Standard Article

Organosilicon Derivatives of Fullerenes

Organic Silicon Compounds (1998)

  1. Wataru Ando,
  2. Takahiro Kusukawa

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0195

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Ando, W. and Kusukawa, T. 2009. Organosilicon Derivatives of Fullerenes. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of Tsukuba, Department of Chemistry, Tsukuba, Ibaraki, Japan

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Photoconductivity of Fullerene-Doped Polysilanes
  • 3
    Photochemical Reactions of 2,2-Diaryltrisilane
  • 4
    Photochemical and Thermal Additions of Cyclosilanes to Fullerenes
  • 5
    Photochemical Additions of Polysilacyclobutanes and -Butene to C60
  • 6
    Reactions of Silyllithium Reagents with C60
  • 7
    Reactions of Silicon-Substituted Nucleophiles
  • 8
    Reactions of Silyl Diazonium Compounds

Keywords:

  • fullerenes and organosilicon derivatives ;
  • disilirane and digermirane - oxidation and ionization potential;
  • oxadisilirane;
  • MALDITOF mass spectrum of product;
  • bis-silylated fullerene formation;
  • photochemical reactions of cyclotetrasilane with C60;
  • nucleophilic addition to C60;
  • silicon-substituted nucleophile reactions

Featured Compounds

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  1. 1 - 121
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:496.9904
Molecular Formula:C30H52Si3
InChIKey:YDWMKHCIMYBJBS-UHFFFAOYSA-N
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Compound 7a
Molecular Weight:1071.2543
Molecular Formula:C84H34Si
InChIKey:QGZVAFBQDYHMKR-UHFFFAOYSA-N
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Compound 7b
Molecular Weight:1071.2543
Molecular Formula:C84H34Si
InChIKey:IEKWOHVZOYSKBM-UHFFFAOYSA-N
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Compound 11a
Molecular Weight:902.9353
Molecular Formula:C72H10Si
InChIKey:ZZSRAIPHAHMERJ-UHFFFAOYSA-N
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Compound 11b
Molecular Weight:902.9353
Molecular Formula:C72H10Si
InChIKey:BKAVTFXJEITCIB-UHFFFAOYSA-N
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Compound 12
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 13
Molecular Weight:546.9321
Molecular Formula:C37H46Si2
InChIKey:PQXGMDOGBDKESX-UHFFFAOYSA-N
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Compound 14
Molecular Weight:1267.5741
Molecular Formula:C97H46Si2
InChIKey:WNDKRPFEJBKNQR-UHFFFAOYSA-N
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Compound 15
Molecular Weight:548.905
Molecular Formula:C36H44OSi2
InChIKey:HTDMQEWCWIWCMD-UHFFFAOYSA-N
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Compound 16
Molecular Weight:1269.547
Molecular Formula:C96H44OSi2
InChIKey:XGXBYDYIYUCPQT-UHFFFAOYSA-N
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Compound 17
Molecular Weight:1269.547
Molecular Formula:C96H44OSi2
InChIKey:ZBVKLDFJTFOXBB-UHFFFAOYSA-N
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Compound 18
Molecular Weight:692.15
Molecular Formula:C41H54Ge2
InChIKey:CMXYHMOLBRCZSM-UHFFFAOYSA-N
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Compound 19
Molecular Weight:1414.76
Molecular Formula:C100H52Ge2O
InChIKey:BHGBAGITGCGZSL-UHFFFAOYSA-N
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Compound 21
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 20
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 22
Molecular Weight:304.6177
Molecular Formula:C18H32Si2
InChIKey:INMMWNSTTZOEDL-UHFFFAOYSA-N
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Compound 23
Molecular Weight:1025.2597
Molecular Formula:C78H32Si2
InChIKey:XNNASIGWEIVOGM-UHFFFAOYSA-N
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Compound 24a
Molecular Weight:336.7026
Molecular Formula:C20H40Si2
InChIKey:GYKUETVIUOHWJW-UHFFFAOYSA-N
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Compound 24b
Molecular Weight:280.5963
Molecular Formula:C16H32Si2
InChIKey:QIAPYTXHHBAHLZ-UHFFFAOYSA-N
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Compound 26a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 25
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 26
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 24
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 27a
Molecular Weight:841.3858
Molecular Formula:C56H56Si4
InChIKey:YWJNCSHAZBEAPV-UHFFFAOYSA-N
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Compound 28a
Molecular Weight:1562.0278
Molecular Formula:C116H56Si4
InChIKey:ZHZFUHPDRAXESG-UHFFFAOYSA-N
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Compound 29a
Molecular Weight:1562.0278
Molecular Formula:C116H56Si4
InChIKey:WYVHZDWJXZIJFG-UHFFFAOYSA-N
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Compound 29b
Molecular Weight:1545.9854
Molecular Formula:C115H52Si4
InChIKey:JZFCKXAWFDBOQH-UHFFFAOYSA-N
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Compound 29c
Molecular Weight:1628.03
Molecular Formula:C108H40Ge4
InChIKey:OAIMULPLSAZVKQ-UHFFFAOYSA-N
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Compound 27b
Molecular Weight:729.1732
Molecular Formula:C48H40Si4
InChIKey:MHBOFSJQAKACCM-UHFFFAOYSA-N
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Compound 27c
Molecular Weight:907.39
Molecular Formula:C48H40Ge4
InChIKey:ICDVVVADCQVJJQ-UHFFFAOYSA-N
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Compound 28b
Molecular Weight:1449.8152
Molecular Formula:C108H40Si4
InChIKey:NTCWEJIMHKEFBG-UHFFFAOYSA-N
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Compound 28c
Molecular Weight:1628.03
Molecular Formula:C108H40Ge4
InChIKey:SDAOKRCWFOKJHG-UHFFFAOYSA-N
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Compound 27
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30b
Molecular Weight:800.079
Molecular Formula:C48H40Cl2Si4
InChIKey:UMGYNDKGUGCSKU-UHFFFAOYSA-N
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Compound 31b
Molecular Weight:617.786
Molecular Formula:C36H30Cl2Si3
InChIKey:OLVMGLMRWWJEAI-UHFFFAOYSA-N
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Compound 33
Molecular Weight:743.1567
Molecular Formula:C48H38OSi4
InChIKey:ACYRMGLKVJCINY-UHFFFAOYSA-N
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Compound 34a
Molecular Weight:198.306
Molecular Formula:C12H19LiSi
InChIKey:AXJXGWGBAIMRNB-UHFFFAOYSA-N
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Compound 35a
Molecular Weight:913.0147
Molecular Formula:C72H20Si
InChIKey:MNPKFPRDNZCCPH-UHFFFAOYSA-N
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Compound 34b
Molecular Weight:232.322
Molecular Formula:C15H17LiSi
InChIKey:PYBDALRJQIARHO-UHFFFAOYSA-N
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Compound 34c
Molecular Weight:246.349
Molecular Formula:C16H19LiSi
InChIKey:KUYRMQRQIYEDIR-UHFFFAOYSA-N
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Compound 35b
Molecular Weight:947.0309
Molecular Formula:C75H18Si
InChIKey:ZFVQXMCQAJSZPD-UHFFFAOYSA-N
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Compound 35c
Molecular Weight:961.0575
Molecular Formula:C76H20Si
InChIKey:GABOHDXHVLQMDK-UHFFFAOYSA-N
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 36
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 37
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 38
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 34d
Molecular Weight:254.594
Molecular Formula:C9H27LiSi4
InChIKey:KOFUVNISAOOCMP-UHFFFAOYSA-N
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Compound 34e
Molecular Weight:226.359
Molecular Formula:C14H23LiSi
InChIKey:TWDSBIAVQGGIMQ-UHFFFAOYSA-N
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Compound 34f
Molecular Weight:240.386
Molecular Formula:C15H25LiSi
InChIKey:ZJNSUANHKMQLCC-UHFFFAOYSA-N
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Compound 34g
Molecular Weight:274.402
Molecular Formula:C18H23LiSi
InChIKey:NOCVPBGGSCWTQC-UHFFFAOYSA-N
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Compound 34h
Molecular Weight:270.91
Molecular Formula:C14H23GeLi
InChIKey:ALGILRCAVWOMCB-UHFFFAOYSA-N
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Compound 34i
Molecular Weight:242.86
Molecular Formula:C12H19GeLi
InChIKey:WEIPXDUHIQSDJX-UHFFFAOYSA-N
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Compound 36d
Molecular Weight:1215.9474
Molecular Formula:C78H54Si8
InChIKey:WJDBKMHUOIYKCK-UHFFFAOYSA-N
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Compound 35d
Molecular Weight:969.3026
Molecular Formula:C69H28Si4
InChIKey:WTMWKABNTUPXQB-UHFFFAOYSA-N
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Compound 34
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 35e
Molecular Weight:941.0679
Molecular Formula:C74H24Si
InChIKey:WYNSHMTUNVWQEL-UHFFFAOYSA-N
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Compound 35f
Molecular Weight:955.0944
Molecular Formula:C75H26Si
InChIKey:SNFXNZPVAIPDOT-UHFFFAOYSA-N
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Compound 35g
Molecular Weight:989.1107
Molecular Formula:C78H24Si
InChIKey:MKKDABGHZNCPLF-UHFFFAOYSA-N
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Compound 35h
Molecular Weight:985.62
Molecular Formula:C74H24Ge
InChIKey:WKJNBYZESKDJTQ-UHFFFAOYSA-N
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Compound 35i
Molecular Weight:957.57
Molecular Formula:C72H20Ge
InChIKey:LWRIMBJMKUYRPP-UHFFFAOYSA-N
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Compound 36a
Molecular Weight:1103.3715
Molecular Formula:C84H38Si2
InChIKey:YWVNQKJUNHIQII-UHFFFAOYSA-N
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Compound 36b
Molecular Weight:1171.404
Molecular Formula:C90H34Si2
InChIKey:KKCDRYPQKLHSOZ-UHFFFAOYSA-N
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Compound 36c
Molecular Weight:1199.4571
Molecular Formula:C92H38Si2
InChIKey:YVQGWTHREZVPPI-UHFFFAOYSA-N
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Compound 36e
Molecular Weight:1159.4778
Molecular Formula:C88H46Si2
InChIKey:GSFAJZJCLGRKNA-UHFFFAOYSA-N
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Compound 36f
Molecular Weight:1187.531
Molecular Formula:C90H50Si2
InChIKey:APUMSZRLMPYVDW-UHFFFAOYSA-N
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Compound 36g
Molecular Weight:1255.5634
Molecular Formula:C96H46Si2
InChIKey:NXNWYQFBLRXMFA-UHFFFAOYSA-N
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Compound 36h
Molecular Weight:1248.59
Molecular Formula:C88H46Ge2
InChIKey:WCKWVBONOCEVAX-UHFFFAOYSA-N
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Compound 36i
Molecular Weight:1192.48
Molecular Formula:C84H38Ge2
InChIKey:URCPZVPFLGJBGX-UHFFFAOYSA-N
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Compound 37a
Molecular Weight:915.0306
Molecular Formula:C72H22Si
InChIKey:WUUPSWKIGDCZNT-UHFFFAOYSA-N
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Compound 37b
Molecular Weight:949.0468
Molecular Formula:C75H20Si
InChIKey:DFPDZLKYGKAWIR-UHFFFAOYSA-N
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Compound 37c
Molecular Weight:963.0734
Molecular Formula:C76H22Si
InChIKey:XKRMCYQEYSQEIQ-UHFFFAOYSA-N
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Compound 37d
Molecular Weight:971.3185
Molecular Formula:C69H30Si4
InChIKey:RGHCOJSMXFTQSE-UHFFFAOYSA-N
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Compound 37e
Molecular Weight:943.0837
Molecular Formula:C74H26Si
InChIKey:CTHKKNQNHWGSIM-UHFFFAOYSA-N
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Compound 37f
Molecular Weight:957.1103
Molecular Formula:C75H28Si
InChIKey:GPZRWRFVDMODGO-UHFFFAOYSA-N
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Compound 37g
Molecular Weight:991.1265
Molecular Formula:C78H26Si
InChIKey:SCJIGZOILRFQNJ-UHFFFAOYSA-N
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Compound 37h
Molecular Weight:987.64
Molecular Formula:C74H26Ge
InChIKey:BVUMLWSDZGDYSH-UHFFFAOYSA-N
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Compound 37i
Molecular Weight:959.59
Molecular Formula:C72H22Ge
InChIKey:BFPFRMCGUVVTNU-UHFFFAOYSA-N
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Compound 38a
Molecular Weight:1828.0453
Molecular Formula:C144H42Si2
InChIKey:BVAGOJBHKPJZPX-UHFFFAOYSA-N
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Compound 38b
Molecular Weight:1896.0777
Molecular Formula:C150H38Si2
InChIKey:FAXSKIOGMQYBAW-UHFFFAOYSA-N
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Compound 38c
Molecular Weight:1924.1309
Molecular Formula:C152H42Si2
InChIKey:AYZUSWHLWIPMRO-UHFFFAOYSA-N
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Compound 38d
Molecular Weight:1940.6211
Molecular Formula:C138H58Si8
InChIKey:MCBCGXZUCLQDDY-UHFFFAOYSA-N
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Compound 38e
Molecular Weight:1884.1516
Molecular Formula:C148H50Si2
InChIKey:POXZSSDURHSRIT-UHFFFAOYSA-N
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Compound 38f
Molecular Weight:1912.2048
Molecular Formula:C150H54Si2
InChIKey:WWOLLVNLIDBZIM-UHFFFAOYSA-N
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Compound 38g
Molecular Weight:1980.2372
Molecular Formula:C156H50Si2
InChIKey:ROTIMIYLMVHYSF-UHFFFAOYSA-N
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Compound 38h
Molecular Weight:1928.71
Molecular Formula:C148H50GeSi
InChIKey:LBIMIDFJIBIPJM-UHFFFAOYSA-N
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Compound 38i
Molecular Weight:1872.6
Molecular Formula:C144H42GeSi
InChIKey:WJXGWQWCCXJACH-UHFFFAOYSA-N
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Compound 39
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 39c
Molecular Weight:478.8151
Molecular Formula:C32H38Si2
InChIKey:MYGACGYHGHVXFO-UHFFFAOYSA-N
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Compound 39e
Molecular Weight:438.8358
Molecular Formula:C28H46Si2
InChIKey:INGFVVDBTICRAM-UHFFFAOYSA-N
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Compound 39g
Molecular Weight:534.9214
Molecular Formula:C36H46Si2
InChIKey:IKOBEWUHYXDMQU-UHFFFAOYSA-N
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Compound 39k
Molecular Weight:510.9647
Molecular Formula:C30H38Si4
InChIKey:JBMXUADTXCSPTI-UHFFFAOYSA-N
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Compound 40
Molecular Weight:1223.777
Molecular Formula:C84H46Si6
InChIKey:JMWFNAXTGUGEBO-UHFFFAOYSA-N
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Compound 41
Molecular Weight:506.8683
Molecular Formula:C34H42Si2
InChIKey:JXNYBACQWCOCGD-UHFFFAOYSA-N
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Compound 42
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 44
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43a
Molecular Weight:146.974
Molecular Formula:C4H11ClMgSi
InChIKey:Not Available
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Compound 43b
Molecular Weight:132.947
Molecular Formula:C3H9ClMgSi
InChIKey:KRPAWJPHEZHHRY-UHFFFAOYSA-M
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Compound 43c
Molecular Weight:209.043
Molecular Formula:C9H13ClMgSi
InChIKey:XCJKCCXDNXOCOR-UHFFFAOYSA-M
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Compound 43d
Molecular Weight:158.984
Molecular Formula:C5H11ClMgSi
InChIKey:DHZVNAMPYYNHDG-UHFFFAOYSA-M
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Compound 43e
Molecular Weight:191.026
Molecular Formula:C6H15ClMgOSi
InChIKey:XPVBIOXOBCIMTF-UHFFFAOYSA-M
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Compound 44a
Molecular Weight:808.8656
Molecular Formula:C64H12Si
InChIKey:HCIRHLJTJJKGPO-UHFFFAOYSA-N
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Compound 44b
Molecular Weight:794.839
Molecular Formula:C63H10Si
InChIKey:OOASXZJOLNAWHD-UHFFFAOYSA-N
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Compound 44c
Molecular Weight:870.935
Molecular Formula:C69H14Si
InChIKey:UFAKVERKJBKILX-UHFFFAOYSA-N
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Compound 44d
Molecular Weight:820.8763
Molecular Formula:C65H12Si
InChIKey:OXPKTIMWNFJDFD-UHFFFAOYSA-N
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Compound 44e
Molecular Weight:852.9181
Molecular Formula:C66H16OSi
InChIKey:MQTFIUZADBCXQQ-UHFFFAOYSA-N
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Compound 45a
Molecular Weight:895.0733
Molecular Formula:C68H22Si2
InChIKey:MERBSZGRQANWLU-UHFFFAOYSA-N
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Compound 45b
Molecular Weight:867.0201
Molecular Formula:C66H18Si2
InChIKey:OHUHWJHPSHQXKT-UHFFFAOYSA-N
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Compound 45c
Molecular Weight:1019.212
Molecular Formula:C78H26Si2
InChIKey:GUFQWFYKGJPLMU-UHFFFAOYSA-N
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Compound 45d
Molecular Weight:919.0947
Molecular Formula:C70H22Si2
InChIKey:YDNPPVDKQYRJOB-UHFFFAOYSA-N
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Compound 45e
Molecular Weight:983.1784
Molecular Formula:C72H30O2Si2
InChIKey:RMJFNKVSKVUMOC-UHFFFAOYSA-N
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Compound 46
Molecular Weight:881.0036
Molecular Formula:C66H16OSi2
InChIKey:TVHNXHXBRIMDIB-UHFFFAOYSA-N
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Compound 47
Molecular Weight:829.284
Molecular Formula:C63H9ClSi
InChIKey:WKCKLFFDORHYKM-UHFFFAOYSA-N
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Compound 48
Molecular Weight:837.916
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 49
Molecular Weight:104.151
Molecular Formula:C5H9LiSi
InChIKey:ZVXXEONXFWSCIZ-UHFFFAOYSA-N
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Compound 50
Molecular Weight:818.8604
Molecular Formula:C65H10Si
InChIKey:BUPGDMCTBNAVTM-UHFFFAOYSA-N
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Compound 52
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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