Standard Article

Allenyl and Polyenyl Cations

Dienes and Polyenes (1997)

  1. L. R. Subramanian

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0115

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Subramanian, L. R. 2009. Allenyl and Polyenyl Cations. Patai's Chemistry of Functional Groups. .

Author Information

  1. Eberhard-Karls-Universität Tübingen, Institut für Organische Chemie, Tübingen, Germany

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Allenyl Cations
  • 3
    Butatrienyl Cations

Keywords:

  • allenyl and polyenyl cations;
  • allenyl cations by allenic derivative solvolysis;
  • allenyl cations;
  • ferrocenyl-substituted allenyl cations;
  • Meyer Schuster rearrangement;
  • spectroscopic allenyl cation identification;
  • butatrienyl cations;
  • 13C-NMR chemical shifts of tris(ethynyl)methyl cations

Featured Compounds

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  1. 1 - 108
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9'
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8a
Molecular Weight:298.3777
Molecular Formula:C22H18O
InChIKey:RIAXKBQNFHZEPR-UHFFFAOYSA-N
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Compound 6a
Molecular Weight:302.797
Molecular Formula:C21H15Cl
InChIKey:QIGOWOWZGHXRGX-UHFFFAOYSA-N
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Compound 6b
Molecular Weight:330.85
Molecular Formula:C23H19Cl
InChIKey:HSJBUVYOWFGTIR-UHFFFAOYSA-N
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Compound 6c
Molecular Weight:332.823
Molecular Formula:C22H17ClO
InChIKey:LPBAGMGKIRDEDK-UHFFFAOYSA-N
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Compound 8b
Molecular Weight:326.4309
Molecular Formula:C24H22O
InChIKey:AHJWCVVKSSNDPF-UHFFFAOYSA-N
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Compound 8c
Molecular Weight:328.4037
Molecular Formula:C23H20O2
InChIKey:FHHAMHRFTKFKJW-UHFFFAOYSA-N
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Compound 9a
Molecular Weight:268.3517
Molecular Formula:C21H16
InChIKey:DHMMQGOHHYFZBU-UHFFFAOYSA-N
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Compound 9'a
Molecular Weight:268.3517
Molecular Formula:C21H16
InChIKey:IQLRZAPROBSSMX-UHFFFAOYSA-N
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Compound 9b
Molecular Weight:296.4049
Molecular Formula:C23H20
InChIKey:QDSBIDZQTGAWMK-UHFFFAOYSA-N
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Compound 9'b
Molecular Weight:296.4049
Molecular Formula:C23H20
InChIKey:JWKUQFZZKLVDET-UHFFFAOYSA-N
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Compound 9c
Molecular Weight:298.3777
Molecular Formula:C22H18O
InChIKey:AJZZCVXXEWYWFE-UHFFFAOYSA-N
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Compound 9'c
Molecular Weight:298.3777
Molecular Formula:C22H18O
InChIKey:RUTKEBDFDWYYDL-UHFFFAOYSA-N
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Compound 10
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 12
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 13
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10a
Molecular Weight:302.797
Molecular Formula:C21H15Cl
InChIKey:QIGOWOWZGHXRGX-UHFFFAOYSA-N
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Compound 10b
Molecular Weight:330.85
Molecular Formula:C23H19Cl
InChIKey:HSJBUVYOWFGTIR-UHFFFAOYSA-N
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Compound 11a
Molecular Weight:325.426
Molecular Formula:C22H15NS
InChIKey:QKYPCIKPMKZCGX-UHFFFAOYSA-N
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Compound 11b
Molecular Weight:353.479
Molecular Formula:C24H19NS
InChIKey:QGGLTFAEIDQFOE-UHFFFAOYSA-N
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Compound 12a
Molecular Weight:388.545
Molecular Formula:C24H20OS2
InChIKey:XHWHZHQGBGFEBW-UHFFFAOYSA-N
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Compound 12b
Molecular Weight:416.598
Molecular Formula:C26H24OS2
InChIKey:ZVVSYQPFRFMFHC-UHFFFAOYSA-N
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Compound 13a
Molecular Weight:327.3759
Molecular Formula:C22H17NO2
InChIKey:KQGFAQVUBAQFEK-UHFFFAOYSA-N
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Compound 13b
Molecular Weight:355.429
Molecular Formula:C24H21NO2
InChIKey:RXBDPRJMJRRQFI-UHFFFAOYSA-N
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Compound 14a
Molecular Weight:283.3664
Molecular Formula:C21H17N
InChIKey:UOULLNIASMUIHM-UHFFFAOYSA-N
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Compound 14b
Molecular Weight:311.4195
Molecular Formula:C23H21N
InChIKey:UXSUCERMAMZJER-UHFFFAOYSA-N
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Compound 15
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 16
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 15a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 15b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 17b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18b
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 19
Molecular Weight:302.797
Molecular Formula:C21H15Cl
InChIKey:QIGOWOWZGHXRGX-UHFFFAOYSA-N
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Compound 22a
Molecular Weight:523.566
Molecular Formula:C29H24F3NO3S
InChIKey:PULXTKMGUDKUEW-UHFFFAOYSA-N
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Compound 20
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 21
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 23
Molecular Weight:373.4889
Molecular Formula:C28H23N
InChIKey:QUPXKVBNRLLZDW-UHFFFAOYSA-N
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Compound 22b
Molecular Weight:509.539
Molecular Formula:C28H22F3NO3S
InChIKey:SPWUZBATTQOXML-UHFFFAOYSA-N
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Compound 22
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24
Molecular Weight:270.796
Molecular Formula:C18H19Cl
InChIKey:PZGJLLKTPAZIGD-UHFFFAOYSA-N
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Compound 25
Molecular Weight:270.796
Molecular Formula:C18H19Cl
InChIKey:INVLLGOJRKBNIY-UHFFFAOYSA-N
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Compound 27
Molecular Weight:124.1803
Molecular Formula:C8H12O
InChIKey:VJKHTMGYHCBXHV-UHFFFAOYSA-N
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:98.143
Molecular Formula:C6H10O
InChIKey:JPKQHUHDYLMRJW-UHFFFAOYSA-N
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Compound 31
Molecular Weight:176.2548
Molecular Formula:C12H16O
InChIKey:ODEVDECXRUVZAJ-UHFFFAOYSA-N
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Compound 32
Molecular Weight:176.2548
Molecular Formula:C12H16O
InChIKey:GVZTZXBMNLFWKT-VIJZIMQTSA-N
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Compound 33
Molecular Weight:194.701
Molecular Formula:C12H15Cl
InChIKey:NWPJNYLJZQEMJD-UHFFFAOYSA-N
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 36
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 38
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47a
Molecular Weight:83.151
Molecular Formula:C6H11
InChIKey:PKLOMQAMJDSMFE-UHFFFAOYSA-N
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Compound 47c
Molecular Weight:145.2204
Molecular Formula:C11H13
InChIKey:QKJORMQLHHGECV-UHFFFAOYSA-N
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Compound 39
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 40
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 44
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:174.743
Molecular Formula:C8H15ClSi
InChIKey:WSSUODWANZMVMQ-UHFFFAOYSA-N
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Compound 47
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 48
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47b
Molecular Weight:207.2898
Molecular Formula:C16H15
InChIKey:HSOJRGDAZZJKFL-UHFFFAOYSA-N
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Compound 47d
Molecular Weight:207.2898
Molecular Formula:C16H15
InChIKey:BEXHAJXSHZNMSO-UHFFFAOYSA-N
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Compound 47e
Molecular Weight:269.3591
Molecular Formula:C21H17
InChIKey:JUIYOBBCTGJBPM-UHFFFAOYSA-N
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Compound 48a
Molecular Weight:98.143
Molecular Formula:C6H10O
InChIKey:JPKQHUHDYLMRJW-UHFFFAOYSA-N
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Compound 48b
Molecular Weight:222.2818
Molecular Formula:C16H14O
InChIKey:DNPLZGLNEGAZNC-UHFFFAOYSA-N
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Compound 48c
Molecular Weight:160.2124
Molecular Formula:C11H12O
InChIKey:FUPXYICBZMASCM-UHFFFAOYSA-N
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Compound 48d
Molecular Weight:222.2818
Molecular Formula:C16H14O
InChIKey:GKABQYUTWQPLER-UHFFFAOYSA-N
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Compound 48e
Molecular Weight:284.3511
Molecular Formula:C21H16O
InChIKey:VWRQCJRTHKUVNF-UHFFFAOYSA-N
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Compound 49
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 50
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 50a
Molecular Weight:146.1858
Molecular Formula:C10H10O
InChIKey:PCSOYIMQFRSHSP-UHFFFAOYSA-N
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Compound 50b
Molecular Weight:272.425
Molecular Formula:C19H28O
InChIKey:LUAKXJPRIUIGSE-UHFFFAOYSA-N
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Compound 50c
Molecular Weight:320.6494
Molecular Formula:C16H28OSi3
InChIKey:JOYOJZKHBVYLIW-UHFFFAOYSA-N
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Compound 50d
Molecular Weight:332.3939
Molecular Formula:C25H16O
InChIKey:LIVFKPCWZMFWNG-UHFFFAOYSA-N
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Compound 49a
Molecular Weight:129.1779
Molecular Formula:C10H9
InChIKey:SAJWNUUOOGBLLB-UHFFFAOYSA-N
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Compound 49b
Molecular Weight:255.4171
Molecular Formula:C19H27
InChIKey:YYCCRKGOXDIACA-UHFFFAOYSA-N
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Compound 49c
Molecular Weight:303.6415
Molecular Formula:C16H27Si3
InChIKey:CJTJIIICBVZAOA-UHFFFAOYSA-N
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Compound 49d
Molecular Weight:315.3861
Molecular Formula:C25H15
InChIKey:MSHYUKCVDKTOSS-UHFFFAOYSA-N
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Compound 51
Molecular Weight:185.2842
Molecular Formula:C14H17
InChIKey:NOFRQKGPIXGNKT-UHFFFAOYSA-N
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Compound 53
Molecular Weight:93.1458
Molecular Formula:C7H9
InChIKey:ZYOPXPSYOPSFPZ-UHFFFAOYSA-N
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Compound 52
Molecular Weight:93.1458
Molecular Formula:C7H9
InChIKey:ZYOPXPSYOPSFPZ-UHFFFAOYSA-N
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Compound 54a
Molecular Weight:521.002
Molecular Formula:C33H25ClO4
InChIKey:MKIPNKIIIUPIFI-UHFFFAOYSA-N
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Compound 54b
Molecular Weight:565.453
Molecular Formula:C33H25BrO4
InChIKey:TXFYTDCPQVWLBZ-UHFFFAOYSA-N
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Compound 56
Molecular Weight:470.5147
Molecular Formula:C32H22O4
InChIKey:VGOKMLUBXWGKJZ-UHFFFAOYSA-N
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Compound 49e
Molecular Weight:87.0982
Molecular Formula:C7H3
InChIKey:WTDYJFOKHSTDED-UHFFFAOYSA-N
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Compound 50e
Molecular Weight:104.1061
Molecular Formula:C7H4O
InChIKey:GZIUHUAWSKKRLT-UHFFFAOYSA-N
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Compound 57
Molecular Weight:389.284
Molecular Formula:C23H17BrO
InChIKey:WHHPBZUZHKOZAK-UHFFFAOYSA-N
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Compound 58
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 60
Molecular Weight:354.441
Molecular Formula:C25H22O2
InChIKey:CHRTVMVLIXKJHD-UHFFFAOYSA-N
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Compound 61
Molecular Weight:65.0927
Molecular Formula:C5H5
InChIKey:UUDJYDOJEQMAEI-UHFFFAOYSA-N
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Compound 62
Molecular Weight:214.162
Molecular Formula:C6H5F3O3S
InChIKey:LJLVUMPTGCABDP-UHFFFAOYSA-N
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Compound 63
Molecular Weight:65.0927
Molecular Formula:C5H5
InChIKey:UUDJYDOJEQMAEI-UHFFFAOYSA-N
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Compound 64
Molecular Weight:82.1005
Molecular Formula:C5H6O
InChIKey:JUKHVNMXKSHNQY-UHFFFAOYSA-N
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Compound 66
Molecular Weight:453.082
Molecular Formula:C25H21ClS3
InChIKey:JQNKSJALMPFXRF-UHFFFAOYSA-N
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Compound 67
Molecular Weight:465.093
Molecular Formula:C26H21ClS3
InChIKey:QACBXQOPTKJVPJ-UHFFFAOYSA-N
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