Standard Article

Synthesis and Uses of Organosilver Compounds

Organic Derivatives of Gold and Silver (1999)

  1. Hubert Schmidbaur,
  2. Angela Bayler

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0212

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Schmidbaur, H. and Bayler, A. 2009. Synthesis and Uses of Organosilver Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. Technische Universität München, Lehrstuhl für Anorganische und Analytische Chemie, Earching, Germany

Publication History

  1. Published Online: 15 DEC 2009

Featured Compounds

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  1. 1 - 25
Compound 1
Drug synonym:Not Available
Molecular Weight:688.698
Molecular Formula:C24H44Ag2N2Si4
SMILES:C[Si](C)(C)C([Ag])(c1ccccn1)[Si](C)(C)C.C[Si](C)(C)C([Ag])(c1ccccn1)[Si](C)(C)C
InChI:1S/2C12H22NSi2.2Ag/c2*1-14(2,3)12(15(4,5)6)11-9-7-8-10-13-11;;/h2*7-10H,1-6H3;;
InChIKey:KNVLBROGICFTSS-UHFFFAOYSA-N
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Compound 2
Drug synonym:Not Available
Molecular Weight:476.337
Molecular Formula:C8H16AgO8S4
SMILES:[Ag-].O=S1(=O)CCCS(=O)(=O)C1.O=S1(=O)CCCS(=O)(=O)C1
InChI:1S/2C4H8O4S2.Ag/c2*5-9(6)2-1-3-10(7,8)4-9;/h2*1-4H2;/q;;-1
InChIKey:VXKWHDIVJBGDGW-UHFFFAOYSA-N
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Compound 3
Drug synonym:Not Available
Molecular Weight:393.9283
Molecular Formula:C8H20Ag2P2
SMILES:C[P+]1(C)C[Ag-]C[P+](C)(C)C[Ag-]C1
InChI:1S/2C4H10P.2Ag/c2*1-5(2,3)4;;/h2*1-2H2,3-4H3;;/q2*+1;2*-1
InChIKey:VTZJYOICZPUFPD-UHFFFAOYSA-N
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Compound 4
Drug synonym:Not Available
Molecular Weight:474.056
Molecular Formula:C14H28Ag2P2
SMILES:C1CC[P+]2(CC1)C[Ag-]C[P+]1(CCCCC1)C[Ag-]C2
InChI:1S/2C7H14P.2Ag/c2*1-8(2)6-4-3-5-7-8;;/h2*1-7H2;;/q2*+1;2*-1
InChIKey:QEGZKWPTHOTPOJ-UHFFFAOYSA-N
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Compound 5
Drug synonym:Not Available
Molecular Weight:481.824
Molecular Formula:C8H20Ag2As2
SMILES:C[As+]1(C)C[Ag-]C[As+](C)(C)C[Ag-]C1
InChI:1S/2C4H10As.2Ag/c2*1-5(2,3)4;;/h2*1-2H2,3-4H3;;/q2*+1;2*-1
InChIKey:SBOCAXWMFHMKIE-UHFFFAOYSA-N
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Compound 6
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
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Compound 7
Drug synonym:Not Available
Molecular Weight:1372.9719
Molecular Formula:C78H64Ag2O2P4
SMILES:O=C1C([Ag-]C(C(=O)C([Ag-]C1[P+](c1ccccc1)(c1ccccc1)c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1
InChI:1S/2C39H32OP2.2Ag/c2*40-33(31-41(34-19-7-1-8-20-34,35-21-9-2-10-22-35)36-23-11-3-12-24-36)32-42(37-25-13-4-14-26-37,38-27-15-5-16-28-38)39-29-17-6-18-30-39;;/h2*1-32H;;/q2*+2;2*-1
InChIKey:CDBGAQVLOPOMSX-UHFFFAOYSA-N
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Compound 8
Drug synonym:Not Available
Molecular Weight:926.057
Molecular Formula:C46H41AgClO6P3
SMILES:[O-][Cl](=O)(=O)=O.COC(=O)C1[Ag](=P(c2ccccc2)(c2ccccc2)c2ccccc2)=P(C[P+]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
InChI:1S/C28H26O2P2.C18H15P.Ag.ClHO4/c1-30-28(29)22-32(26-18-10-4-11-19-26,27-20-12-5-13-21-27)23-31(24-14-6-2-7-15-24)25-16-8-3-9-17-25;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;2-1(3,4)5/h2-22H,23H2,1H3;1-15H;;(H,2,3,4,5)/q+1;;;/p-1
InChIKey:HJYNCNKGLWVHDV-UHFFFAOYSA-M
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Compound 9
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
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Compound 10
Drug synonym:Not Available
Molecular Weight:678.283
Molecular Formula:C26H24Ag2P2S2
SMILES:[Ag]CP(=S)(c1ccccc1)c1ccccc1.[Ag]CP(=S)(c1ccccc1)c1ccccc1
InChI:1S/2C13H12PS.2Ag/c2*1-14(15,12-8-4-2-5-9-12)13-10-6-3-7-11-13;;/h2*2-11H,1H2;;
InChIKey:QZTXLZBJFYZVAX-UHFFFAOYSA-N
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Compound 11
Drug synonym:Not Available
Molecular Weight:1076.698
Molecular Formula:C52H48Ag2P4S2
SMILES:C[P+](C([Ag])P(=S)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.C[P+](C([Ag])P(=S)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
InChI:1S/2C26H24P2S.2Ag/c2*1-27(23-14-6-2-7-15-23,24-16-8-3-9-17-24)22-28(29,25-18-10-4-11-19-25)26-20-12-5-13-21-26;;/h2*2-22H,1H3;;/q2*+1;;
InChIKey:JYKQZQQQGFSKAR-UHFFFAOYSA-N
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Compound 12
Drug synonym:Not Available
Molecular Weight:317.941
Molecular Formula:C5H3AgF7N
SMILES:CC#N.FC(F)(F)C(F)([Ag])C(F)(F)F
InChI:1S/C3F7.C2H3N.Ag/c4-1(2(5,6)7)3(8,9)10;1-2-3;/h;1H3;
InChIKey:WPIMBWFCDQMOOP-UHFFFAOYSA-N
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Compound 13
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
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Compound 15
Drug synonym:Not Available
Molecular Weight:227.0518
Molecular Formula:C9H11Ag
SMILES:Cc1cc(C)c([Ag])c(C)c1
InChI:1S/C9H11.Ag/c1-7-4-8(2)6-9(3)5-7;/h4-5H,1-3H3;
InChIKey:NYELAPCNIJKSNE-UHFFFAOYSA-N
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Compound 16
Drug synonym:Not Available
Molecular Weight:413.26
Molecular Formula:C24H17Ag
SMILES:[Ag]c1c(cc(cc1-c1ccccc1)-c1ccccc1)-c1ccccc1
InChI:1S/C24H17.Ag/c1-4-10-19(11-5-1)22-16-23(20-12-6-2-7-13-20)18-24(17-22)21-14-8-3-9-15-21;/h1-17H;
InChIKey:ZFCKFAHTLOTVFZ-UHFFFAOYSA-N
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Compound 17
Drug synonym:Not Available
Molecular Weight:242.0665
Molecular Formula:C9H12AgN
SMILES:CN(C)Cc1ccccc1[Ag]
InChI:1S/C9H12N.Ag/c1-10(2)8-9-6-4-3-5-7-9;/h3-6H,8H2,1-2H3;
InChIKey:RTFIDKBDDPCERA-UHFFFAOYSA-N
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Compound 18
Drug synonym:Not Available
Molecular Weight:245.0241
Molecular Formula:C8H9AgO2
SMILES:COc1cccc(OC)c1[Ag]
InChI:1S/C8H9O2.Ag/c1-9-7-4-3-5-8(6-7)10-2;/h3-5H,1-2H3;
InChIKey:TXXNYAYLUKVZCJ-UHFFFAOYSA-N
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Compound 19
Drug synonym:Not Available
Molecular Weight:275.05
Molecular Formula:C9H11AgO3
SMILES:COc1cc(OC)c([Ag])c(OC)c1
InChI:1S/C9H11O3.Ag/c1-10-7-4-8(11-2)6-9(5-7)12-3;/h4-5H,1-3H3;
InChIKey:KBQAVMHZTAHQHG-UHFFFAOYSA-N
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Compound 20
Drug synonym:Not Available
Molecular Weight:265.0601
Molecular Formula:C10H9AgN2
SMILES:[Ag]c1nccn1Cc1ccccc1
InChI:1S/C10H9N2.Ag/c1-2-4-10(5-3-1)8-12-7-6-11-9-12;/h1-7H,8H2;
InChIKey:UEQAUAYXFBNUQP-UHFFFAOYSA-N
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Compound 21
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
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Compound 22
Drug synonym:Not Available
Molecular Weight:686.277
Molecular Formula:C32H40Ag2Li2O2
SMILES:CCOCC.CCOCC.[Li]c1ccccc1.[Li]c1ccccc1.[Ag]c1ccccc1.[Ag]c1ccccc1
InChI:1S/4C6H5.2C4H10O.2Ag.2Li/c4*1-2-4-6-5-3-1;2*1-3-5-4-2;;;;/h4*1-5H;2*3-4H2,1-2H3;;;;
InChIKey:KFPNVELRXLVPAN-UHFFFAOYSA-N
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Compound 23
Drug synonym:Not Available
Molecular Weight:766.412
Molecular Formula:C36H48Ag2Li2N4
SMILES:[Li]c1ccccc1CN(C)C.[Li]c1ccccc1CN(C)C.CN(C)Cc1ccccc1[Ag].CN(C)Cc1ccccc1[Ag]
InChI:1S/4C9H12N.2Ag.2Li/c4*1-10(2)8-9-6-4-3-5-7-9;;;;/h4*3-6H,8H2,1-2H3;;;;
InChIKey:RCHDMQXITBMQRE-UHFFFAOYSA-N
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Compound 24
Drug synonym:Not Available
Molecular Weight:Not Available
Molecular Formula:Not Available
SMILES:Not Available
InChI:Not Available
InChIKey:Not Available
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Compound 25
Drug synonym:Not Available
Molecular Weight:1413.809
Molecular Formula:C55H53AgAu2F3O3P2S
SMILES:[O-]S(=O)(=O)C(F)(F)F.Cc1cc(C)c([Au]([Ag-][Au](c2c(C)cc(C)cc2C)[P+](c2ccccc2)(c2ccccc2)c2ccccc2)[P+](c2ccccc2)(c2ccccc2)c2ccccc2)c(C)c1
InChI:1S/2C18H15P.2C9H11.CHF3O3S.Ag.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-7-4-8(2)6-9(3)5-7;2-1(3,4)8(5,6)7;;;/h2*1-15H;2*4-5H,1-3H3;(H,5,6,7);;;/q;;;;;-1;2*+1/p-1
InChIKey:AZERTWJIOVQCCE-UHFFFAOYSA-M
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Compound 26
Drug synonym:Not Available
Molecular Weight:865.794
Molecular Formula:C43H49AgF3N4O3S
SMILES:[O-]S(=O)(=O)C(F)(F)F.Cc1cc(C)c(c(C)c1)-n1ccn(-c2c(C)cc(C)cc2C)[c+]1[Ag][c+]1n(ccn1-c1c(C)cc(C)cc1C)-c1c(C)cc(C)cc1C
InChI:1S/2C21H24N2.CHF3O3S.Ag/c2*1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;2-1(3,4)8(5,6)7;/h2*7-12H,1-6H3;(H,5,6,7);/q2*+1;;/p-1
InChIKey:KYVGQBFZFHVMBU-UHFFFAOYSA-M
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