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Silicon-Substituted Carbenes

Organic Silicon Compounds (1998)

  1. Gerhard Maas

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0175

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Maas, G. 2009. Silicon-Substituted Carbenes. Patai's Chemistry of Functional Groups. .

Author Information

  1. Universität Ulm, Abteilung Organische Chemie I, Ulm, Germany

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Geometric and Electronic Structure: Theory and Experiment
  • 3
    Silicon-Substituted Carbenes in Synthesis
  • 4
    Concluding Remarks
  • 5
    Acknowledgments

Keywords:

  • chemistry of (trimethylsilyl)carbene;
  • silicon-substituted carbenes;
  • silicon-substituted carbenes in synthesis;
  • α-elimination reactions - silylmethyl halides;
  • photochemistry of (silyl)diazo compounds in argon matrix;
  • silylcarbene-to-silene rearrangement;
  • silyl-substituted diazoacetate transition-metal catalyzed decomposition ;
  • silylcarbenes by rearrangement reactions