Standard Article

Tris(trimethylsilyl)silane in Organic Synthesis

Organic Silicon Compounds (1998)

  1. C. Chatgilialoglu,
  2. C. Ferreri*,
  3. T. Gimisis

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0187

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Chatgilialoglu, C., Ferreri, C. and Gimisis, T. 2009. Tris(trimethylsilyl)silane in Organic Synthesis. Patai's Chemistry of Functional Groups. .

Author Information

  1. Consiglio Nazionale delle Ricerche, I.Co.C.E.A., Bologna, Italy

  1. *

    On sabbatical leave. Permanent address: Dipartimento di Chimica Organica e Biologica, Università di Napoli ‘Federico II’, Via Mezzocannone 16, 80134 Napoli, Italy.

Publication History

  1. Published Online: 15 DEC 2009

Chemistry Terms

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Abstract

  • 1
    Introduction
  • 2
    Autoxidation of Tris(trimethylsilyl)silane
  • 3
    Reductions
  • 4
    Hydrosilylations
  • 5
    Consecutive Radical Reactions

Keywords:

  • radical chain reactions;
  • tris(trimethylsilyl)silane in organic synthesis;
  • silane hydrogen donor abilities;
  • tris(trimethylsilyl)silane autoxidation;
  • hydrosilylations;
  • consecutive radical reactions;
  • intramolecular C_C bond formation and (TMS)3SiH;
  • radical cyclization fragmentation transannulation ring expansion and termination

Featured Compounds

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  1. 1 - 45
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:460.689
Molecular Formula:C29H48O4
InChIKey:GHVGZHHINLJDET-QJHQESIPSA-N
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Compound 4
Molecular Weight:114.2285
Molecular Formula:C8H18
InChIKey:Not Available
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Compound 5
Molecular Weight:142.2386
Molecular Formula:C9H18O
InChIKey:GYHFUZHODSMOHU-UHFFFAOYSA-N
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Compound 6
Molecular Weight:435.355
Molecular Formula:C21H27BrN2O3
InChIKey:DGICFYFGUXJPTH-ZNFPLGDCSA-N
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Compound 7
Molecular Weight:376.287
Molecular Formula:C19H22BrNO2
InChIKey:SBTNYBAAWNOXBW-DYTRJAOYSA-N
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Compound 8
Molecular Weight:297.3914
Molecular Formula:C19H23NO2
InChIKey:GHFNKSZDDOSEEK-NFIWBVQOSA-N
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10
Molecular Weight:393.275
Molecular Formula:C18H21BrN2O3
InChIKey:ITIBPWJHQNJDQE-RHSMWYFYSA-N
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Compound 11
Molecular Weight:384.265
Molecular Formula:C17H22BrNO4
InChIKey:WZIWSQURMKAOOV-UHFFFAOYSA-N
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Compound 12
Molecular Weight:357.1437
Molecular Formula:C13H12INO3
InChIKey:MFZQYJGSZJNFMX-JMEBYUIHSA-N
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Compound 13
Molecular Weight:231.2472
Molecular Formula:C13H13NO3
InChIKey:WSCLTECOEJKRIS-QROSGCPLSA-N
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Compound 14
Molecular Weight:231.2472
Molecular Formula:C13H13NO3
InChIKey:KQBJQFHEKPJBPQ-GHMZBOCLSA-N
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Compound 15
Molecular Weight:454.38
Molecular Formula:C20H25NO6Se
InChIKey:HGQMWIGXNCAHGS-JVUMBYKBSA-N
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Compound 16
Molecular Weight:215.2032
Molecular Formula:C9H13NO5
InChIKey:XZUXSYJWSIFXJI-ALKRTJFJSA-N
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Compound 17
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:(CH2)nC8H11IO2
InChIKey:YOFKOEDCTARKLR-UHFFFAOYSA-N
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Compound 19
Molecular Weight:335.309
Molecular Formula:C13H23BrO3Si
InChIKey:GJLLQJFJJAJQHV-UHFFFAOYSA-N
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Compound 20
Molecular Weight:286.4824
Molecular Formula:C15H30O3Si
InChIKey:KAKNWRXFCMULMG-STQMWFEESA-N
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Compound 21
Molecular Weight:347.406
Molecular Formula:C16H31BrOSi
InChIKey:KYUZGZGZWBOFQX-UHFFFAOYSA-N
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Compound 22
Molecular Weight:282.5368
Molecular Formula:C17H34OSi
InChIKey:LSOCCOCUENVFFX-QKWOLQBZSA-N
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Compound 23
Molecular Weight:284.5526
Molecular Formula:C17H36OSi
InChIKey:SGNMVHMHFDTMMJ-HWMZRRJGSA-N
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Compound 24
Molecular Weight:446.306
Molecular Formula:C15H19IN4O2S
InChIKey:VCCSDCJUQKYJOF-UHFFFAOYSA-N
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Compound 25
Molecular Weight:539.041
Molecular Formula:C24H46N2O2SSi4
InChIKey:RNENQTWZORYIJC-KMDXXIMOSA-N
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Compound 26
Molecular Weight:292.397
Molecular Formula:C15H20N2O2S
InChIKey:JBCFXPULTKRBRS-SOUVJXGZSA-N
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Compound 27
Molecular Weight:354.463
Molecular Formula:C21H22O3S
InChIKey:WHJYVSGZMLRZBF-APBAKZIRSA-N
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Compound 28
Molecular Weight:357.35
Molecular Formula:C20H22OSe
InChIKey:IUWJHGJEHDCZEX-QHHAFSJGSA-N
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Compound 29
Molecular Weight:438.322
Molecular Formula:C19H19IO2S
InChIKey:SYGATBPWIZZKMT-UHFFFAOYSA-N
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Compound 30
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 31
Molecular Weight:423.727
Molecular Formula:C16H39BrSi4
InChIKey:SZFHLNHQFPVFLC-JKSUJKDBSA-N
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Compound 32
Molecular Weight:270.6338
Molecular Formula:C13H30Si3
InChIKey:VVQCGTBNEFIOEI-BETUJISGSA-N
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Compound 33
Molecular Weight:346.8036
Molecular Formula:C15H38OSi4
InChIKey:DMAXFOHOJMDZHB-LOACHALJSA-N
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Compound 34
Molecular Weight:272.6066
Molecular Formula:C12H28OSi3
InChIKey:PUDYPFZBWDLZQW-TXEJJXNPSA-N
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Compound 35
Molecular Weight:154.2063
Molecular Formula:C9H14O2
InChIKey:FFAJOVVIEBFBKD-CLFYSBASSA-N
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Compound 36
Molecular Weight:194.2701
Molecular Formula:C12H18O2
InChIKey:MBSLMSRPDNBARJ-ARJAWSKDSA-N
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Compound 37
Molecular Weight:148.2017
Molecular Formula:C10H12O
InChIKey:VJSYOOZIGLICBV-UHFFFAOYSA-N
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Compound 38
Molecular Weight:396.9054
Molecular Formula:C20H44Si4
InChIKey:WSOMBRCJALHSCW-NRRUETGQSA-N
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Compound 39
Molecular Weight:243.2564
Molecular Formula:C11H17NO5
InChIKey:BSZICDCZXJSDKW-SOFGYWHQSA-N
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Compound 40
Molecular Weight:Not Available
Molecular Formula:(CH2)nC10H15N3O3
InChIKey:OFYVIRGXBOGEDZ-UHFFFAOYSA-N
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Compound 41
Molecular Weight:179.219
Molecular Formula:C9H13N3O
InChIKey:AGZKZTBAUQUVFN-IEIXJENWSA-N
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Compound 43
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 44
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:213.297
Molecular Formula:C10H15NO2S
InChIKey:AFYYAZGHEXCIJE-UHFFFAOYSA-N
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Compound 46
Molecular Weight:241.35
Molecular Formula:C12H19NO2S
InChIKey:JVRIXHAPZJZXFQ-UHFFFAOYSA-N
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  1. 1 - 45