Standard Article

Silyl Radicals

Organic Silicon Compounds (2001)

  1. C. Chatgilialoglu1,
  2. C.H. Schiesser2

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0238

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Chatgilialoglu, C. and Schiesser, C. 2009. Silyl Radicals. Patai's Chemistry of Functional Groups. .

Author Information

  1. 1

    Consiglio Nazionale delle Ricerche, I.Co.C.E.A., Bologna, Italy

  2. 2

    The University of Melbourne, Victoria, School of Chemistry, Victoria, Australia

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Organosilyl Radical Structure, Reactions and Mechanisms
  • 3
    Organosilanes as Reagents in Radical Chain Reactions

Keywords:

  • silyl radicals;
  • organosilyl radical structure, reactions and mechanisms;
  • silyl radical chemical properties;
  • organosilanes as radical chain reaction reagents;
  • tris(trimethylsilyl)silane;
  • consecutive radical reactions;
  • allylations;
  • radical allylations with allylsilanes

Featured Compounds

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  1. 1 - 104
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2
Molecular Weight:324.6073
Molecular Formula:C20H28Si2
InChIKey:FHBHHEICZUZNEK-UHFFFAOYSA-N
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Compound 3
Molecular Weight:323.5994
Molecular Formula:C20H27Si2
InChIKey:FHBHHEICZUZNEK-UHFFFAOYSA-N
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:289.7324
Molecular Formula:C12H33Si4
InChIKey:VCDJSOAZCOJLJX-UHFFFAOYSA-N
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Compound 7
Molecular Weight:331.8122
Molecular Formula:C15H39Si4
InChIKey:OUDOFAKFAKCELX-UHFFFAOYSA-N
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Compound 8
Molecular Weight:373.8919
Molecular Formula:C18H45Si4
InChIKey:WNGZMQFMMHZKBG-UHFFFAOYSA-N
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Compound 9
Molecular Weight:500.1311
Molecular Formula:C27H63Si4
InChIKey:WMMCOVKZESATGH-UHFFFAOYSA-N
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Compound 10
Molecular Weight:373.8919
Molecular Formula:C18H45Si4
InChIKey:JNCHSHLNFDMVJJ-UHFFFAOYSA-N
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Compound 11
Molecular Weight:75.1619
Molecular Formula:C2H7OSi
InChIKey:LWIGVRDDANOFTD-UHFFFAOYSA-N
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Compound 12
Molecular Weight:75.1613
Molecular Formula:C2H7OSi
InChIKey:QRAPFBOJMGMROL-UHFFFAOYSA-N
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Compound 61
Molecular Weight:256.4903
Molecular Formula:C15H20Si2
InChIKey:GMYXDFFQZJVNAZ-UHFFFAOYSA-N
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Compound 62
Molecular Weight:230.401
Molecular Formula:C13H14SSi
InChIKey:ZKRPWXZKBYBVSS-UHFFFAOYSA-N
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Compound 63
Molecular Weight:214.4106
Molecular Formula:C12H14Si2
InChIKey:YYAHGALKQFCAFZ-UHFFFAOYSA-N
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Compound 13
Molecular Weight:290.7727
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 14
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 15
Molecular Weight:281.4012
Molecular Formula:C17H17O2Si
InChIKey:AJMXZPFUYCLGEZ-UHFFFAOYSA-N
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Compound 16
Molecular Weight:501.0221
Molecular Formula:C30H56Si3
InChIKey:ZROFKDAHRWBJLE-UHFFFAOYSA-N
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Compound 19
Molecular Weight:340.727
Molecular Formula:C14H24S2Si3
InChIKey:QPDSEFDPPJWNRT-UHFFFAOYSA-N
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Compound 17
Molecular Weight:365.7637
Molecular Formula:C22H45Si2
InChIKey:MKRRAMOGHVSMJG-UHFFFAOYSA-N
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Compound 20
Molecular Weight:268.546
Molecular Formula:C11H16S2Si2
InChIKey:CIBLDOXLUPTALQ-UHFFFAOYSA-N
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Compound 21
Molecular Weight:308.5957
Molecular Formula:C14H24O2Si3
InChIKey:PIWWEMYDIUQCBD-UHFFFAOYSA-N
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Compound 22
Molecular Weight:402.516
Molecular Formula:C8H24Cl4Si5
InChIKey:KTCMIGLPOACLHU-UHFFFAOYSA-N
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Compound 23
Molecular Weight:772.0515
Molecular Formula:C27H82Si13
InChIKey:VWHYXBVFKWELJV-UHFFFAOYSA-N
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Compound 24
Molecular Weight:844.2326
Molecular Formula:C30H90Si14
InChIKey:XLTICRKQLKJUEZ-UHFFFAOYSA-N
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Compound 25
Molecular Weight:266.602
Molecular Formula:C13H26Si3
InChIKey:HGPBJAMQWFNHCU-UHFFFAOYSA-N
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Compound 26
Molecular Weight:324.7566
Molecular Formula:C15H32Si4
InChIKey:NLVCCJAWWLJRKO-UHFFFAOYSA-N
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Compound 27
Molecular Weight:348.9272
Molecular Formula:C12H36Si6
InChIKey:RTCLHEHPUHREBC-UHFFFAOYSA-N
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Compound 28
Molecular Weight:616.25
Molecular Formula:C12H36Ge6
InChIKey:DEOSXKDJJKBMNZ-UHFFFAOYSA-N
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Compound 29
Molecular Weight:354.7087
Molecular Formula:C20H30Si3
InChIKey:ZQCBDOSOKXYSHP-UHFFFAOYSA-N
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Compound 30
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 31
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 34
Molecular Weight:62.1002
Molecular Formula:H2O2Si
InChIKey:PXRMLPZQBFWPCV-UHFFFAOYSA-N
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Compound 35
Molecular Weight:221.4969
Molecular Formula:C7H21O2Si3
InChIKey:KFXSRVHINCNROW-UHFFFAOYSA-N
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Compound 37
Molecular Weight:221.4969
Molecular Formula:C7H21O2Si3
InChIKey:FAMLAZBYJQGVTF-UHFFFAOYSA-N
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Compound 36
Molecular Weight:221.4969
Molecular Formula:C7H21O2Si3
InChIKey:ZVBQNPNGDUYLMK-UHFFFAOYSA-N
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Compound 38
Molecular Weight:221.4969
Molecular Formula:C7H21O2Si3
InChIKey:QNWOFLWXQGHSRH-UHFFFAOYSA-N
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Compound 39
Molecular Weight:66.1011
Molecular Formula:C5H6
InChIKey:ZTXSPLGEGCABFL-UHFFFAOYSA-N
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Compound 40
Molecular Weight:181.3699
Molecular Formula:C11H21Si
InChIKey:RELUHNFKBLFTKS-UHFFFAOYSA-N
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Compound 41
Molecular Weight:1449.8152
Molecular Formula:C108H40Si4
InChIKey:SYYDYVKJXDOXPW-UHFFFAOYSA-N
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Compound 42
Molecular Weight:1448.8073
Molecular Formula:C108H39Si4
InChIKey:SYYDYVKJXDOXPW-UHFFFAOYSA-N
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Compound 44
Molecular Weight:820.2601
Molecular Formula:C54H43OSi4
InChIKey:SLVVIIADAQUIDH-UHFFFAOYSA-N
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Compound 45
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 47
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 50
Molecular Weight:1199.4571
Molecular Formula:C92H38Si2
InChIKey:YVQGWTHREZVPPI-UHFFFAOYSA-N
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Compound 51
Molecular Weight:1199.4571
Molecular Formula:C92H38Si2
InChIKey:DVCDBWMDHAFHSK-UHFFFAOYSA-N
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Compound 105
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 57
Molecular Weight:73.146
Molecular Formula:C2H5OSi
InChIKey:SLKVCTUCNPKKAT-UHFFFAOYSA-N
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Compound 58
Molecular Weight:73.146
Molecular Formula:C2H5OSi
InChIKey:RHAMJWUQPYGPFM-UHFFFAOYSA-N
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Compound 59
Molecular Weight:73.146
Molecular Formula:C2H5OSi
InChIKey:CPBHJGWJMLDUNB-UHFFFAOYSA-N
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Compound 60
Molecular Weight:576.389
Molecular Formula:C32H16N8OTi
InChIKey:SJHHDDDGXWOYOE-UHFFFAOYSA-N
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Compound 64
Molecular Weight:151.034
Molecular Formula:C6H8Cl2
InChIKey:HNNSUVSMKQVPCJ-UHFFFAOYSA-N
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Compound 65
Molecular Weight:361.217
Molecular Formula:C16H18Cl2O5
InChIKey:NIZGHNWBNWIEGD-CXTNEJHOSA-N
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Compound 66
Molecular Weight:611.78
Molecular Formula:C27H44N2O5SeSi2
InChIKey:JNDJFBDBBZNEOM-MSNJVRRCSA-N
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Compound 67
Molecular Weight:650.888
Molecular Formula:C29H42N2O9SSi2
InChIKey:LILFYLQINDIMSZ-CTDWIVFPSA-N
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Compound 68
Molecular Weight:402.35
Molecular Formula:C20H21NO3Se
InChIKey:CHKYRFCWRSMTDH-UHFFFAOYSA-N
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Compound 69
Molecular Weight:296.27
Molecular Formula:C14H19NOSe
InChIKey:PVFRRZOAFPWFJO-UHFFFAOYSA-N
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Compound 70
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 72
Molecular Weight:239.107
Molecular Formula:C8H15BrO3
InChIKey:VBUCTLDUXSNAPM-JEDNCBNOSA-N
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Compound 73
Molecular Weight:331.268
Molecular Formula:C14H19BrO2S
InChIKey:SAVUNZFVYZIUCO-GFOMBABLSA-N
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Compound 74
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:437.485
Molecular Formula:C25H27NO6
InChIKey:RJWFNVVQUNHMKR-YOEKFXIASA-N
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Compound 76
Molecular Weight:545.646
Molecular Formula:C31H31NO6S
InChIKey:ZGBVTDFIPCXGFB-MJAHCGDXSA-N
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Compound 78
Molecular Weight:619.78
Molecular Formula:C35H40OS2Se
InChIKey:ASDMUEWHVLBHLO-LAGRICQCSA-N
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Compound 79
Molecular Weight:246.3877
Molecular Formula:C17H26O
InChIKey:FWPDMLVNBGPLNP-TWTHRLDESA-N
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Compound 80
Molecular Weight:354.549
Molecular Formula:C23H30OS
InChIKey:NYDBJMIHNXRYLF-IDPYYCDMSA-N
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Compound 81
Molecular Weight:501.787
Molecular Formula:C22H23Cl3N2O5
InChIKey:IGHZKCQAEJIATD-UHFFFAOYSA-N
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Compound 82
Molecular Weight:398.4522
Molecular Formula:C22H26N2O5
InChIKey:KFPPPTFCGKNVTD-UEXGIBASSA-N
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Compound 83
Molecular Weight:409.36
Molecular Formula:C18H18O4SSe
InChIKey:JGRJDULSYHHDAV-OUKQBFOZSA-N
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Compound 84
Molecular Weight:254.302
Molecular Formula:C12H14O4S
InChIKey:AIQTWLFCLWSCSQ-JOYOIKCWSA-N
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Compound 85a
Molecular Weight:341.26
Molecular Formula:C15H18O4Se
InChIKey:HXIVNXHTGZIPFC-IIANPFDCSA-N
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Compound 85b
Molecular Weight:423.38
Molecular Formula:C19H20O4SSe
InChIKey:NGDYABKBYWIUKD-IYOXOMEYSA-N
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Compound 86
Molecular Weight:186.2051
Molecular Formula:C9H14O4
InChIKey:MXBFYLIXGZHMIH-POYBYMJQSA-N
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Compound 87
Molecular Weight:268.329
Molecular Formula:C13H16O4S
InChIKey:CIPRZPBGUPAWEH-GXFFZTMASA-N
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Compound 88
Molecular Weight:397.32
Molecular Formula:C18H22O5Se
InChIKey:RWNCSHXQYXOYHG-MVDMCNAVSA-N
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Compound 89
Molecular Weight:707.73
Molecular Formula:C37H40O7SSe
InChIKey:QXIHYOXFARJPJZ-KWNHOTCJSA-N
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Compound 90
Molecular Weight:355.29
Molecular Formula:C16H20O4Se
InChIKey:NPTRMJCRQGBZLF-YLSINNKHSA-N
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Compound 91
Molecular Weight:304.4669
Molecular Formula:C20H32O2
InChIKey:XLAXAEUVSDKNMH-BIPSIXNQSA-N
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Compound 92
Molecular Weight:290.4403
Molecular Formula:C19H30O2
InChIKey:HTBOWVZXXBRJFC-UHFFFAOYSA-N
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Compound 93
Molecular Weight:446.306
Molecular Formula:C15H19IN4O2S
InChIKey:VCCSDCJUQKYJOF-UHFFFAOYSA-N
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Compound 95
Molecular Weight:292.397
Molecular Formula:C15H20N2O2S
InChIKey:JBCFXPULTKRBRS-SOUVJXGZSA-N
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Compound 94
Molecular Weight:539.041
Molecular Formula:C24H46N2O2SSi4
InChIKey:RNENQTWZORYIJC-KMDXXIMOSA-N
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Compound 96
Molecular Weight:332.2204
Molecular Formula:C14H21IO
InChIKey:CWKIWSVKVDZZOU-PVYBRLDNSA-N
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Compound 97
Molecular Weight:220.3505
Molecular Formula:C15H24O
InChIKey:PTMXFPLEASLVFK-XQLPTFJDSA-N
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Compound 98
Molecular Weight:252.3062
Molecular Formula:C14H20O4
InChIKey:MJYUDOISVDVPKB-UHFFFAOYSA-N
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Compound 99
Molecular Weight:137.2221
Molecular Formula:C9H15N
InChIKey:LHFOBQMZIHZSDD-CSKARUKUSA-N
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Compound 101
Molecular Weight:535.0692
Molecular Formula:C28H54O2Si4
InChIKey:UXGBISVWNAUGHH-SBLABSPLSA-N
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Compound 100
Molecular Weight:396.585
Molecular Formula:C25H32O2S
InChIKey:MUDQCBMDWQKKFG-SPABJCFRSA-N
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Compound 102
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 103
Molecular Weight:487.039
Molecular Formula:C20H42O2SSi5
InChIKey:VGYRFOPZKIDNNE-UHFFFAOYSA-N
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Compound 104
Molecular Weight:282.4522
Molecular Formula:C18H22OSi
InChIKey:KAKFRPFWRQJJGB-UHFFFAOYSA-N
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Compound 106
Molecular Weight:242.4729
Molecular Formula:C14H30OSi
InChIKey:LRCXSHDMMWZLCW-UHFFFAOYSA-N
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Compound 107
Molecular Weight:215.044
Molecular Formula:C8H7BrO2
InChIKey:UEWYUCGVQMZMGY-UHFFFAOYSA-N
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Compound 108
Molecular Weight:236.3068
Molecular Formula:C14H20O3
InChIKey:SHJOAHACNWZRJR-UHFFFAOYSA-N
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Compound 109
Molecular Weight:135.14
Molecular Formula:C8H7O2
InChIKey:IPBVNPXQWQGGJP-UHFFFAOYSA-N
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Compound 110
Molecular Weight:377.6129
Molecular Formula:C22H37O3Si
InChIKey:IQDNLVKVTQYDGB-UHFFFAOYSA-N
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Compound 111
Molecular Weight:377.6129
Molecular Formula:C22H37O3Si
InChIKey:IQDNLVKVTQYDGB-UHFFFAOYSA-N
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Compound 112
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 113
Molecular Weight:346.7606
Molecular Formula:C14H34O2Si4
InChIKey:FLTZTYNMYBLEFK-UHFFFAOYSA-N
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  1. 1 - 104