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Highly Reactive Small-Ring Monosilacycles and Medium-Ring Oligosilacycles

Organic Silicon Compounds (1998)

  1. Wataru Ando,
  2. Yoshio Kabe

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0204

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Ando, W. and Kabe, Y. 2009. Highly Reactive Small-Ring Monosilacycles and Medium-Ring Oligosilacycles. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of Tsukuba, Department of Chemistry, Tsukuba, Japan

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Silyl Carbene-to-Silene Rearrangement and Ring Formation
  • 3
    Ylide and Small-Ring Formations by Silylene Reactions with Heteroatoms and Cumulenes
  • 4
    Ring Formation by Wurtz and Diyne Coupling Reactions
  • 5
    Ring Formation by Kipping and Gilman Reactions

Keywords:

  • silyl carbene-to-silene rearrangement and ring formation;
  • monosilanyl diazo compound decomposition;
  • silyl carbene-to-silene rearrangement and ring formation;
  • oligosilanyl diazo compound decomposition;
  • oxa(thia)siliranes and sila(thio)carbonyl ylides;
  • small-ring monosilacycles and medium-ring oligosilacycles;
  • Wurtz and Diyne coupling reactions and ring formation;
  • oligosilabridged cyclic acetylenes