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Activating and Directive Effects of Silicon

Organic Silicon Compounds (1998)

  1. Alan R. Bassindale,
  2. Simon J. Glynn,
  3. Peter G. Taylor

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0169

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Bassindale, A. R., Glynn, S. J. and Taylor, P. G. 2009. Activating and Directive Effects of Silicon. Patai's Chemistry of Functional Groups. .

Author Information

  1. The Open University, Department of Chemistry, Milton Keynes, UK

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Electronic Effects of R3Si
  • 3
    The Measurement and Interpretation of R3Si Activating and Directive Parameters
  • 4
    Activating and Directive Effects of Silicon in Electrophilic Aromatic Substitution
  • 5
    Activating and Directive Effects in Aliphatic Electrophilic Reactions
  • 6
    Activating and Directive Effects of Silicon in Carbanionic Reactions
  • 7
    Stabilization of Developing Negative Charge by Silicon

Keywords:

  • silicon activating and directive effects;
  • R3Si as substituent in aromatic compounds;
  • R3Si effect on silylcarbanions;
  • activating effects of silicon in electrophilic aromatic substitution;
  • directive effects in aliphatic electrophilic reactions;
  • vinylsilane reaction;
  • vinylsilane substitution;
  • propargylsilane reactions