Standard Article

29Si NMR Experiments in Solutions of Organosilicon Compounds

Organic Silicon Compounds (2001)

  1. Jan Schraml

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0237

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Schraml, J. 2009. 29Si NMR Experiments in Solutions of Organosilicon Compounds. Patai's Chemistry of Functional Groups. .

Author Information

  1. Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Prague, Czech Republic

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Basic Facts
  • 3
    Referencing
  • 4
    Solvent Effects
  • 5
    Sensitivity Enhancements
  • 6
    Line Assignments and Connectivity
  • 7
    Determination of Coupling Constants
  • 8
    Relaxations
  • 9
    Nuclear Overhauser Effect (NOE)
  • 10
    Miscellaneous
  • 11
    Common Mistakes and Pitfalls—Comments and Warnings
  • 12
    Acknowledgements

Keywords:

  • organosilicon compound solution and Si NMR experiments;
  • solvent effects;
  • line assignments and connectivity;
  • triple resonance;
  • sensitivity enhancements;
  • Fourier transform NMR spectroscopy techniques (FT NMR);
  • INADEQUATE and double-quantum filter;
  • coupling constant determination