Standard Article

Recent Developments in the Chemistry of Compounds with Silicon–Nitrogen Bonds

Organic Silicon Compounds (2001)

  1. Peter Neugebauer,
  2. Bettina Jaschke,
  3. Uwe Klingebiel

Published Online: 15 DEC 2009

DOI: 10.1002/9780470682531.pat0240

Patai's Chemistry of Functional Groups

Patai's Chemistry of Functional Groups

How to Cite

Neugebauer, P., Jaschke, B. and Klingebiel, U. 2009. Recent Developments in the Chemistry of Compounds with Silicon–Nitrogen Bonds. Patai's Chemistry of Functional Groups. .

Author Information

  1. University of Goettingen, Institute of Inorganic Chemistry, Goettingen, Germany

Publication History

  1. Published Online: 15 DEC 2009

Abstract

  • 1
    Introduction
  • 2
    Preparation and Properties of the Si[BOND]N Bond
  • 3
    Aminosilanes
  • 4
    Lithium Derivatives of Silylamines
  • 5
    Lithium Derivatives of Hydrazines
  • 6
    Iminosilanes
  • 7
    Cyclic Silicon–Nitrogen Compounds
  • 8
    Cyclodisilazanes
  • 9
    Cyclotrisilazanes
  • 10
    Cyclotetrasilazanes
  • 11
    Application of Cyclosilazanes as Precursors for Silicon-Based Ceramics

Keywords:

  • Si[BOND]N bond preparation;
  • silylamine preparation involving H2 elimination;
  • lithium derivatives of silylamines;
  • lithium derivatives of hydrazines;
  • cyclodisilazanes;
  • NH-functional cyclodisilazane lithiation;
  • cyclotetrasilazanes;
  • interconversion reactions

Featured Compounds

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  1. 1 - 152
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 76
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 7
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 9
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 11
Molecular Weight:171.3552
Molecular Formula:C9H21NSi
InChIKey:GXLZMBVLJWXRIB-UHFFFAOYSA-N
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Compound 12
Molecular Weight:189.329
Molecular Formula:C11H15NSi
InChIKey:FVTIWXTUSQSDKB-UHFFFAOYSA-N
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Compound 13
Molecular Weight:204.3885
Molecular Formula:C8H24N4Si
InChIKey:SSCVMVQLICADPI-UHFFFAOYSA-N
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Compound 14
Molecular Weight:204.3885
Molecular Formula:C8H24N4Si
InChIKey:SSCVMVQLICADPI-UHFFFAOYSA-N
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Compound 15
Molecular Weight:145.3503
Molecular Formula:C5H15NSi2
InChIKey:IQLGVHROSAXBAG-UHFFFAOYSA-N
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Compound 16
Molecular Weight:146.3384
Molecular Formula:C4H14N2Si2
InChIKey:SBABCWSGUZFAAS-UHFFFAOYSA-N
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Compound 17
Molecular Weight:159.3769
Molecular Formula:C6H17NSi2
InChIKey:LSVFYHKGPYLGAK-UHFFFAOYSA-N
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Compound 18
Molecular Weight:262.6474
Molecular Formula:C8H26N2Si4
InChIKey:FAOJKZYVDUKALA-UHFFFAOYSA-N
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Compound 19
Molecular Weight:319.5477
Molecular Formula:C19H21NSi2
InChIKey:VWWJHCQHJATLIE-UHFFFAOYSA-N
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Compound 20
Molecular Weight:347.6009
Molecular Formula:C21H25NSi2
InChIKey:BPFUNLWWZJNYBD-UHFFFAOYSA-N
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Compound 21
Molecular Weight:229.4252
Molecular Formula:C12H15NSi2
InChIKey:AXIFIIKRWNZSFH-UHFFFAOYSA-N
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Compound 22
Molecular Weight:257.4784
Molecular Formula:C14H19NSi2
InChIKey:SUTYUQBZYOVCGG-UHFFFAOYSA-N
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Compound 23
Molecular Weight:292.7812
Molecular Formula:C6H24N2Si6
InChIKey:ZLDKJQWFTZHHHR-UHFFFAOYSA-N
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Compound 24
Molecular Weight:191.5265
Molecular Formula:C4H17NSi4
InChIKey:DUKFGFDWUXGAOH-UHFFFAOYSA-N
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Compound 25
Molecular Weight:377.7023
Molecular Formula:C21H27NSi3
InChIKey:YULYQFNOLIDLOA-UHFFFAOYSA-N
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Compound 26
Molecular Weight:267.5901
Molecular Formula:C12H25NSi3
InChIKey:GTTYJUABHVMCLX-UHFFFAOYSA-N
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Compound 27
Molecular Weight:335.6225
Molecular Formula:C18H21NSi3
InChIKey:BEIZNPJXIBPTDR-UHFFFAOYSA-N
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Compound 28
Molecular Weight:301.6063
Molecular Formula:C15H23NSi3
InChIKey:GWIVNVSOVHIPLR-UHFFFAOYSA-N
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Compound 29
Molecular Weight:381.545
Molecular Formula:C24H23N3Si
InChIKey:DFPSJJBPZRWHRN-UHFFFAOYSA-N
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Compound 30
Molecular Weight:337.5755
Molecular Formula:C18H35N3OSi
InChIKey:OKVLTJUVNQZBSY-UHFFFAOYSA-N
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Compound 31
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 32
Molecular Weight:307.7311
Molecular Formula:C10H33N3Si4
InChIKey:TXCIGUCDBWZMDD-UHFFFAOYSA-N
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 86
Molecular Weight:501.833
Molecular Formula:C18H46Cl2N4Si4
InChIKey:LDZGWBABKLEYDN-UHFFFAOYSA-N
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Compound 34
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 35
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 36
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 37
Molecular Weight:554.876
Molecular Formula:C30H40Li2N2Si4
InChIKey:FTAPQMXHXRCHNB-UHFFFAOYSA-N
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Compound 38
Molecular Weight:474.917
Molecular Formula:C22H56Li2N2Si4
InChIKey:BTTSHPVQVYLFEK-UHFFFAOYSA-N
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Compound 39
Molecular Weight:442.768
Molecular Formula:C24H56Li2N2Si2
InChIKey:ZUJWAUSMTJXLSI-UHFFFAOYSA-N
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Compound 40
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 42
Molecular Weight:630.99
Molecular Formula:C42H63LiN2Si
InChIKey:KRQSTBLBBLNKDP-NALJPSAASA-N
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Compound 41
Molecular Weight:705.111
Molecular Formula:C46H73LiN2OSi
InChIKey:GIVINIQSFCLGKL-OGDGMPRMSA-N
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Compound 43
Molecular Weight:859.316
Molecular Formula:C52H91LiN2O5Si
InChIKey:QQVNVUCFBDSZAZ-IAXKJERASA-N
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Compound 44
Molecular Weight:384.7547
Molecular Formula:C18H37FN2Si3
InChIKey:CTEGJESZWCIZHN-UHFFFAOYSA-N
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Compound 45
Molecular Weight:396.621
Molecular Formula:C18H35FLi2N2Si3
InChIKey:SCIWYPPEQRVANG-UHFFFAOYSA-N
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Compound 47
Molecular Weight:1029.786
Molecular Formula:C52H102Li2N4O4Si6
InChIKey:UETVJDGOXYUASR-DYJXUTKKSA-N
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Compound 48
Molecular Weight:671.381
Molecular Formula:C22H68Li2N6OSi8
InChIKey:MVXPOONOMHAUCY-UHFFFAOYSA-N
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Compound 49
Molecular Weight:739.455
Molecular Formula:C26H72Li2N6O2Si8
InChIKey:DCYURIBKOAKFKP-UHFFFAOYSA-N
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Compound 50
Molecular Weight:734.768
Molecular Formula:C32H72Li6N6O6Si2
InChIKey:TXSRZJILLKOPRD-UHFFFAOYSA-N
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Compound 51
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 52
Molecular Weight:738.13
Molecular Formula:C33H73FLiNO9Si3
InChIKey:BVMHPWKQMUJYOU-UHFFFAOYSA-N
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Compound 53
Molecular Weight:530.301
Molecular Formula:C26H57ClLiNO3Si2
InChIKey:DKMYNJBSWLMZDB-UHFFFAOYSA-N
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Compound 54
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 55
Molecular Weight:977.231
Molecular Formula:C40H104Li8N16Si4
InChIKey:LGOXUUMODNWQIN-UHFFFAOYSA-N
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Compound 56
Molecular Weight:860.275
Molecular Formula:C48H82F4LiNO3Si2
InChIKey:LMQSERCAEOHUCC-UHFFFAOYSA-N
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Compound 57
Molecular Weight:807.168
Molecular Formula:C44H74F5LiNO2Si2
InChIKey:UCGQCFNTQYTHGI-UHFFFAOYSA-M
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Compound 58
Molecular Weight:572.91
Molecular Formula:C30H66Li2N2O3Si2
InChIKey:PEOKPSLUHIEHPJ-UHFFFAOYSA-N
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Compound 59
Molecular Weight:612.958
Molecular Formula:C32H46Li2N4Si4
InChIKey:BDINOOALKLFMLR-UHFFFAOYSA-N
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Compound 60
Molecular Weight:624.825
Molecular Formula:C32H44Li4N4Si4
InChIKey:FNRGLFVXGDKBFS-UHFFFAOYSA-N
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Compound 62
Molecular Weight:375.7386
Molecular Formula:C22H41NSi2
InChIKey:NIPRGGUAKFVKRU-UHFFFAOYSA-N
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Compound 61
Molecular Weight:617.995
Molecular Formula:C34H65FLiNO3Si2
InChIKey:PSYSRJPFDBXCCZ-UHFFFAOYSA-N
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Compound 63
Molecular Weight:355.749
Molecular Formula:C20H45NSi2
InChIKey:VRYORSBIKQOYCJ-UHFFFAOYSA-N
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Compound 64
Molecular Weight:75.2174
Molecular Formula:H5NSi2
InChIKey:QCEJSTYKRODNLI-UHFFFAOYSA-N
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Compound 65
Molecular Weight:375.7386
Molecular Formula:C22H41NSi2
InChIKey:NIPRGGUAKFVKRU-UHFFFAOYSA-N
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Compound 66
Molecular Weight:447.8237
Molecular Formula:C25H50AlNSi2
InChIKey:KZQMDLJBMDBACM-UHFFFAOYSA-N
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Compound 68
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 69
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 67
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 70
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 71
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 72
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 73
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 77
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 74
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 75
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 78
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 79
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 80
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 81
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 82
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 83
Molecular Weight:342.7105
Molecular Formula:C18H42N2Si2
InChIKey:COXXQXOPTUHDMK-UHFFFAOYSA-N
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Compound 84
Molecular Weight:346.6561
Molecular Formula:C16H38N2O2Si2
InChIKey:WRDYNLUUWWGLAM-UHFFFAOYSA-N
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Compound 85
Molecular Weight:540.693
Molecular Formula:C18H42Cl4N2Si4
InChIKey:UWNPEDIXNHZMMO-UHFFFAOYSA-N
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Compound 87
Molecular Weight:402.9132
Molecular Formula:C18H46N2Si4
InChIKey:XYLXLMWINTYVRS-UHFFFAOYSA-N
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Compound 88
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 89
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 90
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 91
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 93
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 92
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 94
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 95
Molecular Weight:214.278
Molecular Formula:C10H24Li2N2Si
InChIKey:MLBYAQFPBBQSPW-UHFFFAOYSA-N
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Compound 96
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 97
Molecular Weight:292.537
Molecular Formula:C14H33LiN2Si2
InChIKey:COIVJXYBVRJHQQ-UHFFFAOYSA-N
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Compound 98
Molecular Weight:615.3204
Molecular Formula:C29H70N4Si5
InChIKey:ZTYUESJDSLNXQU-UHFFFAOYSA-N
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Compound 100
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 99
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 101
Molecular Weight:219.5075
Molecular Formula:C6H21N3Si3
InChIKey:WGGNJZRNHUJNEM-UHFFFAOYSA-N
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Compound 102
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 103
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 104
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 105
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 106
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 107
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 108
Molecular Weight:815.383
Molecular Formula:C24H63B9F6N12Si3
InChIKey:ZKIKAVABBFORCM-UHFFFAOYSA-N
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Compound 110
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 109
Molecular Weight:225.441
Molecular Formula:C6H20LiN3Si3
InChIKey:CIUYCDIIQCFIBY-UHFFFAOYSA-N
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Compound 111
Molecular Weight:341.6962
Molecular Formula:C10H29F2N3Si4
InChIKey:CTTGBLJQGCOQAS-UHFFFAOYSA-N
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Compound 112
Molecular Weight:463.8848
Molecular Formula:C14H37F4N3Si5
InChIKey:VYMMLMLRNNRNNG-UHFFFAOYSA-N
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Compound 113
Molecular Weight:586.0734
Molecular Formula:C18H45F6N3Si6
InChIKey:CMEBNCUMBXFUIH-UHFFFAOYSA-N
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Compound 114
Molecular Weight:569.9986
Molecular Formula:C19H45F6N3Si5
InChIKey:FNABPDAIOVMHAP-UHFFFAOYSA-N
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Compound 115
Molecular Weight:887.7569
Molecular Formula:C28H72F6N6Si10
InChIKey:ARKSYQAGWMBWKX-UHFFFAOYSA-N
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Compound 116
Molecular Weight:463.8848
Molecular Formula:C14H37F4N3Si5
InChIKey:VBTWINQEUHGYPK-UHFFFAOYSA-N
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Compound 117
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 118
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 117a
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 119
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 120
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 121
Molecular Weight:375.7614
Molecular Formula:C9H28F3N3Si5
InChIKey:YZKFDANSJPWRGK-UHFFFAOYSA-N
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Compound 122
Molecular Weight:647.4437
Molecular Formula:C18H56F2N6Si9
InChIKey:ZBCOWQOTAZGSNZ-UHFFFAOYSA-N
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Compound 123
Molecular Weight:647.4437
Molecular Formula:C18H56F2N6Si9
InChIKey:CLKZVXKXKPKZPT-UHFFFAOYSA-N
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Compound 124
Molecular Weight:359.74
Molecular Formula:C10H31FLiN3Si5
InChIKey:MGLBJEHEUGTHLD-UHFFFAOYSA-N
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Compound 125
Molecular Weight:359.74
Molecular Formula:C10H31FLiN3Si5
InChIKey:VLBAJYDZZNSAFT-UHFFFAOYSA-N
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Compound 126
Molecular Weight:685.5919
Molecular Formula:C20H61FN6Si10
InChIKey:GOJLPGDMGUXOHK-UHFFFAOYSA-N
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Compound 127
Molecular Weight:667.6015
Molecular Formula:C20H62N6Si10
InChIKey:HHFQDFMOWHNROC-UHFFFAOYSA-N
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Compound 128
Molecular Weight:785.077
Molecular Formula:C30H73B6F4N9Si3
InChIKey:RABRCJRBOBNWKW-UHFFFAOYSA-N
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Compound 129
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 130
Molecular Weight:292.6767
Molecular Formula:C8H28N4Si4
InChIKey:FIADVASZMLCQIF-UHFFFAOYSA-N
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Compound 131
Molecular Weight:448.754
Molecular Formula:C16H42Li2N4O2Si4
InChIKey:IMSZZBZMRXCYKD-UHFFFAOYSA-N
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Compound 132
Molecular Weight:298.61
Molecular Formula:C8H27LiN4Si4
InChIKey:SYPSPQFHKIDNOD-UHFFFAOYSA-N
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Compound 133
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 134
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 135
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 136
Molecular Weight:304.543
Molecular Formula:C8H26Li2N4Si4
InChIKey:FOIGEHZHYDGHFQ-UHFFFAOYSA-N
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Compound 137
Molecular Weight:419.597
Molecular Formula:C10H30BF4N3Si5
InChIKey:LLEZBTYRVBDFGM-UHFFFAOYSA-N
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Compound 138
Molecular Weight:1091.859
Molecular Formula:C28H86B2F6N10Si14
InChIKey:LIKPHAZYMATWFZ-UHFFFAOYSA-N
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Compound 139
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 140
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 142
Molecular Weight:858.246
Molecular Formula:C32H80B6F4N10Si4
InChIKey:LDXQKYIAMMPGFZ-UHFFFAOYSA-N
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Compound 141
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 143
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 144
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 145
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 146
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 147
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 149
Molecular Weight:486.778
Molecular Formula:C16H41Cl2N5Si4
InChIKey:IPBIMDGWZKDMCE-UHFFFAOYSA-N
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Compound 148
Molecular Weight:542.67
Molecular Formula:C16H40Cl4N4Si4
InChIKey:HNXNMVIFSRPVDB-UHFFFAOYSA-N
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Compound 150
Molecular Weight:393.8519
Molecular Formula:C6H27N9Si6
InChIKey:IPVQRCSZOWFWKU-UHFFFAOYSA-N
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Compound 152
Molecular Weight:140.2833
Molecular Formula:N4Si3
InChIKey:HQVNEWCFYHHQES-UHFFFAOYSA-N
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Compound 151
Molecular Weight:99.199
Molecular Formula:HN3Si2
InChIKey:KHEPUIMPXCVIQZ-UHFFFAOYSA-N
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