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The Synthesis and Uses of Isotopically Labelled Amino and Quaternary Ammonium Salts

Amino, Nitroso, Nitro and Related Groups (1996)

  1. Kenneth C. Westaway

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0090

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Westaway, K. C. 2009. The Synthesis and Uses of Isotopically Labelled Amino and Quaternary Ammonium Salts. Patai's Chemistry of Functional Groups. .

Author Information

  1. Laurentian University, Department of Chemistry, Ontario, Canada

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    The Theory of Kinetic Isotope Effects
  • 3
    Using Kinetic Isotope Effects to Elucidate the Mechanism of Benzidine-Type Rearrangements of Amines
  • 4
    Using Kinetic Isotope Effects to Model the SN2 Transition States for Reactions Involving Quaternary Ammonium Salts

Keywords:

  • isotopically labelled amino and quaternary ammonium salts - synthesis and uses;
  • kinetic isotope effects theory;
  • primary hydrogen deuterium kinetic isotope effects;
  • inverse secondary hydrogen deuterium kinetic isotope effect;
  • nitrogen isotope effects and whole-molecule isotope ratio mass spectrometry;
  • nitrogen, carbon-13 and carbon-14 kinetic isotope effects;
  • BEBOVIB IV calculations modeling transition state;
  • secondary alpha deuterium and primary leaving group nitrogen kinetic isotope effects

Featured Compounds

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  1. 1 - 12
Compound 2
Molecular Weight:184.2371
Molecular Formula:C12H12N2
InChIKey:Not Available
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Compound 11
Molecular Weight:184.2371
Molecular Formula:C12H12N2
InChIKey:Not Available
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Compound 3
Molecular Weight:184.2371
Molecular Formula:C12H12N2
InChIKey:RDMFEHLCCOQUMH-UHFFFAOYSA-N
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Compound 12
Molecular Weight:184.2371
Molecular Formula:C12H12N2
InChIKey:RDMFEHLCCOQUMH-UHFFFAOYSA-N
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Compound 4
Molecular Weight:214.2631
Molecular Formula:C13H14N2O
InChIKey:RBLUJIWKMSZIMK-UHFFFAOYSA-N
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Compound 5
Molecular Weight:214.2631
Molecular Formula:C13H14N2O
InChIKey:CADHKBANACADRO-UHFFFAOYSA-N
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Compound 9
Molecular Weight:218.682
Molecular Formula:C12H11ClN2
InChIKey:NLGIEISQJFZTIS-UHFFFAOYSA-N
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Compound 6
Molecular Weight:127.572
Molecular Formula:C6H6ClN
InChIKey:QSNSCYSYFYORTR-UHFFFAOYSA-N
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Compound 7
Molecular Weight:251.111
Molecular Formula:C12H8Cl2N2
InChIKey:XHQLXCFUPJSGOE-FOCLMDBBSA-N
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Compound 8
Molecular Weight:253.127
Molecular Formula:C12H10Cl2N2
InChIKey:GQLZJDIJIIFRPK-UHFFFAOYSA-N
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Compound 10
Molecular Weight:255.142
Molecular Formula:C12H10Cl2N2
InChIKey:XHUVPEWMZVWVQZ-UHFFFAOYSA-P
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Compound 13
Molecular Weight:292.171
Molecular Formula:C14H14BrNO
InChIKey:QZZOSJVUQNHXGO-UHFFFAOYSA-N
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  1. 1 - 12