Standard Article

Reaction Mechanisms of Nucleophilic Attack at Silicon

Organic Silicon Compounds (1998)

  1. Alan R Bassindale,
  2. Simon J. Glynn,
  3. Peter G. Taylor

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0171

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Bassindale, A. R., Glynn, S. J. and Taylor, P. G. 2009. Reaction Mechanisms of Nucleophilic Attack at Silicon. Patai's Chemistry of Functional Groups. .

Author Information

  1. The Open University, Department of Chemistry, Milton Keynes, UK

Publication History

  1. Published Online: 15 DEC 2009

Chemistry Terms

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Abstract

  • 1
    Introduction
  • 2
    Direct Substitution of a Leaving Group by a Nucleophile
  • 3
    Nucleophile-Catalysed Substitution at Silicon and Racemization

Keywords:

  • nucleophilic attack at silicon - reaction mechanisms;
  • stereochemistry of substitution;
  • substrate structure effect;
  • kinetics of substitution;
  • geometry of intermediate/transition state;
  • nucleophile-catalysed substitution at silicon and racemization;
  • direct substitution of leaving group by nucleophile;
  • pentacoordinate silicon species pseudorotation

Featured Compounds

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  1. 1 - 17
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 13
Molecular Weight:233.3056
Molecular Formula:C10H14F3NSi
InChIKey:FVOHPNWNIYAMJK-QMMMGPOBSA-N
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 15
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 16
Molecular Weight:346.927
Molecular Formula:C18H23ClN2OSi
InChIKey:BUIGKEYSLCTNPI-WGARNICYSA-N
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Compound 17
Molecular Weight:213.3489
Molecular Formula:C10H19NO2Si
InChIKey:POPFRVBIEBZJFY-WMZJFQQLSA-N
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Compound 20
Molecular Weight:319.4708
Molecular Formula:C17H25NO3Si
InChIKey:OJZRIDDLOVGXQN-AVVWSFFYSA-N
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Compound 23
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:291.4622
Molecular Formula:C19H21NSi
InChIKey:YZMLIUWIKYVIMD-UHFFFAOYSA-N
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Compound 30
Molecular Weight:234.3679
Molecular Formula:C16H14Si
InChIKey:FYPVRHDXFWNYTG-UHFFFAOYSA-N
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Compound 31
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 33
Molecular Weight:323.893
Molecular Formula:C15H22ClN3OSi
InChIKey:WWWLNJHIIIYHRY-BDQAORGHSA-M
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