Molecular Formula:C4H10FO2P
InChIKey:Not Available
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Compound 4
Molecular Weight:182.1729
Molecular Formula:C7H16FO2P
InChIKey:Not Available
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Compound 5
Molecular Weight:184.1457
Molecular Formula:C6H14FO3P
InChIKey:Not Available
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Compound 6
Molecular Weight:269.341
Molecular Formula:C10H24NO3PS
InChIKey:PJISLFCKHOHLLP-UHFFFAOYSA-N
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Compound 7
Molecular Weight:269.341
Molecular Formula:C10H24NO3PS
InChIKey:MQPTUFFJIGGQGB-UHFFFAOYSA-N
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Compound 8
Molecular Weight:267.368
Molecular Formula:C11H26NO2PS
InChIKey:JJIUCEJQJXNMHV-UHFFFAOYSA-N
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Compound 9
Molecular Weight:180.157
Molecular Formula:C7H14FO2P
InChIKey:SNTRKUOVAPUGAY-UHFFFAOYSA-N
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Compound 10
Molecular Weight:132.914
Molecular Formula:CH3Cl2OP
InChIKey:SCLFRABIDYGTAZ-UHFFFAOYSA-N
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Compound 11
Molecular Weight:100.0045
Molecular Formula:CH3F2OP
InChIKey:PQIOSYKVBBWRRI-UHFFFAOYSA-N
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Compound 12
Molecular Weight:116.914
Molecular Formula:CH3Cl2P
InChIKey:CDPKWOKGVUHZFR-UHFFFAOYSA-N
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Compound 13
Molecular Weight:137.333
Molecular Formula:Cl3P
InChIKey:FAIAAWCVCHQXDN-UHFFFAOYSA-N
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Compound 14
Molecular Weight:166.1553
Molecular Formula:C6H15O3P
InChIKey:BLKXLEPPVDUHBY-UHFFFAOYSA-N
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Compound 15
Molecular Weight:200.6
Molecular Formula:C6H14ClO3P
InChIKey:GUFGWNUUDBGEGH-UHFFFAOYSA-N
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Compound 16
Molecular Weight:153.332
Molecular Formula:Cl3OP
InChIKey:XHXFXVLFKHQFAL-UHFFFAOYSA-N
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Compound 17
Molecular Weight:136.878
Molecular Formula:Cl2FOP
InChIKey:YNECJZSONMVFHE-UHFFFAOYSA-N
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Compound 18
Molecular Weight:161.955
Molecular Formula:C2H6Cl2NOP
InChIKey:YNHXBEVSSILHPI-UHFFFAOYSA-N
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Compound 19
Molecular Weight:174.0294
Molecular Formula:C2H8O5P2
InChIKey:CCQOIBGABQRPJK-UHFFFAOYSA-N
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Compound 20
Molecular Weight:321.161
Molecular Formula:CH3AlCl7P
InChIKey:IEFRNHDPSFFSEP-UHFFFAOYSA-J
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Compound 22
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 21
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 23
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 25
Molecular Weight:118.515
Molecular Formula:ClFO2S
InChIKey:IXPAAHZTOUOJJM-UHFFFAOYSA-N
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Compound 26
Molecular Weight:240.879
Molecular Formula:C3H9Al2Cl4
InChIKey:VWZBCCLCYOSYEC-UHFFFAOYSA-J
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Compound 27
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:367.228
Molecular Formula:C9H23INO2PS
InChIKey:SWRKBUGJWNPDJT-BTQNPOSSSA-M
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Compound 31
Molecular Weight:176.15
Molecular Formula:C4H10NaO2PS
InChIKey:JEPFQIUZULLGOT-OGFXRTJISA-M
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Compound 34
Molecular Weight:140.0932
Molecular Formula:C4H10FO2P
InChIKey:DYAHQFWOVKZOOW-MRVPVSSYSA-N
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Compound 32
Molecular Weight:182.221
Molecular Formula:C6H15O2PS
InChIKey:NUIKPDZWPJNTCE-SECBINFHSA-N
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Compound 33
Molecular Weight:166.1553
Molecular Formula:C6H15O3P
InChIKey:WTROTLSCVGMDKH-SNVBAGLBSA-N
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 38
Molecular Weight:153.1167
Molecular Formula:C4H12NO3P
InChIKey:ZAMDBRIEKCKJBM-UHFFFAOYSA-N
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Compound 39
Molecular Weight:155.1078
Molecular Formula:C4H11FNO2P
InChIKey:JYXIMOLVBWANAH-UHFFFAOYSA-N
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Compound 40
Molecular Weight:98.0134
Molecular Formula:CH4FO2P
InChIKey:XQGIZQWEZVJRDD-UHFFFAOYSA-N
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Compound 41
Molecular Weight:239.315
Molecular Formula:C9H22NO2PS
InChIKey:UOXJNGFFPMOZDM-UHFFFAOYSA-N
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Compound 42
Molecular Weight:124.0755
Molecular Formula:C3H9O3P
InChIKey:UFZOPKFMKMAWLU-UHFFFAOYSA-N
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Compound 44
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:154.1015
Molecular Formula:C4H11O4P
InChIKey:OVJINGLXJWTWBM-UHFFFAOYSA-N
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Compound 46
Molecular Weight:212.1806
Molecular Formula:C7H17O5P
InChIKey:HAWPIZIMCDPZGJ-UHFFFAOYSA-N
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Compound 48
Molecular Weight:125.0581
Molecular Formula:C3H7FO2P
InChIKey:LXQZDMVTLQTWIQ-UHFFFAOYSA-N
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Compound 49
Molecular Weight:99.0208
Molecular Formula:CH5FO2P
InChIKey:JNXMBKPIISQTAH-UHFFFAOYSA-N
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Compound 50
Molecular Weight:81.0055
Molecular Formula:CH3FOP
InChIKey:NHECROQTANGFLT-UHFFFAOYSA-N
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Compound 51
Molecular Weight:232.257
Molecular Formula:C8H13N2O4S
InChIKey:WWZYJJGFUIAWNW-UHFFFAOYSA-N
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Compound 52
Molecular Weight:446.137
Molecular Formula:C15H18Br2N4O2
InChIKey:JHZHWVQTOXIXIV-UHFFFAOYSA-N
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Compound 53
Molecular Weight:359.208
Molecular Formula:C14H16Cl2N4O3
InChIKey:QELSIJXWEROXOE-UHFFFAOYSA-N
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Compound 54
Molecular Weight:521.522
Molecular Formula:C17H25N5O10S2
InChIKey:XLJDHNWDIFYIHX-UHFFFAOYSA-N
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Compound 55
Molecular Weight:261.116
Molecular Formula:C9H13BrN2O2
InChIKey:VNYBTNPBYXSMOO-UHFFFAOYSA-M
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Compound 56
Molecular Weight:261.3196
Molecular Formula:C14H19N3O2
InChIKey:KFIIABIGRKUSOL-MFKMUULPSA-N
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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  1. 1 - 54