Standard Article

Transition-Metal Silyl Complexes

Organic Silicon Compounds (1998)

  1. Moris S. Eisen

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0197

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Eisen, M. S. 2009. Transition-Metal Silyl Complexes. Patai's Chemistry of Functional Groups. .

Author Information

  1. Technion—Israel Institute of Technology, Department of Chemistry, Haifa, Israel

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Group-3 Silyl Complexes
  • 3
    Lanthanide Silyl Derivatives
  • 4
    Group-4 Silyl Complexes
  • 5
    Actinide Silyl Complexes
  • 6
    Group-5 Silyl Complexes
  • 7
    General Introduction to Late-Transition-Metal Silicon-Containing Complexes
  • 8
    Group-6 Silylene Complexes
  • 9
    Group-6 Silyl Complexes
  • 10
    Group-7 Silylene Complexes
  • 11
    Group-7 Silyl Derivatives
  • 12
    Group-8 Silyl Derivatives
  • 13
    Group-9 Silicon-Containing Complexes
  • 14
    Group-10 Silicon-Containing Complexes
  • 15
    Copper and Mercury Silyl Complexes
  • 16
    Acknowledgments

Keywords:

  • transition-metal silyl complexes;
  • lanthanide silyl derivatives;
  • actinide silyl complexes;
  • group-5 silyl complexes;
  • late-transition-metal silicon-containing complexes;
  • group-6 silylene complexes;
  • group-7 silylene complexes;
  • methyl iridium triflate complex

Featured Compounds

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  1. 1 - 104
Compound 1
Molecular Weight:1192.57
Molecular Formula:C52H98Si6Sm2
InChIKey:JMDJPLLROPTIKM-UHFFFAOYSA-N
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Compound 4
Molecular Weight:353.594
Molecular Formula:C17H27PZr
InChIKey:NTJLNPUJBRVLDZ-UHFFFAOYSA-N
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Compound 5
Molecular Weight:329.591
Molecular Formula:C18H22Zr
InChIKey:SKJNVLLXSHXQSJ-UHFFFAOYSA-N
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Compound 7
Molecular Weight:438.44
Molecular Formula:C25H31PSiTi
InChIKey:SQICNGLZAQTXBD-UHFFFAOYSA-N
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Compound 8
Molecular Weight:536.275
Molecular Formula:C26H38N2P2Ti2
InChIKey:HHCRPHHPLZAXTF-UHFFFAOYSA-N
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Compound 10
Molecular Weight:964.82
Molecular Formula:C36H48Cl2Hf2Si2
InChIKey:UEJBLPAWXRYSMD-UHFFFAOYSA-L
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Compound 11
Molecular Weight:1575.535
Molecular Formula:C72H70B2F20Si2Zr2
InChIKey:IACBYMCKMPNIFI-UHFFFAOYSA-N
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Compound 12
Molecular Weight:1715.801
Molecular Formula:C82H90B2F20Si2Zr2
InChIKey:BTDKNOZPPCAILI-UHFFFAOYSA-N
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Compound 13
Molecular Weight:426.763
Molecular Formula:C19H34NPSiZr
InChIKey:BCPKQPHLRZKOGB-UHFFFAOYSA-N
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 18
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 19
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound A
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound B
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound C
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound D
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound E
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound F
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound G
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound H
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound I
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 20
Molecular Weight:431.4343
Molecular Formula:C20H17CrNO5Si
InChIKey:GFSRJTAUIDQINJ-UHFFFAOYSA-N
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Compound 21
Molecular Weight:488.5287
Molecular Formula:C23H24CrN2O5Si
InChIKey:WECONXBBTQUSQM-UHFFFAOYSA-N
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Compound 22
Molecular Weight:601.7294
Molecular Formula:C30H39CrN3O5Si
InChIKey:SHOROIROWGPUOY-UHFFFAOYSA-N
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Compound 23
Molecular Weight:355.3383
Molecular Formula:C14H13CrNO5Si
InChIKey:DLQWWKRDLFTPNZ-UHFFFAOYSA-N
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Compound 24
Molecular Weight:405.397
Molecular Formula:C18H15CrNO5Si
InChIKey:NZLFVKXVWJOXIK-UHFFFAOYSA-N
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Compound 25
Molecular Weight:391.3704
Molecular Formula:C17H13CrNO5Si
InChIKey:FVMAIUFRLKNNAX-UHFFFAOYSA-N
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Compound 26
Molecular Weight:430.34
Molecular Formula:C14H22Si2W
InChIKey:BSHDJTCGMNDHEK-UHFFFAOYSA-N
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Compound 27
Molecular Weight:946.355
Molecular Formula:C48H65P2ReSi2
InChIKey:NCNLICGPWYQAIP-UHFFFAOYSA-N
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Compound 28
Molecular Weight:910.239
Molecular Formula:C46H53P2ReSi2
InChIKey:QBLOUMMMTXYCCK-UHFFFAOYSA-N
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Compound 29a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 29b
Molecular Weight:1034.968
Molecular Formula:C38H44CdFe2O12P2Si2
InChIKey:DHTXNSXQEXFKBR-UHFFFAOYSA-N
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Compound 31
Molecular Weight:1491.49
Molecular Formula:C62H62Fe2HgO12P4Si2
InChIKey:RHIIWQBHKNUUBL-UHFFFAOYSA-N
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Compound 44
Molecular Weight:467.351
Molecular Formula:C15H34FeN3O6PSi
InChIKey:HJHKLYOKVGHAJB-UHFFFAOYSA-N
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Compound 45
Molecular Weight:575.491
Molecular Formula:C25H38FeN3O5PSi
InChIKey:LEUPDDDLAZJQFD-UHFFFAOYSA-N
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Compound 46
Molecular Weight:637.56
Molecular Formula:C30H40FeN3O5PSi
InChIKey:BMJNKYZRXJTPRD-UHFFFAOYSA-N
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Compound 48
Molecular Weight:1738.01
Molecular Formula:C72H98F6N4O6P4Ru2S4Si2
InChIKey:FJOVFIMLZNRRRN-UHFFFAOYSA-L
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Compound 30
Molecular Weight:1684.838
Molecular Formula:C62H62Au2Fe2O12P4Si2
InChIKey:OJIBBIOQGUNOCO-UHFFFAOYSA-N
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Compound 32
Molecular Weight:1056.12
Molecular Formula:C18H19NO13Os3Si
InChIKey:CMICFMFGWBJYEL-UHFFFAOYSA-N
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Compound 33
Molecular Weight:1028.11
Molecular Formula:C17H19NO12Os3Si
InChIKey:LXILRJJNSAENLY-UHFFFAOYSA-N
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Compound 35
Molecular Weight:1552.46
Molecular Formula:C38H32O13Os3P2PtSi
InChIKey:ZLAAHVCVBDOAQG-UHFFFAOYSA-N
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Compound 36
Molecular Weight:1552.46
Molecular Formula:C38H32O13Os3P2PtSi
InChIKey:ZLAAHVCVBDOAQG-UHFFFAOYSA-N
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Compound 50
Molecular Weight:538.011
Molecular Formula:C17H19Fe2IO3Si
InChIKey:BALWTXKATKBQHM-UHFFFAOYSA-N
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Compound L
Molecular Weight:842
Molecular Formula:C27H40O4OsP2RuSSi
InChIKey:IQNUKQGZZCMZGP-UHFFFAOYSA-N
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Compound 38
Molecular Weight:865.23
Molecular Formula:C46H52Ru2Si2
InChIKey:CQHVNRXTLZHDNI-BJDJZHDASA-N
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Compound 40
Molecular Weight:941.46
Molecular Formula:C51H76BRuSi5
InChIKey:MNCLQHKAGYZGJT-UHFFFAOYSA-N
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Compound 39
Molecular Weight:328.8207
Molecular Formula:C13H32Si5
InChIKey:AZDNWDIENWBPLQ-UHFFFAOYSA-N
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Compound 41
Molecular Weight:379.263
Molecular Formula:C18H17FeNO3Si
InChIKey:DBMJDKUDPKNGHF-UHFFFAOYSA-N
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Compound 43
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47
Molecular Weight:1018.08
Molecular Formula:C37H50F6N2O6P2RuS3Si
InChIKey:QDCAZCKNMQMGBX-UHFFFAOYSA-L
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Compound M
Molecular Weight:842
Molecular Formula:C27H40O4OsP2RuSSi
InChIKey:KVCINDHLLMROFX-UHFFFAOYSA-N
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Compound N
Molecular Weight:842
Molecular Formula:C27H40O4OsP2RuSSi
InChIKey:GEJOPWNXCKUCNV-UHFFFAOYSA-N
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Compound 52
Molecular Weight:502.498
Molecular Formula:C28H34FeO3Si
InChIKey:XACHSCONPWUCJF-JSQOVPBCSA-N
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Compound 53
Molecular Weight:547.72
Molecular Formula:C28H34O3RuSi
InChIKey:RDDHNHSXQDKWGD-XHJVEBLCSA-N
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Compound 54
Molecular Weight:514.509
Molecular Formula:C29H34FeO3Si
InChIKey:KBLYRGBVJLTVGZ-UHFFFAOYSA-N
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Compound 64
Molecular Weight:898.172
Molecular Formula:C41H58IrO6PSi
InChIKey:WDOFWJWSUKVKGW-DVACKJPTSA-M
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Compound 72
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:587.71
Molecular Formula:C22H36IrO4P
InChIKey:COZMQCCAFXSQBL-UHFFFAOYSA-M
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Compound 56
Molecular Weight:816.073
Molecular Formula:C39H48IrO3PSi
InChIKey:WPWBVLBWMRFEHJ-UHFFFAOYSA-N
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Compound 57
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 58
Molecular Weight:896.276
Molecular Formula:C44H56IrO2PSi2
InChIKey:MUMZTCSOFQLQMD-UHFFFAOYSA-N
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Compound 59
Molecular Weight:744.084
Molecular Formula:C32H48IrO2PSi2
InChIKey:SWHFIAREDQKINT-UHFFFAOYSA-N
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Compound 60
Molecular Weight:681.95
Molecular Formula:C31H54IrO2P
InChIKey:CWCJGQGTIBWLFO-XBFKZRQXSA-M
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Compound 61
Molecular Weight:561.758
Molecular Formula:C22H42IrO2P
InChIKey:MHKBISHLIHBJOU-XBFKZRQXSA-M
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Compound 62
Molecular Weight:713.863
Molecular Formula:C29H46IrO6P
InChIKey:XGDNJTIOSQRBJM-DVACKJPTSA-M
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Compound 63
Molecular Weight:593.671
Molecular Formula:C20H34IrO6P
InChIKey:NWOYPMZURQVKDV-DVACKJPTSA-M
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Compound 65
Molecular Weight:777.98
Molecular Formula:C32H46IrO6PSi
InChIKey:YZBFVPPUCCFYQH-DVACKJPTSA-M
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Compound 65a
Molecular Weight:688.03
Molecular Formula:C29H56IrO2PSi
InChIKey:VIGRODVEJFMKAA-NPDUFXBMSA-M
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Compound 66
Molecular Weight:912.217
Molecular Formula:C46H49IrP2Si2
InChIKey:AWOQREXMWCHANE-UHFFFAOYSA-N
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Compound 67
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 68
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 69
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:714.417
Molecular Formula:C24H61ClIrOP3Si
InChIKey:WYBVJQLAKIHKKL-UHFFFAOYSA-M
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Compound 74
Molecular Weight:1440.701
Molecular Formula:C48H120Cl2Ir2Li2O2P6Si2
InChIKey:HMJONUXMXLQBHH-UHFFFAOYSA-L
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Compound 82
Molecular Weight:886.266
Molecular Formula:C38H72OP2PtSi3
InChIKey:IERHYUPVJJYBDM-UHFFFAOYSA-N
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Compound 89
Molecular Weight:667.847
Molecular Formula:C24H38P2PtSi3
InChIKey:KTUHLTAHNOLSPZ-UHFFFAOYSA-N
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Compound 96
Molecular Weight:1133.378
Molecular Formula:C36H74P4Pt2Si4
InChIKey:MYGIKOXGUWQYLN-UHFFFAOYSA-N
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Compound 98
Molecular Weight:649.2
Molecular Formula:C32H40P2PdSi2
InChIKey:YRXZGEJROGNFAN-UHFFFAOYSA-N
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Compound 102
Molecular Weight:507.21
Molecular Formula:C18H36N2PdS2Si2
InChIKey:UFCZRLCQCVWECC-UHFFFAOYSA-N
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Compound 105
Molecular Weight:507.443
Molecular Formula:C22H40N4NiO2Si2
InChIKey:ZLYLETQWIAJREK-UHFFFAOYSA-N
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 76
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:283.14
Molecular Formula:C7H13ClOPdSi
InChIKey:WQONCWGHIIWGBG-UHFFFAOYSA-M
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Compound 78
Molecular Weight:283.14
Molecular Formula:C7H13ClOPdSi
InChIKey:NIPOZNADKYAHSR-UHFFFAOYSA-M
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Compound 79
Molecular Weight:283.14
Molecular Formula:C7H13ClOPdSi
InChIKey:UBEKQWXWRCCYBX-UHFFFAOYSA-M
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Compound 80
Molecular Weight:904.711
Molecular Formula:C38H71ClP2PtSi3
InChIKey:JNSKROWLKQGFMG-UHFFFAOYSA-M
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Compound 81
Molecular Weight:868.25
Molecular Formula:C38H70P2PtSi3
InChIKey:ZBVDZYFSGLVRAH-UHFFFAOYSA-N
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Compound 83
Molecular Weight:904.711
Molecular Formula:C38H71ClP2PtSi3
InChIKey:RKIUPZHIQOZNHO-UHFFFAOYSA-N
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Compound 84
Molecular Weight:900.292
Molecular Formula:C39H74OP2PtSi3
InChIKey:OTGAHBGQJKCBIU-UHFFFAOYSA-N
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Compound 85
Molecular Weight:1355.787
Molecular Formula:C52H104P4Pt2Si4
InChIKey:MQCGYZYVVYADFQ-UHFFFAOYSA-N
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Compound 87
Molecular Weight:1295.584
Molecular Formula:C52H100P4Pt2Si2
InChIKey:PSYXTXMLHANLKJ-UHFFFAOYSA-N
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Compound 86
Molecular Weight:679.909
Molecular Formula:C26H54P2PtSi2
InChIKey:YMUJZWSKZXXZRQ-UHFFFAOYSA-N
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Compound 88
Molecular Weight:1117.251
Molecular Formula:C36H58P4Pt2Si4
InChIKey:MCTXVLLHGSZDGP-UHFFFAOYSA-N
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Compound 90
Molecular Weight:693.819
Molecular Formula:C30H48P2PtSi
InChIKey:VUPKIDBOYWMGKI-UHFFFAOYSA-N
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Compound 91
Molecular Weight:262.421
Molecular Formula:C18H18Si
InChIKey:MVNVMCKXRSSBIA-UHFFFAOYSA-N
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 93
Molecular Weight:572.469
Molecular Formula:C15H36Cl2P2PtSi
InChIKey:SIQBUZHPVIWSMR-UHFFFAOYSA-M
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Compound 94
Molecular Weight:200.4686
Molecular Formula:C10H24Si2
InChIKey:DVWBNOACKNOYSV-UHFFFAOYSA-N
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Compound 95
Molecular Weight:703.996
Molecular Formula:C24H46P2PtSi4
InChIKey:AKUGSYAQIBAWAK-UHFFFAOYSA-N
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Compound 99
Molecular Weight:791.31
Molecular Formula:C38H46O4P2PdSi2
InChIKey:ZBXXDCQWWQNXCJ-XPPFCZECSA-N
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Compound 103
Molecular Weight:196.3647
Molecular Formula:C10H20N2Si
InChIKey:FPQXNXPXMVRQEP-UHFFFAOYSA-N
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Compound 104
Molecular Weight:339.0884
Molecular Formula:C13H20N2NiO3Si
InChIKey:QZLOQWOEKKVNMB-UHFFFAOYSA-N
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Compound 106
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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  1. 1 - 104