Standard Article

The Effect of Pressure on Reactions of Dienes and Polyenes

Dienes and Polyenes (1997)

  1. Frank-Gerrit Klärner,
  2. Matthias K. Diedrich

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0108

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Klärner, F.-G. and Diedrich, M. K. 2009. The Effect of Pressure on Reactions of Dienes and Polyenes. Patai's Chemistry of Functional Groups. .

Author Information

  1. Universität Gesamthochschule Essen, Institut für Organische Chemie, Essen, Germany

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Volume of Activation and Reaction
  • 3
    Cycloadditions
  • 4
    Pericyclic Rearrangements
  • 5
    Miscellaneous Reactions of Dienes and Polyenes
  • 6
    Concluding Remarks
  • 7
    Acknowledgements

Keywords:

  • volume of activation and reaction;
  • pressure effect on diene and polyene reactions;
  • cycloadditions;
  • heteroaromatic compounds - furans, pyrroles or thiophenes;
  • Diels Alder reactions of tropones as dienes;
  • higher cycloadditions and trienes and tetraenes;
  • catalyzed Diels Alder reactions;
  • pericyclic rearrangements

Featured Compounds

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  1. 1 - 85
Compound 51a
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:QVWDCTQRORVHHT-UHFFFAOYSA-N
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Compound 1
Molecular Weight:88.536
Molecular Formula:C4H5Cl
InChIKey:YACLQRRMGMJLJV-UHFFFAOYSA-N
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Compound 7
Molecular Weight:80.1277
Molecular Formula:C6H8
InChIKey:Not Available
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Compound 2
Molecular Weight:177.071
Molecular Formula:C8H10Cl2
InChIKey:REOYRKVGKWJQOY-UHFFFAOYSA-N
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Compound 3
Molecular Weight:177.071
Molecular Formula:C8H10Cl2
InChIKey:RRBHRPHCJASXKZ-UHFFFAOYSA-N
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Compound 4
Molecular Weight:177.071
Molecular Formula:C8H10Cl2
InChIKey:WCSPZPSVAKHCMG-UHFFFAOYSA-N
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Compound 5
Molecular Weight:177.071
Molecular Formula:C8H10Cl2
InChIKey:KDUDIFZXLKGGSI-YUMQZZPRSA-N
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Compound 6
Molecular Weight:177.071
Molecular Formula:C8H10Cl2
InChIKey:KDUDIFZXLKGGSI-OCAPTIKFSA-N
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Compound 8
Molecular Weight:160.2554
Molecular Formula:C12H16
InChIKey:OPOFYMSEXICFOW-MMVSWEMESA-N
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Compound 9
Molecular Weight:160.2554
Molecular Formula:C12H16
InChIKey:AIERRONNQKQUME-KIYNQFGBSA-N
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Compound 10
Molecular Weight:160.2554
Molecular Formula:C12H16
InChIKey:OPOFYMSEXICFOW-HCWSGVFWSA-N
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Compound 11
Molecular Weight:160.2554
Molecular Formula:C12H16
InChIKey:PNSGRIVSGNAUDG-QKEWWQLBSA-N
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Compound 12
Molecular Weight:160.2554
Molecular Formula:C12H16
InChIKey:PNSGRIVSGNAUDG-QKEWWQLBSA-N
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Compound 13
Molecular Weight:54.0904
Molecular Formula:C4H6
InChIKey:KAKZBPTYRLMSJV-UHFFFAOYSA-N
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Compound 14
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:Not Available
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Compound 15
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:UHHCYAAVGADGGP-GVHYBUMESA-N
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Compound 16
Molecular Weight:108.1809
Molecular Formula:C8H12
InChIKey:Not Available
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Compound 17
Molecular Weight:130.1433
Molecular Formula:C9H6O
InChIKey:Not Available
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Compound 18
Molecular Weight:316.4776
Molecular Formula:C21H32O2
InChIKey:MEQSJWRGVQAVJY-HMXCVIKNSA-N
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Compound 19
Molecular Weight:414.5345
Molecular Formula:C25H34O5
InChIKey:BEUFZAIVBOZSEG-YBVSRZJMSA-N
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Compound 20
Molecular Weight:414.5345
Molecular Formula:C25H34O5
InChIKey:MDHKZLNRGUXUAV-RLNXEHRBSA-N
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Compound 21
Molecular Weight:316.4776
Molecular Formula:C21H32O2
InChIKey:SGPKKYHABMKBPF-YWQIWOKJSA-N
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Compound 22
Molecular Weight:489.6457
Molecular Formula:C31H39NO4
InChIKey:FXYXHAIEKJFJKK-UOLNHJNBSA-N
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Compound 23
Molecular Weight:190.2814
Molecular Formula:C13H18O
InChIKey:KZWXZXRYXARECB-OLZOCXBDSA-N
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Compound 24
Molecular Weight:288.3383
Molecular Formula:C17H20O4
InChIKey:BTHDCVWRZZVAES-WBIFSWSFSA-N
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Compound 25
Molecular Weight:288.3383
Molecular Formula:C17H20O4
InChIKey:BTHDCVWRZZVAES-GMEHOMJHSA-N
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Compound 27a
Molecular Weight:128.1705
Molecular Formula:C10H8
InChIKey:CUFNKYGDVFVPHO-UHFFFAOYSA-N
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Compound 27
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 27b
Molecular Weight:142.1971
Molecular Formula:C11H10
InChIKey:WSQIUQGZWDQMEL-UHFFFAOYSA-N
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Compound 27c
Molecular Weight:170.2503
Molecular Formula:C13H14
InChIKey:RUNBRXWUHPOTOO-UHFFFAOYSA-N
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Compound 27d
Molecular Weight:156.2237
Molecular Formula:C12H12
InChIKey:LHUAPYYTVFDUKN-UHFFFAOYSA-N
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Compound 27e
Molecular Weight:170.2503
Molecular Formula:C13H14
InChIKey:LHJYMASHUCFWKK-UHFFFAOYSA-N
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Compound 27f
Molecular Weight:170.2503
Molecular Formula:C13H14
InChIKey:PJQZUJWACMAGJJ-UHFFFAOYSA-N
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Compound 27g
Molecular Weight:184.2768
Molecular Formula:C14H16
InChIKey:XAEZWHYYUCDIAT-UHFFFAOYSA-N
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Compound 27h
Molecular Weight:198.3034
Molecular Formula:C15H18
InChIKey:FWKQNCXZGNBPFD-UHFFFAOYSA-N
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Compound 27i
Molecular Weight:198.3034
Molecular Formula:C15H18
InChIKey:MVQMUQBJJIHQGS-UHFFFAOYSA-N
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Compound 27k
Molecular Weight:240.3832
Molecular Formula:C18H24
InChIKey:JYIYZQYIDFBWJR-UHFFFAOYSA-N
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Compound 32c
Molecular Weight:312.3597
Molecular Formula:C19H20O4
InChIKey:WCAFWSBCSAHUHV-MHWRWJLKSA-N
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Compound 32g
Molecular Weight:326.3863
Molecular Formula:C20H22O4
InChIKey:LSSWLIBZYORVRJ-MHWRWJLKSA-N
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Compound 32h
Molecular Weight:340.4129
Molecular Formula:C21H24O4
InChIKey:XEKBMEPRVKNNFU-WOJGMQOQSA-N
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Compound 33c
Molecular Weight:286.3224
Molecular Formula:C17H18O4
InChIKey:OXCORSCVCGZVJL-UHFFFAOYSA-N
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Compound 34
Molecular Weight:154.2078
Molecular Formula:C12H10
InChIKey:AZBGWNFFBVLTKT-UHFFFAOYSA-N
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Compound 36
Molecular Weight:306.3202
Molecular Formula:C20H10N4
InChIKey:BOILJJPFVNUGNN-UHFFFAOYSA-N
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Compound 37
Molecular Weight:306.3202
Molecular Formula:C20H10N4
InChIKey:AAUFQDHHRUUHKS-UHFFFAOYSA-N
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Compound 38
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 39
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 40
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 41
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 42
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:156.2237
Molecular Formula:C12H12
InChIKey:RDGWXWRIVOVEAN-UHFFFAOYSA-N
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Compound 44
Molecular Weight:146.1858
Molecular Formula:C10H10O
InChIKey:JKUZBZCEYNHDLS-UHFFFAOYSA-N
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Compound 46
Molecular Weight:378.547
Molecular Formula:C26H34O2
InChIKey:MRIPPQMFDPCVPP-UHFFFAOYSA-N
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Compound 47
Molecular Weight:913.3176
Molecular Formula:C64H80O4
InChIKey:LLHOXVHGNOBREP-UHFFFAOYSA-N
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Compound 50
Molecular Weight:660.6638
Molecular Formula:C36H36O12
InChIKey:XTFILFGDVAIKCJ-UHFFFAOYSA-N
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Compound 48
Molecular Weight:188.2225
Molecular Formula:C12H12O2
InChIKey:TXLTWPYNXMSPDX-UHFFFAOYSA-N
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Compound 49
Molecular Weight:330.3319
Molecular Formula:C18H18O6
InChIKey:MPUAHBJGOASHJJ-UHFFFAOYSA-N
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Compound 44a
Molecular Weight:210.228
Molecular Formula:C14H10O2
InChIKey:KGWFDDIOZVPOTL-KPWCQOOUSA-N
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Compound 51
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 53
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 54
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 56
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 51b
Molecular Weight:122.1213
Molecular Formula:C7H6O2
InChIKey:MDYOLVRUBBJPFM-UHFFFAOYSA-N
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Compound 51c
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:IQYJSKNHDZZDGA-UHFFFAOYSA-N
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Compound 51d
Molecular Weight:140.567
Molecular Formula:C7H5ClO
InChIKey:MTHNMAUDCHXFMM-UHFFFAOYSA-N
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Compound 63
Molecular Weight:198.2604
Molecular Formula:C14H14O
InChIKey:WCYSFEBMRLLDGZ-UHFFFAOYSA-N
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Compound 61
Molecular Weight:170.1674
Molecular Formula:C10H6N2O
InChIKey:LKWMPUFCEXWBNY-UHFFFAOYSA-N
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Compound 66
Molecular Weight:300.3538
Molecular Formula:C20H16N2O
InChIKey:NJHKFWBULFHOBT-UHFFFAOYSA-N
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Compound 62
Molecular Weight:170.1674
Molecular Formula:C10H6N2O
InChIKey:PIERVLXWTWFHCU-UHFFFAOYSA-N
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Compound 64
Molecular Weight:300.3538
Molecular Formula:C20H16N2O
InChIKey:YXVAEBUUZYFJPI-UHFFFAOYSA-N
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Compound 65
Molecular Weight:300.3538
Molecular Formula:C20H16N2O
InChIKey:DQEMQDXBDGCUPP-UHFFFAOYSA-N
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Compound 68
Molecular Weight:248.2793
Molecular Formula:C16H12N2O
InChIKey:GAKCOGXKAIEUTI-UHFFFAOYSA-N
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Compound 69
Molecular Weight:274.3166
Molecular Formula:C18H14N2O
InChIKey:ACURAXZUEMWJJJ-UHFFFAOYSA-N
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Compound 72
Molecular Weight:274.3166
Molecular Formula:C18H14N2O
InChIKey:GMXXACAOFNJIMM-UHFFFAOYSA-N
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Compound 70
Molecular Weight:274.3166
Molecular Formula:C18H14N2O
InChIKey:PFYHCVJCCNKOJL-UHFFFAOYSA-N
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Compound 59
Molecular Weight:187.1947
Molecular Formula:C11H9NO2
InChIKey:ZLBVPKUDXBDIPP-UHFFFAOYSA-N
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Compound 60
Molecular Weight:187.1947
Molecular Formula:C11H9NO2
InChIKey:ZLBVPKUDXBDIPP-UHFFFAOYSA-N
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Compound 71
Molecular Weight:350.3728
Molecular Formula:C22H14N4O
InChIKey:PLJMTWLLJNCYBG-UHFFFAOYSA-N
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