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Silicenium Ions: Quantum Chemical Computations

Organic Silicon Compounds (1998)

  1. Christoph Maerker,
  2. Paul von Ragué Schleyer

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0172

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Maerker, C. and von Ragué Schleyer, P. 2009. Silicenium Ions: Quantum Chemical Computations. Patai's Chemistry of Functional Groups. .

Author Information

  1. The University of Erlangen-Nürnberg, Computer Chemistry Center of the Institute of Organic Chemistry, Erlangen, Germany

  1. New postal address: Center for Computational Quantum Chemistry The University of Georgia, Athens, GA 30602 USA. Fax: +1-706-542-0406

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Computational Methods
  • 3
    Quantum Mechanical Studies of Silicenium Cations
  • 4
    Concluding Remarks and Outlook

Keywords:

  • silicenium ions - quantum chemical computations;
  • organosilicon compounds and quantum chemical investigations;
  • Fast Multipole Method (FMM);
  • silicenium cation quantum mechanical studies;
  • trialkyl-substituted silicenium ions;
  • Si NMR chemical shifts of silicenium ions;
  • resonance stabilization by aromatic substituents;
  • organoboryl group stabilization